IP Library Granted Patent US 9,868,798
Granted Patent B2
US 9,868,798 · App. 15/126,173 · Granted Jan 16, 2018

Amic acids and imides derived from terpolymers

Inventors: Osama M. Musa (Bedminster, NJ); Krishnamurthy Nacharaju (Hilliard, OH); Cristian Grigoras (Suffern, NY)
Assignee: ISP Investments LLC
C08F8/32A61K8/8164A61Q5/00A61Q5/02A61Q19/00A61Q19/10C08F22/36C08F122/40C09D131/04
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Quick Facts
Patent No.
US 9,868,798
App. No.
15/126,173
Granted
Jan 16, 2018
Kind
B2
Abstract

The present invention provides amic acids and imides derived from a polymer comprising: (a) maleic anhydride, (b) a first C 1 -C 7 alkyl vinyl ether monomer, and (c) a second C 8 -C 30 alkyl vinyl ether monomer, wherein the polymer contains an amic acid or an imide group. The polymers containing an amic acid or an imide group of the invention may be employed in a wide variety of compositions, particularly in oral care compositions. Non-limiting generic structures of the amidic polymers are set out below: (I) wherein R 1 -R 3 , M, a, b, c, d, e, and f are defined herein.

Claims (29)

1. The polymer comprising:

(a) a first repeating unit selected from the group consisting of:

and combinations thereof, and

(b) a second repeating unit selected from the group consisting of:

and combinations thereof, wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

2. The polymer according to claim 1 , further comprising a repeating unit selected from the group consisting of:

and combinations thereof; wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

3. The polymer according to claim 2 , wherein R 1 is CH 3 , R 2 is C 12 H 25 , R 3 is selected from the group consisting of C 4 H 9 , C 8 H 17 , C 12 H 25 , and C 16 H 33 , and M is H or Na.

4. The polymer according to claim 2 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time.

5. The polymer according to claim 4 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time and e and f are not both zero at the same time.

6. The polymer according to claim 4 , selected from the group consisting of:

7. A composition comprising a polymer comprising: (a) maleic anhydride, (b) a first C 1 -C 7 alkyl vinyl ether monomer, and (c) a second C 8 -C 30 alkyl vinyl ether monomer, wherein the polymer contains an amic acid or an imide group.

8. The composition according to claim 7 , comprising:

(a) a first repeating unit selected from the group consisting of:

and combinations thereof, and

(b) a second repeating unit selected from the group consisting of:

and combinations thereof, wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

9. The composition according to claim 8 , further comprising a repeating unit selected from the group consisting of:

and combinations thereof; wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals alkaline earth metals, ammonium salts, and combinations thereof.

10. The composition according to claim 9 , wherein R 1 is CH 3 , R 2 is C 12 H 25 , R 3 is selected from the group consisting of C 4 H 9 , C 8 H 7 , C 2 H 25 , and C 16 H 33 , and M is H or Na.

11. The composition according to claim 9 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time.

12. The composition according to claim 11 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time and e and f are not both zero at the same time.

13. The composition according to claim 11 , selected from the group consisting of:

14. The composition according to claim 7 , wherein the composition is selected from the group consisting of adhesives, aerosols, agricultural agents, anti-soil redeposition agents, battery agents, beverages, biocides, cementing agents, cleaning agents, coating agents, conductive materials, cosmetic agents, dental agents, detergents, dispersants, drugs, electronics, encapsulations, foods, hair sprays, household-industrial agents, inks and coatings, interlaminate adhesives, lithographic solutions, membrane additive agents, metal working fluids, oilfield agents, paints, paper agents, personal care agents, pharmaceuticals, pigments, plasters, plastics, printing agents, reactive biocides, reactive rheology modifiers, refractive index modifiers, sequestrants, soil release agents, static control agents, and wood-care agents.

15. The composition according to claim 14 , wherein the personal care agent composition is selected from the group consisting of adhesives, antiperspirants and deodorants, cosmetics, drug delivery systems, facial compositions, hair compositions, modified natural oils, oil compositions, oral care agents, pharmaceutical compositions, pigments, skin and tissue compositions, sun care products, tablet coatings, thermal protection, toothpaste compositions, transdermal patches, wear resistance, and wrinkle reduction.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
CHANGE OF NAME Recorded Mar 24, 2017
From: ISP INVESTMENTS INC.
To: ISP INVESTMENTS LLC
Reel/Frame 042092/0260 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2017
From: MUSA, OSAMA M.; NACHARAJU, KRISHNAMURTHY; GRIGORAS, CRISTIAN
To: ISP INVESTMENTS INC.
Reel/Frame 041702/0829 →
Continuity (2)
Provisional Application 61954000 · Mar 17, 2014
Related Publication 20170101485A1 · Apr 13, 2017