Method for recovering rare earth element
View Patent ↗An object of the present invention is to provide a method for recovering a rare earth element, including subjecting a workpiece containing at least a rare earth element and an iron group element to an oxidation treatment, then turning the treatment environment into an environment where carbon is present, and subjecting an oxidation-treated workpiece to a heat treatment, thereby separating a rare earth element in the form of an oxide from an iron group element, according to which an oxide of a rare earth element can be efficiently separated from an iron group element at low treatment cost, and also wear and damage to the treatment container can be suppressed to allow the container to be used repeatedly for a long period of time. The method of the present invention as a means for resolution is characterized in that the oxidation-treated workpiece is mixed with petroleum coke as a carbon supply source, placed in a treatment container, and then subjected to the heat treatment in an inert gas atmosphere or in vacuum at a temperature of 950° C. to 1150° C. (excluding 1150° C.).
1. A method for recovering a rare earth element, comprising subjecting a workpiece containing at least a rare earth element and an iron group element to an oxidation treatment, then turning the treatment environment into an environment where carbon is present, and subjecting an oxidation-treated workpiece to a heat treatment, thereby separating a rare earth element in the form of an oxide from an iron group element,
the method being characterized in that the oxidation-treated workpiece is mixed with petroleum coke as a carbon supply source, placed in a treatment container, and then subjected to the heat treatment in an inert gas atmosphere or in vacuum at a temperature of between at least 950° C. and at most 1100° C.
2. The method according to claim 1 , characterized in that the petroleum coke is in granular or powder form having a particle size of 125 μm or less.
3. The method according to claim 1 , characterized in that at least part of the workpiece is in granular or powder form having a particle size of 500 μm or less.
4. The method according to claim 1 , characterized in that the workpiece has an iron group element content of 30 mass % or more.
5. The method according to claim 1 , characterized in that the workpiece is an R—Fe—B based permanent magnet.
6. The method according to claim 1 , characterized in that a mass obtained as a heat treatment product is ground, and then a powder containing an oxide of a rare earth element as a main component is separated from an alloy of an iron group element and carbon by a magnetic method and recovered.