IP Library Granted Patent US 9,914,643
Granted Patent B2
US 9,914,643 · App. 15/155,715 · Granted Mar 13, 2018

Incremental hydrogen production from an existing steam/natural gas reformer

Inventor: Rodney J. Allam (Chippenham, GB)
Assignee: GTLpetrol Holding Co. LLC
C01B3/56B01D53/002B01D53/047B01D2257/108B01D2257/504B01D2257/80C01B2203/0205C01B2203/042C01B2203/0475C01B2203/0495C01B2203/147
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Quick Facts
Patent No.
US 9,914,643
App. No.
15/155,715
Granted
Mar 13, 2018
Kind
B2
Abstract

In some aspects, a method for incremental hydrogen production includes separating in a first Pressure Swing Absorption (PSA) system an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream. The first waste stream is compressed to at least 40 bar to produce a compressed waste stream. Water is removed from the compressed waste stream to produce a dried waste stream. Carbon dioxide is removed from the dried waste stream to produce a remaining waste stream, and the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream. A second PSA system separates the remaining waste stream into a second hydrogen stream and a second waste stream, and the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream.

Claims (14)

1. A method for incremental hydrogen production, comprising:

separating in a first Pressure Swing Absorption (PSA) system an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream;

compressing the first waste stream to at least 40 bar to produce a compressed waste stream;

removing water from the compressed waste stream to produce a dried waste stream;

removing carbon dioxide from the dried waste stream to produce a remaining waste stream, wherein the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream;

separating in a second PSA system the remaining waste stream into a second hydrogen stream and a second waste stream, wherein the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream; and

passing the second waste stream to a reformer furnace as fuel gas.

2. A system for incremental hydrogen production, comprising:

a first Pressure Swing Absorption (PSA) system configured to separate an existing reformer synthesis gas product stream into a first hydrogen stream and a first waste stream;

a compressor configured to compress the first waste stream to at least 40 bar to produce a compressed waste stream;

a drier configured to remove water from the compressed waste stream to produce a dried waste stream;

a low-temperature separator configured to remove carbon dioxide from the dried waste stream to produce a remaining waste stream, wherein the removed carbon dioxide is at least 85% of carbon dioxide in the existing reformer synthesis gas product stream;

a second PSA system configured to separate the remaining waste stream into a second hydrogen stream and a second waste stream, wherein the second hydrogen stream comprises at least 11% of hydrogen from the existing reformer synthesis gas product stream; and

a conduit configured to pass the second waste stream to a reformer furnace as fuel gas.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 24, 2018
From: GTLPETROL HOLDING CO. LLC
To: NIQUAN ENERGY LLC
Reel/Frame 047621/0953 →
Continuity (2)
Provisional Application 62162229 · May 15, 2015
Related Publication 20170101313A1 · Apr 13, 2017