Multifilament and braid
It is provided that a multifilament and a braid that are capable of being processed into products in a wide range of temperature and are excellent in dimensional stability and abrasion resistance. A multifilament comprising 5 or more monofilaments, wherein the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit, and wherein a difference between a maximum value and a minimum value in a ratio of a diffraction peak intensity of orthorhombic crystal (200) plane to a diffraction peak intensity of orthorhombic crystal (110) plane in a monofilament cross section is 0.22 or less.
1. A multifilament comprising 5 or more monofilaments, wherein
the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit, and wherein
a difference between a maximum value and a minimum value in a ratio of a diffraction peak intensity of orthorhombic crystal (200) plane to a diffraction peak intensity of orthorhombic crystal (110) plane in a monofilament cross section is 0.22 or less.
2. The multifilament according to claim 1 , wherein a coefficient of variation CV of the peak intensity ratio defined by Equation (1) below is 50% or less:
Coefficient of variation CV (%)=(standard deviation of the peak intensity ratio of the monofilaments)/(average value of the peak intensity of the monofilaments)×100 (1).
3. The multifilament according to claim 1 , which has a difference between a maximum value of a degree of crystal orientation and a minimum value of a degree of crystal orientation of 0.010 or less in the mono filament cross section.
4. The multifilament according to claim 1 , which shows, in accordance with JIS L 1095, 1000 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 5 cN/dtex and 100 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 10 cN/dtex.
5. The multifilament according to claim 1 , wherein the monofilament has a titer of 3 dtex or more and 40 dtex or less.
6. The multifilament according to claim 1 , which has a maximum thermal stress of 0.20 cN/dtex or more.
7. The multifilament according to claim 1 , wherein a coefficient of variation CV′ of initial modulus defined by Equation (2) below is 30% or less:
Coefficient of variation CV′(%)=(standard deviation of initial modulus of the monofilament)/(average value of initial moduli of the monofilaments)×100 (2)
8. The multifilament according to claim 1 , which has a thermal stress of 0.15 cN/dtex or more at 120° C.
9. The multifilament according to claim 1 , which has a thermal shrinkage of 0.20% or less at 70° C. and a thermal shrinkage of 3.0% or less at 120° C.
10. The multifilament according to claim 1 , which has a tensile strength of 18 cN/dtex or more and an initial modulus of 600 cN/dtex or more.
11. A method for producing the multifilament according to claim 1 , the method comprising:
a dissolution step of dissolving the polyethylene in a solvent to obtain a polyethylene solution;
a spinning step of discharging the polyethylene solution out of a nozzle at a temperature of melting point of the polyethylene or higher and cooling a discharged yarn thread with a coolant at 10° C. or higher and 60° C. or lower;
a drawing step of drawing a discharged undrawn yarn while removing the solvent; and
a winding step of winding a resulting yarn at 50° C. or lower and at a tensile force of 5 cN/dtex or less, wherein
the drawing step includes 1 or more and 3 or less in number of drawing step, a draw ratio is 7.0 times or more and 60 times or less, and a total drawing time is 0.5 minutes or longer and 20 minutes or shorter.
12. A braid comprising a multifilament comprising 5 or more mono filaments, wherein
the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit, and wherein
in the multifilament in a state where the braid is unbraided, a difference between a maximum value and a minimum value in a ratio of a di inaction peak intensity of orthorhombic crystal (200) plane to a diffraction peak intensity of orthorhombic crystal (110) plane in a monofilament cross section is 0.18 or less.
13. The braid according to claim 12 , wherein a coefficient of variation CV of the peak intensity ratio defined by Equation (1) below is 40% or less:
Coefficient of variation CV (%)=(standard deviation of the peak intensity ratio of the monofilament)/(average value of the peak intensity of the monofilament)×100 (1)
14. The braid according to claim 12 , which has a difference between a maximum value of a degree of crystal orientation and a minimum value of a degree of crystal orientation of 0.012 or less.
15. The braid according to claim 12 , which shows 1000 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 5 cN/dtex in accordance with JIS L-1095.
16. The braid according to claim 12 , wherein in the abrasion resistance test measured at a load of 5 cN/dtex, a difference between a number of reciprocating abrasions of the braid and a number of reciprocating abrasions of the multifilament in a state where the braid is upbraided is 320 times or less.
17. The braid according to claim 12 , wherein the multifilament in the state where the braid is unbraided shows 100 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 10 cN/dtex in accordance with JIS L-1095.
18. The braid according to claim 12 , wherein a difference between a tensile strength of the braid and a tensile strength of the multifilament in the state where the braid is unbraided is 5 cN/dtex or less.
19. The braid according to claim 12 , which has a thermal shrinkage of 3.0% or less at 120° C.
20. The braid according to claim 12 , which has a tensile strength of 18 cN/dtex or more and an initial modulus of 300 cN/dtex or more.
21. The braid according to claim 12 , wherein the monofilament has a titer of 2 dtex or more and 40 dtex or less in the state that the braid is unbraided.
22. The braid according to claim 12 , wherein the multifilament in the state that the braid is unbraided has a thermal shrinkage of 0.11% or less at 70° C. and a thermal shrinkage of 2.15% or less at 120° C.
23. The braid according to claim 12 , wherein the multifilament in the state that the braid is unbraided has a thermal stress of 0.15 cN/dtex or more at 120° C.
24. A method for producing the braid according to claim 12 , the method comprising a step of:
braiding the multifilament and performing heat treatment, wherein
the heat treatment is performed at 70° C. or higher; a time of the heat treatment is 0.1 seconds or longer and 30 minutes or shorter; and a tensile force of 0.02 cN/dtex or more and 15 cN/dtex or less is applied to the braid in the heat treatment.
25. The method for producing the braid according to claim 24 , wherein a length of the braid after the heat treatment is 1.05 times or more and 15 times or less as long as a length of the braid before the heat treatment by the tensile force.
26. A fishing line obtained from the braid according to claim 12 .
27. A net obtained from the braid according to claim 12 .
28. A rope obtained from the braid according to claim 12 .