SLOW DISSOLVING HYPOCHLORITE SHAPED ARTICLE
It has now been discovered that forming a shaped article from a blend of calcium hypochlorite and lime, wherein the lime content is greater than 10% by weight, based on the total weight of the shaped article, the resulting solid shaped article has a favorable dissolution (solubility) profile and the solid shaped article maintains structural integrity during use in an aqueous environment.
1 . A shaped article comprising a blend of calcium hypochlorite and lime, wherein the total lime content in the shaped article is greater than 10% by weight, based on the total weight of the shaped article.
2 . The shaped article according to claim 1 , wherein the lime comprises calcium hydroxide.
3 . The shaped article according to claim 1 , wherein the total lime content in the shaped article is at least 11% by weight, based on the total weight of the shaped article.
4 . The shaped article according to claim 2 , wherein the total lime content in the shaped article is at least 11% by weight, based on the total weight of the shaped article.
5 . The shaped article according to claim 3 , wherein the total lime content in the shaped article is at least 12% by weight, based on the total weight of the shaped article.
6 . The shaped article according to claim 4 , wherein the total lime content in the shaped article is at least 12% by weight, based on the total weight of the shaped article.
7 . The shaped article according to claim 3 , wherein the lime comprises between 11% and 70% by weight of the shaped article, based on the total weight of the shaped article.
8 . The shaped article according to claim 7 , wherein the lime comprises between 11% and 50% by weight of the shaped article, based on the total weight of the shaped article.
9 . The shaped article according to claim 8 , wherein the lime comprises between 11% and 20% by weight of the shaped article, based on the total weight of the shaped article.
10 . The shaped article according to claim 1 , wherein the calcium hypochlorite contains hydrated water up to 25% by weight, based on the total weight of the calcium hypochlorite.
11 . The shaped article according to claim 10 , wherein the calcium hypochlorite contains hydrated water between 5 and 16% by weight, based on the total weight of the calcium hypochlorite.
12 . The shaped article according to claim 1 , wherein the calcium hypochlorite contains hydrated water between 5 and 16% by weight, based on the total weight of the calcium hypochlorite, and the lime comprises calcium hydroxide, and the calcium hydroxide comprises between 11% and 30% by weight based on the total weight of the shaped article.
13 . The shaped article according to claim 1 , further comprising additives in amounts up about 30% by weight, based on the total weight of the shaped article.
14 . The shaped article according to claim 13 wherein the additive comprises magnesium sulfate, water soluble zinc salts or hydrates of zinc salts, scale inhibiting agent, pigments, dyes, binders, lubricants, color-containing salts and mixtures thereof.
15 . The shaped article according to claim 1 , in the form of tablets, bricks, briquettes, pellets, or an extrusion.
16 . The shaped article according to claim 1 , having a total weight between 1 and 500 grams.
17 . A method of treating water, said method comprising
(i) providing a shaped article formed from a composition comprising a blend of calcium hypochlorite and lime, wherein the total lime content in the shaped article is greater than 10% by weight, based on the total weight of the shaped article; and
(ii) contacting the shaped article with water to be treated.
18 . The method according to claim 17 , wherein the lime comprises calcium hydroxide, and the calcium hydroxide comprises between 11% and 30% by weight based on the total weight of the shaped article.
19 . The method of claim 18 , wherein the shaped article is contacted with the water to be treated by placing the shaped article in a skimmer of a swimming pool.
20 . The method of claim 17 , wherein the shaped article is contacted with the water to be treated by placing the shaped article in a chlorine feeder and the water to be treated is contacted with the shaped article within the chlorine feeder.
21 . The method of claim 17 , wherein the shaped article is contacted with the water to be treated by placing the shaped article in a floater which floats in the water to be treated, and water enters the floater to contact the shaped article.
22 . A method of manufacturing the shaped article comprising a blend of calcium hypochlorite and lime, wherein the lime is present in an amount greater than 10% by weight, based on the total weight of the blend, said method comprising dry blending calcium hypochlorite with lime to form a blend, and compressing the blend into the shaped article.
23 . The method according to claim 22 , wherein the calcium hypochlorite and the lime are each in form of free flowing particles.