Plated steel sheet with quasicrystal
View Patent ↗A plated steel sheet with a quasicrystal includes a steel sheet and a plated-metal-layer arranged on a surface of the steel sheet. The plated-metal-layer includes, as a chemical composition, Mg, Zn, and Al, and satisfies 25%≤Zn+Al in atomic %. The plated-metal-layer includes, as a metallographic structure, a quasicrystal phase. A Mg content, a Zn content, and an Al content in the quasicrystal phase satisfy 0.5≤Mg/(Zn+Al)≤0.83 in atomic %. In addition, an average equivalent circle diameter of the quasicrystal phase is larger than 1 μm and equal to or smaller than 200 μm.
1. A plated steel sheet with a quasicrystal, comprising a steel sheet and a plated-metal-layer arranged on a surface of the steel sheet,
wherein:
the plated-metal-layer comprises:
as a chemical composition, by atomic %,
20% to 60% of Zn,
0.3% to 15% of Al,
0% to 3.5% of Ca,
0% to 3.5% of Y,
0% to 3.5% of La,
0% to 3.5% of Ce,
0% to 0.5% of Si,
0% to 0.5% of Ti,
0% to 0.5% of Cr,
0% to 2% of Fe,
0% to 0.5% of Co,
0% to 0.5% of Ni,
0% to 0.5% of V,
0% to 0.5% of Nb,
0% to 0.5% of Cu,
0% to 0.5% of Sn,
0% to 0.2% of Mn,
0% to 0.5% of Sr,
0% to 0.5% of Sb,
0% to 0.5% of Pb, and
a balance of Mg and impurities; where
a zinc content and an aluminum content expressed in atomic % in the chemical composition satisfy 25%≤Zn+Al; and
as a metallographic structure, a quasicrystal phase which is defined as a phase in which a magnesium content, a zinc content, and an aluminum content expressed in atomic % satisfy 0.5≤Mg/(Zn+Al)≤0.83; and
an average equivalent circle diameter of the quasicrystal phase is larger than 1 μm and equal to or smaller than 200 μm.
2. The plated steel sheet with a quasicrystal according to claim 1 ,
wherein a calcium content, an yttrium content, a lanthanum content, and a cerium content expressed in atomic % in the chemical composition of the plated-metal-layer satisfy 0.3%≤Ca+Y+La+Ce≤3.5%.
3. The plated steel sheet with a quasicrystal according to claim 1 ,
wherein a silicon content, a titanium content, and a chromium content expressed in atomic % in the chemical composition of the plated-metal-layer satisfy 0.005%≤Si+Ti+Cr≤0.5%.
4. The plated steel sheet with a quasicrystal according to claim 1 ,
wherein a zinc content and an aluminum content expressed in atomic % in the chemical composition of the plated-metal-layer satisfy 30%≤Zn+Al≤50%, and 3≤Zn/Al≤12.
5. The plated steel sheet with a quasicrystal according to claim 1 , wherein:
when viewed in a cross section, whose cutting direction is parallel to a thickness direction of the plated-metal-layer,
the metallographic structure of the plated-metal-layer is a bimodal structure which comprises a fine domain, which is a domain comprising a grain having an equivalent circle diameter of 1 μm or smaller, and a coarse domain, which is a domain comprising a grain having an equivalent circle diameter of larger than 1 μm;
the coarse domain comprises the quasicrystal phase; and
the fine domain comprises at least one selected from a Mg 51 Zn 20 phase, a Mg 32 (Zn, Al) 49 phase, a MgZn phase, a MgZn 2 phase, and a Zn phase.
6. The plated steel sheet with a quasicrystal according to claim 5 ,
wherein: an area fraction of the coarse domain in the metallographic structure is equal to or more than 5% and equal to or less than 80%; and
an area fraction of the fine domain in the metallographic structure is equal to or more than 20% and equal to or less than 95%.
7. The plated steel sheet with a quasicrystal according to claim 5 ,
wherein: an area fraction of the quasicrystal phase included in the coarse domain is equal to or more than 80% and less than 100% in the coarse domain; and
an area fraction in total of the Mg 51 Zn 20 phase, the Mg 32 (Zn, Al) 49 phase, the MgZn phase, the MgZn 2 phase, and the Zn phase included in the fine domain is equal to or more than 80% and less than 100% in the fine domain.
