MAGNESIUM-BASED CEMENTS AND SLURRY PRECURSORS FOR THE SAME
Magnesium based cements are provided using one or more slurry precursors. In an embodiment, a method of forming a magnesium-based cement includes providing an aqueous slurry of a magnesium compound. A magnesium cement co-reactant is also provided. The aqueous slurry of the magnesium compound is mixed with the magnesium cement co-reactant to provide the magnesium-based cement.
1 . A method of forming a magnesium-based cement comprising:
providing an aqueous slurry of a magnesium compound;
providing a magnesium cement co-reactant; and
mixing the aqueous slurry of the magnesium compound with the magnesium cement co-reactant.
2 . The method according to claim 1 , wherein the magnesium compound includes one or more of magnesium oxide and magnesium hydroxide.
3 . The method according to claim 2 , wherein the magnesium compound includes one or more of dead burned magnesium oxide, hard burned magnesium oxide, light burned magnesium oxide, and flash calcined magnesium oxide.
4 . The method according to claim 2 , wherein the magnesium compound includes one or more of Brucite, Brucitic marble, fully hydrated magnesium oxide, partially hydrated magnesium oxide, and synthetic magnesium oxide produced by alkali precipitation from one or more of magnesium containing brines and seawater.
5 . The method according to claim 1 , wherein providing the aqueous slurry of the magnesium compound includes providing the aqueous slurry at a predetermined temperature.
6 . The method according to claim 5 , wherein the predetermined temperature is between about 40° F. to about 140° F.
7 . The method according to claim 1 , wherein the aqueous slurry of the magnesium compound includes a dispersing agent capable of producing a stable slurry.
8 . The method according to claim 7 , wherein the dispersing agent includes one or more of a polyacrylate, a polyacrylamide, a polyacrylic/polyacrylamide copolymer, and one or more of an anionic, a cationic, a nonionic, and an amphoteric surfactant.
9 . The method according to claim 1 , wherein the aqueous slurry of the magnesium compound includes a viscosity control agent capable of producing a stable, slurry having a relatively higher magnesium compound concentration.
10 . The method according to claim 9 , wherein the viscosity control agent includes one or more of a carbohydrate-based mono-saccharide, a di-saccharide, a polysaccharides, a polyhydric alcohol, and one or more of an ethoxylated and a non-ethoxylated polyhydric alcohol based surfactants.
11 . The method of claim 1 , wherein providing the aqueous slurry of the magnesium compound includes one or more of pre-dispersing the magnesium compound and at least partially pre-hydrating the magnesium compound.
12 . The method of claim 11 , wherein providing the aqueous slurry of the magnesium compound includes pre-hydrating the magnesium compound to provide a magnesium oxide to magnesium hydroxide ratio of between about 95% magnesium oxide to 5% magnesium hydroxide to about 0% magnesium oxide to about 100% magnesium hydroxide.
13 . The method according to claim 1 , wherein providing the magnesium cement co-reactant includes providing the magnesium cement co-reactant as an aqueous slurry including the magnesium cement co-reactant.
14 . The method according to claim 13 , wherein providing the magnesium cement co-reactant as an aqueous slurry includes one or more of pre-dispersing the magnesium cement co-reactant and at least partially pre-hydrating the magnesium cement co-reactant.
15 . The method according to claim 1 , wherein the magnesium cement co-reactant includes one or more of an oxychloride co-reactant, an oxysulfate co-reactant, a phosphate co-reactant, and a silicate co-reactant.
16 . The method according to claim 15 , wherein the phosphate co-reactant includes an organo-phosphate including one or more of a mono-potassium phosphate, an ammonium mono-hydrogen phosphate, an ammonium dihydrogen phosphate, a diammonium phosphate, an ammonium polyphosphate, a potassium mono-hydrogen phosphate, a potassium di-hydrogen phosphate, an aluminum phosphate, an ortho-phosphate, an aluminum polyphosphate, an aluminum phosphonate, an ammonium polyphosphate, a pyrophosphate, a polyphosphate, a potassium pyrophosphate, a phosphoric acids, an organic phosphate acids, and a phosphonates.
17 . The method according to claim 1 , wherein the aqueous slurry of the magnesium compound includes from between about 5% to about 90% magnesium compound solids by weight of the slurry.
18 . The method according to claim 17 , wherein the aqueous slurry of the magnesium compound includes from between about 50% to about 70% magnesium compound solids by weight of the slurry.
19 . The method according to claim 1 , further comprising providing one or more retarders capable of increasing a working time of the magnesium-based cement, the one or more retarders including one or more of cold water, a borate, a boric acid, a hydrochloric acid, a sulfuric acid, a citrate, a tartrates, an organic acid, and a salt of an organic acid.
20 . A method of forming a magnesium-based cement comprising:
providing an aqueous slurry of a magnesium cement co-reactant;
providing a magnesium compound; and
mixing the aqueous slurry of the magnesium cement co-reactant with the magnesium compound.