Method for producing corrugated cardboard
The present invention relates to a process for producing corrugated fiberboard from plies of paper which each have a grammage of 70 to 200 g/m 2 and of which at least one ply of paper is obtained by a process comprising the addition of (A) 0.25 to 5 wt %, based on dry paper stock, of at least one cationic polymer comprising vinylamine units, and (B) 0 to 5 wt %, based on dry paper stock, of at least one polymeric anionic compound, to a paper stock, draining the paper stock by sheet formation, coating the paper web obtained with (C) 0.1 to 3 wt %, based on dry paper stock, of at least one starch and drying the coated paper web, wherein the polymeric anionic compound is selected from a polymeric anionic compound (B1) and a polymeric anionic compound (B2), wherein said polymeric anionic compound (B1) is obtainable by copolymerizing a monomer mixture comprising, preferably consisting of, (a) at least one monomer (a) selected from acrylamide and an N-vinylcarboxamide of the formula where R 1 and R 2 are each H or C 1 to C 6 alkyl, (b) at least one acid-functional monoethylenically unsaturated monomer and/or its alkali metal, alkaline earth metal or ammonium salts (b), and (c) optionally one or more monoethylenically unsaturated compounds (c) other than said monomers (a) and (b), and (d) optionally one or more compounds having at least two ethylenically unsaturated double bonds in the molecule, and said polymeric anionic compound (B2) is the hydrolysis product of said polymeric anionic compound (B1) whose carboxamide moieties have been partly or wholly hydrolyzed into amino groups, and also the corrugated fiberboard thus obtained and its use in the manufacture of packaging boxes from corrugated fiberboard.
1. A process for producing corrugated fiberboard from plies of paper which each have a grammage of 70 to 200 g/m 2 and of which at least one ply of paper is obtained by a process comprising:
the addition of
(A) 0.25 to 5 wt %, based on dry paper stock, of at least one cationic polymer comprising vinylamine units, and
(B) 0 to 5 wt %, based on dry paper stock, of at least one polymeric anionic compound,
to a paper stock;
draining the paper stock by sheet formation;
coating a paper web obtained with
(C) 0.1 to 3 wt %, based on dry paper stock, of at least one starch, to obtain a coated paper web; and
drying the coated paper web,
wherein:
the polymeric anionic compound is selected from the group consisting of a polymeric anionic compound (B1) and a polymeric anionic compound (B2); and
the polymeric anionic compound (B1) is obtained by copolymerizing a monomer mixture comprising
(a) at least one monomer selected from the group consisting of acrylamide and an N-vinylcarboxamide of the formula
where R 1 and R 2 are each H or C 1 to C 6 alkyl;
(b) at least one acid-functional monoethylenically unsaturated monomer, an alkali metal, alkaline earth metal or ammonium salt thereof, or a mixture thereof;
(c) optionally one or more monoethylenically unsaturated compounds other than said monomers (a) and (b); and
(d) optionally one or more compounds having at least two ethylenically unsaturated double bonds in the molecule; and
the polymeric anionic compound (B2) is a hydrolysis product of the polymeric anionic compound (B1) whose carboxamide moieties have been partly or wholly hydrolyzed into amino groups.
2. The process according to claim 1 , wherein the cationic polymer comprising vinylamine units is obtained by:
polymerizing:
(a) at least one monomer of the formula
where R 1 and R 2 are each H or C 1 to C 6 alkyl,
(c) optionally one or more monoethylenically unsaturated monomers other than said monomers (a), and
(d) optionally one or more compounds having at least two ethylenically unsaturated double bonds in the molecule; and then
partially or completely hydrolyzing the monomer (I) units polymerized into the polymer, to form amino groups,
and/or
the cationic polymer comprising vinylamine units is obtained by Hofmann degradation of polymers having acrylamide units, methacrylamide units, or both.
3. The process according to claim 1 , wherein the cationic polymer comprising vinylamine units is polyvinylamine or an at least 10 mol % hydrolyzed homopolymer of N-vinylformamide.
4. The process according to claim 1 , wherein the polymeric anionic compound is obtained by polymerizing a monomer mixture comprising:
(a) at least one monomer selected from the group consisting of acrylamide and an N-vinylcarboxamide of the foimula
where R 1 and R 2 are each H or C 1 to C 6 alkyl;
(b) at least one acid-functional monoethylenically unsaturated monomer, an alkali metal, alkaline earth metal or ammonium salt thereof, or a mixture thereof;
(c) optionally one or more monoethylenically unsaturated monomers other than said monomers (a) and (b); and
(d) optionally one or more compounds having at least two ethylenically unsaturated double bonds in the molecule.
5. The process according to claim 1 wherein the polymeric anionic compound is obtained by polymerizing a monomer mixture comprising:
(a1) N-vinyl fonnamide;
(b1) acrylic acid, methacrylic acid, alkali metal or ammonium salts thereof, or a mixture thereof: and
(c1) optionally one or more monoethylenically unsaturated monomers other than the monomers of groups (a) and (b).
6. The process according to claim 1 , wherein the polymeric anionic compound is an anionic copolymer of acrylamide.
7. The process according to claim 1 , wherein the polymeric anionic compound is obtained by copolymerizing a monomer mixture comprising:
(a1) acrylamide;
(b1) acrylic acid, methacrylic acid, alkali metal or ammonium salts thereof, or a mixture thereof; and
(c1) optionally one or more monoethylenically unsaturated monomers other than the monomers of groups (a) and (b).
8. The process according to claim 1 , wherein the paper web obtained is coated with an enzymatically degraded starch.
9. A corrugated fiberboard obtained by the process of claim 1 .
10. A method, comprising manufacturing a packaging box with the corrugated fiberboard of claim 9 .