8. The plated steel sheet with a quasicrystal according to claim 5 ,
wherein, when viewed in the cross section and when a thickness of the plated-metal-layer is regarded as D, an area from a surface of the plated-metal-layer toward the steel sheet in the thickness direction to 0.3×D is regarded as a surface area of the plated-metal-layer, and an area from an interface between the steel sheet and the plated-metal-layer toward the plated-metal-layer in the thickness direction to 0.3×D is regarded as a deep area of the plated-metal-layer,
an area fraction of the coarse domain in the surface area of the plated-metal-layer is equal to or more than 10% and less than 100% and an area fraction of the coarse domain in the deep area of the plated-metal-layer is equal to or more than 10% and less than 100%, and
wherein, when an area except for the surface area and the deep area in the plated-metal-layer is regarded as a center area of the plated-metal-layer,
an area fraction of the fine domain in the center area of the plated-metal-layer is equal to or more than 50% and less than 100%.
9. The plated steel sheet with a quasicrystal according to claim 1 ,
wherein a Mg phase is absent in the metallographic structure of the plated-metal-layer.
10. The plated steel sheet with a quasicrystal according to claim 1 further comprising a Fe—Al containing alloy layer,
wherein: the Fe—Al containing alloy layer is arranged between the steel sheet and the plated-metal-layer;
the Fe—Al containing alloy layer comprises at least one selected from Fe 5 Al 2 and Al 3.2 Fe; and
a thickness of the Fe—Al containing alloy layer is equal to or more than 10 nm and equal to or less than 1000 nm.
11. A method of producing the plated steel sheet with the quasicrystal according to claim 1 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
12. The method of producing the plated steel sheet with the quasicrystal according to claim 11 , wherein:
in the hot-dip-plating process, an oxide in the hot-dip-plating bath is 1 g/l or less;
an oxygen concentration of an atmosphere at dipping the steel sheet is 100 ppm or less in volume ratio;
a plating tub to hold the hot-dip-plating bath is a steel tub;
a dross in the hot-dip-plating bath is removed by a metal pump;
T bath which is a temperature of the hot-dip-plating bath is equal to or higher than 10° C. and equal to or lower than 100° C. higher than the T melt ; and
a time for dipping the steel sheet into the hot-dip-plating bath is equal to or longer than 1 sec and equal to or shorter than 10 sec.
13. A method of producing the plated steel sheet with the quasicrystal according to claim 2 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
14. A method of producing the plated steel sheet with the quasicrystal according to claim 3 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
15. A method of producing the plated steel sheet with the quasicrystal according to claim 4 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
16. A method of producing the plated steel sheet with the quasicrystal according to claim 5 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
17. A method of producing the plated steel sheet with the quasicrystal according to claim 6 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
18. A method of producing the plated steel sheet with the quasicrystal according to claim 7 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
19. A method of producing the plated steel sheet with the quasicrystal according to claim 8 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.
20. A method of producing the plated steel sheet with the quasicrystal according to claim 9 , the method comprising:
a hot-dip-plating process comprising dipping a steel sheet into a hot-dip-plating bath having an adjusted composition in order to form a plated-metal-layer on a surface of the steel sheet;
a first cooling process comprising cooling the steel sheet after the hot-dip-plating process such that an average cooling rate of the plated-metal-layer is equal to or faster than 15° C./sec and equal to or slower than 50° C./sec in a temperature range where a temperature of the plated-metal-layer is from T melt to T solid-liquid in unit of ° C., when the T melt is regarded as a liquidus temperature of the plated-metal-layer and when the T solid-liquid is a temperature range where the plated-metal-layer is in a coexistence state of a solid phase and a liquid phase and where a volume ratio of the solid phase to the plated-metal-layer is equal to or more than 0.3 and equal to or less than 0.8; and
a second cooling process comprising cooling the steel sheet after the first cooling process such that an average cooling rate of the plated-metal-layer is equal to or faster than 100° C./sec and equal to or slower than 3000° C./sec in a temperature range where a temperature of the plated-metal-layer is from a temperature at finishing the first cooling process to 250° C.