GOLF BALLS WITH COVERS OF HIGH ACID IONOMERS
Disclosed is a golf ball comprising a cover prepared from an ionomer composition comprising a high acid ionomer comprising about 15 to about 30 weight % of copolymerized units of a C 3-8 α,β-ethylenically unsaturated carboxylic acid and about 3 to about 13 weight % of copolymerized units of vinyl acetate, alkyl acrylate or alkyl methacrylate.
1 . A golf ball comprising a core and a cover and optionally at least one intermediate layer positioned between the core and the cover, wherein the cover comprises an ionomer of an ethylene acid copolymer comprising copolymerized units of ethylene, about 15 to about 30 weight % of copolymerized units of a C 3-8 α,β-ethylenically unsaturated carboxylic acid, and about 3 to about 13 weight % of copolymerized units of a softening comonomer selected from the group consisting of vinyl acetate, alkyl acrylate and alkyl methacrylate; wherein the acid moieties in the acid copolymer are nominally neutralized to a level from about 15% to about 30% to carboxylate salts comprising alkali metal ions, alkaline earth ions, transition metal ions or combinations thereof.
2 . The golf ball of claim 1 wherein the ethylene acid copolymer comprises copolymerized units of about 67.5 weight percent of ethylene, about 22.5 weight percent of methacrylic acid and about 10 weight percent of n-butyl acrylate.
3 . The golf ball of claim 1 wherein the ethylene acid copolymer comprises copolymerized units of about 68.5 weight percent of ethylene, about 21.5 weight percent of methacrylic acid and about 10 weight percent of n-butyl acrylate.
4 . The golf ball of claim 1 wherein the carboxylate salts comprise zinc ions, sodium ions or a combination thereof.
5 . The golf ball of claim 1 wherein the composition of the cover further comprises an additional ionomer of an ethylene acid copolymer comprising copolymerized units of ethylene, about 3 to about 12 weight % of copolymerized units of a C 3-8 α,β-ethylenically unsaturated carboxylic acid, and about 15 to about 30 weight % of copolymerized units of a softening comonomer selected from the group consisting of vinyl acetate, alkyl acrylate and alkyl methacrylate; wherein the acid moieties in the acid copolymer are nominally neutralized to a level from about 15% to about 70% to carboxylate salts comprising alkali metal ions, alkaline earth ions, transition metal ions or combinations thereof.
6 . The golf ball of claim 5 wherein the additional ionomer comprises about 3 to about 12 weight % of copolymerized units of acrylic acid or methacrylic acid and about 15 to about 30 weight % of copolymerized units of alkyl acrylate or alkyl methacrylate.
7 . The golf ball of claim 6 wherein the additional ionomer comprises about 3 to about 12 weight % of copolymerized units of methacrylic acid and about 15 to about 30 weight % of copolymerized units of n-butyl acrylate.
8 . The golf ball of claim 1 wherein the core comprises polybutadiene rubber or a thermoplastic organic acid modified ionomer composition.
9 . The golf ball of claim 1 wherein the intermediate layer is present and comprises a thermoplastic organic acid modified ionomer composition.
10 . A composition comprising an ionomer of an ethylene acid copolymer comprising copolymerized units of ethylene, about 15 to about 30 weight % of copolymerized units of a C 3-8 α,β-ethylenically unsaturated carboxylic acid, and about 3 to about 13 weight % of copolymerized units of a softening comonomer selected from the group consisting of vinyl acetate, alkyl acrylate and alkyl methacrylate; wherein the acid moieties in the acid copolymer are nominally neutralized to a level from about 15% to about 30% to carboxylate salts comprising alkali metal ions, alkaline earth ions, transition metal ions or combinations thereof.
11 . The composition of claim 10 wherein the ethylene acid copolymer comprises copolymerized units of about 67.5 weight percent of ethylene, about 22.5 weight percent of methacrylic acid and about 10 weight percent of n-butyl acrylate.
12 . The composition of claim 10 wherein the ethylene acid copolymer comprises copolymerized units of about 68.5 weight percent of ethylene, about 21.5 weight percent of methacrylic acid and about 10 weight percent of n-butyl acrylate.
13 . The composition of claim 10 wherein the carboxylate salts comprise zinc ions, sodium ions or a combination thereof.
14 . The composition of claim 10 further comprising an additional ionomer of an ethylene acid copolymer comprising copolymerized units of ethylene, about 3 to about 12 weight % of copolymerized units of a C 3-8 α,β-ethylenically unsaturated carboxylic acid, and about 15 to about 30 weight % of copolymerized units of a softening comonomer selected from the group consisting of vinyl acetate, alkyl acrylate and alkyl methacrylate; wherein the acid moieties in the acid copolymer are nominally neutralized to a level from about 15% to about 70% to carboxylate salts comprising alkali metal ions, alkaline earth ions, transition metal ions or combinations thereof.
15 . The composition of claim 14 wherein the additional ionomer comprises about 3 to about 12 weight % of copolymerized units of acrylic acid or methacrylic acid and about 15 to about 30 weight % of copolymerized units of alkyl acrylate or alkyl methacrylate.
16 . The composition of claim 15 wherein the additional ionomer comprises about 3 to about 12 weight % of copolymerized units of methacrylic acid and about 15 to about 30 weight % of copolymerized units of n-butyl acrylate.