IP Library Granted Patent US 9,469,738
Granted Patent B1
US 9,469,738 · App. 15/144,875 · Granted Oct 18, 2016

Foamed aqueous composition

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Quick Facts
Patent No.
US 9,469,738
App. No.
15/144,875
Granted
Oct 18, 2016
Kind
B1
Abstract

Foamable aqueous compositions can be used to form light-blocking and light-colored foamed, opacifying elements with one or more dry foamed layers. The compositions contain: (a) 0.05 to 20 weight % of porous particles comprising a continuous polymeric phase and a first set of discrete pores, the porous particles having a mode particle size of 2 to 50 μm; (b) at least 20 weight % of a binder material (that can be curable); (c) 0.1 to 30 weight % of one or more additives including dispersants, plasticizers, inorganic or organic pigments or dyes, thickeners, flame retardants, biocides, fungicides, optical brighteners, tinting colorants, metal flakes, and inorganic or organic fillers; (d) water; and (e) at least 0.001 weight % of an opacifying colorant different from (c), which opacifying colorant absorbs electromagnetic radiation. The foamable aqueous composition can be aerated, disposed on a porous substrate, dried, and crushed on that porous substrate.

Claims (33)

1. A foamed aqueous composition comprising:

(a) at least 0.05 weight % and up to and including 20 weight % of porous particles, each porous particle comprising a continuous polymeric phase and a first set of discrete pores dispersed within the continuous polymeric phase, the porous particles having a mode particle size of at least 2 μm and up to and including 50 μm;

(b) at least 20 weight % of a binder material;

(c) at least 0.1 weight % and up to and including 30 weight % of one or more additives selected from the group consisting of dispersants, plasticizers, inorganic or organic pigments and dyes, thickeners, flame retardants, biocides, fungicides, optical brighteners, tinting colorants, metal flakes, and inorganic or organic fillers;

(d) water; and

(e) at least 0.001 weight % of an opacifying colorant different from all of the one or more additives of (c), which opacifying colorant absorbs predetermined electromagnetic radiation,

all amounts being based on the total weight of the foamed aqueous composition, and the foamed aqueous composition having a foam density of at least 0.1 g/cm 3 and up to and including 0.5 g/cm 3 .

2. The foamed aqueous composition of claim 1 , comprising at least 0.5 weight % and up to and including 10 weight % of the porous particles that have a mode particle size of at least 3 μm and up to and including 40 μm, the amount based on the total weight of the foamed aqueous composition.

3. The foamed aqueous composition of claim 1 , wherein the opacifying colorant is present within the porous particles.

4. The foamed aqueous composition of claim 1 , further comprising a carbon black as the opacifying colorant in an amount of at least 0.003 weight % and up to and including 0.2 weight % based on the total weight of the foamed aqueous composition.

5. The foamed aqueous composition of claim 1 , wherein the continuous polymeric phase of the porous particles is chemically crosslinked.

6. The foamed aqueous composition of claim 1 , wherein the opacifying colorant is present within: the continuous polymeric phase of the porous particles; a volume of the first set of discrete pores; or both the volume of the first set of discrete pores and the continuous polymeric phase of the porous particles.

7. The foamed aqueous composition of claim 1 , wherein the porous particles have a mode particle size of at least 3 μm and up to and including 20 μm.

8. The foamed aqueous composition of claim 1 , wherein:

the porous particles are present in an amount of at least 0.5 weight % and up to and including 10 weight %,

the binder material is present in an amount of at least 30 weight % and up to and including 50 weight %,

an optical brightener is present as at least one of the one or more additives in an amount of at least 0.01 and up to and including 2 weight %,

carbon black is present as at least one opacifying colorant in an amount of at least 0.003 weight % and up to and including 0.2 weight %,

a tinting colorant is present as at least one of the one or more additives in an amount of at least 0.0001 weight % and up to and including 3 weight %,

all amounts based on the total weight of the foamed aqueous composition, and

the foamed aqueous composition has a foam density of at least 0.15 g/cm 3 and up to and including 0.4 g/cm 3 .

9. The foamed aqueous composition of claim 1 , wherein the opacifying colorant is a combination of subtractive primary colored pigments.

10. The foamed aqueous composition of claim 1 , wherein the binder material is present in an amount of at least 30 weight % and up to and including 50 weight %, based on the total weight of the foamed aqueous composition.

11. The foamed aqueous composition of claim 1 , further comprising one or more tinting colorants in an amount of at least 0.0001 weight % and up to and including 3 weight %, based on the total weight of the foamed aqueous composition.

12. The foamed aqueous composition of claim 11 , wherein the one or more tinting colorants are present in at least the porous particles.

13. The foamed aqueous composition of claim 11 , wherein the one or more tinting colorants are present within: the continuous polymeric phase of the porous particles; a volume of the first set of discrete pores; or both the volume of the first set of discrete pores and the continuous polymeric phase.

14. The foamed aqueous composition of claim 1 , wherein water is present in an amount of at least 30 weight %, based on the total weight of the foamed aqueous composition.

15. The foamed aqueous composition of claim 1 , wherein the opacifying colorant is present in an amount of at least 0.001 weight % and up to and including 0.5 weight %, based on the total weight of the foamed aqueous composition.

16. The foamed aqueous composition of claim 1 , wherein at least 50 weight % of the opacifying colorant is present within the continuous polymeric phase and the remainder is present within the volume of the pores of the porous particles.

17. The foamed aqueous composition of claim 1 , wherein the opacifying colorant is carbon black.

18. The foamed aqueous composition of claim 1 , having a foam density of at least 0.15 g/cm 3 and up to and including 0.4 g/cm 3 .

19. The foamed aqueous composition of claim 1 , further comprising an optical brightener that is present within: the continuous polymeric phase of the porous particles; a volume of the first set of discrete pores; or both the volume of the first set of discrete pores and the continuous polymeric phase of the porous particles.

20. The foamed aqueous composition of claim 1 , further comprising metal flakes that are present within: the continuous polymeric phase of the porous particles; a volume of the first set of discrete pores, or both the volume of the first set of discrete pores and the continuous polymeric phase of the porous particles.

Assignments (8)
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Jul 24, 2023
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A.
Reel/Frame 064364/0847 →
NOTICE OF SECURITY INTERESTS Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 056984/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056733/0681 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0233 →
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
SECURITY INTEREST Recorded Jan 13, 2017
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 041042/0877 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 3, 2016
From: NAIR, MRIDULA; BRICK, MARY CHRISTINE; PYSZCZEK, ELLEN J.
To: EASTMAN KODAK COMPANY
Reel/Frame 038442/0275 →