Multifilament and braid
It is provided that a multifilament and a braid that are capable of being processed into products in a wide range of temperature and are excellent in dimensional stability and abrasion resistance. A multifilament comprising 5 or more monofilaments, wherein the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit, and shows 1000 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 5 cN/dtex in accordance with JIS L-1095.
1. A multifilament comprising 5 or more monofilaments, wherein
the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit, and shows 1000 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 5 cN/dtex in accordance with JIS L-1095.
2. The multifilament according to claim 1 , which shows 100 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 10 cN/dtex in accordance with JIS L-1095.
3. The multifilament according to claim 1 , wherein the monofilament has a titer of 3 dtex or more and 40 dtex or less.
4. The multifilament according to claim 1 , which has a maximum thermal stress of 0.20 cN/dtex or more.
5. The multifilament according to claim 1 , wherein a coefficient of variation CV of initial modulus defined by Equation (1) below is 30% or less:
Coefficient of variation CV(%)=(standard deviation of initial modulus of the monofilament)/(average value of initial moduli of monofilament)×100 (1).
6. The multifilament according to claim 1 , which has a thermal stress of 0.15 cN/dtex or more at 120° C.
7. The multifilament according to claim 1 , which has a thermal shrinkage of 0.20% or less at 70° C. and a thermal shrinkage of 3.0% or less at 120° C.
8. The multifilament according to claim 1 , which has a tensile strength of 18 cN/dtex or more and an initial modulus of 600 cN/dtex or more.
9. A method for producing the multi filament according to claim 1 , the method comprising:
a dissolution step of dissolving the polyethylene in a solvent to obtain a polyethylene solution;
a spinning step of discharging the polyethylene solution out of a nozzle at a temperature of melting point of the polyethylene or higher and cooling a discharged yarn thread with a coolant at 10° C. or higher and 60° C. or lower;
a drawing step of drawing a discharged undrawn yarn while removing the solvent; and
a winding step of winding a resulting yarn at 50° C. or lower and at a tensile force of 5 cN/dtex or less, wherein
the drawing step includes 1 or more and 3 or less in number of drawing step, a draw ratio is 7.0 times or more and 60 times or less, and a total drawing time is 0.5 minutes or longer and 20 minutes or shorter.
10. A braid comprising a multifilament comprising 5 or more monofilaments, wherein
the braid shows 1000 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 5 cN/dtex in accordance with JIS L-1095, and
the multifilament contains polyethylene having an intrinsic viscosity [η] of 5.0 dL/g or more and 40.0 dL/g or less and substantially including ethylene as a repeating unit.
11. The braid according to claim 10 , wherein in the abrasion resistance test measured at a load of 5 cN/dtex, a difference between a number of reciprocating abrasions of the braid and a number of reciprocating abrasions of the multifilament in a state where the braid is unbraided is 320 times or less.
12. The braid according to claim 10 , wherein the multifilament in the state where the braid is unbraided shows 100 times or more in number of reciprocating abrasions at break in an abrasion resistance test measured at a load of 10 cN/dtex in accordance with JIS L-1095.
13. The braid according to claim 10 , wherein a difference between a tensile strength of the braid and a tensile strength of the multifilament in the state where the braid is unbraided is 5 cN/dtex or less.
14. The braid according to claim 10 , which has a thermal shrinkage of 3.0% or less at 120° C.
15. The braid according to claim 10 , which has a tensile strength of 18 cN/dtex or more and an initial modulus of 300 cN/dtex or more.
16. The braid according to claim 10 , wherein the monofilament has a titer of 2 dtex or more and 40 dtex or less in the state that the braid is unbraided.
17. The braid according to claim 10 , wherein the multifilament in the state that the braid is unbraided has a thermal shrinkage of 0.11% or less at 70° C. and a thermal shrinkage of 2.15% or less at 120° C.
18. The braid according to claim 10 , wherein the multifilament in the state that the braid is unbraided has a thermal stress of 0.15 cN/dtex or more at 120° C.
19. A method for producing the braid according to claim 10 , the method comprising a step of:
braiding the multifilament and performing heat treatment, wherein
the heat treatment is performed at 70° C. or higher; a time of the heat treatment is 0.1 seconds or longer and 30 minutes or shorter; and a tensile force of 0.02 cN/dtex or more and 15 cN/dtex or less is applied to the braid in the heat treatment.
20. The method for producing the braid according to claim 19 , wherein a length of the braid after the heat treatment is 1.05 times or more and 15 times or less as long as a length of the braid before the heat treatment by the tensile force.
21. A fishing line obtained from the braid according to claim 10 .
22. A net obtained from the braid according to claim 10 .
23. A rope obtained from the braid according to claim 10 .