IP Library Granted Patent US 10,842,147
Granted Patent B2
US 10,842,147 · App. 15/162,094 · Granted Nov 24, 2020

Surface disinfectant with residual biocidal property

Inventors: Tian Lan (Huntersville, NC); Samuel James Hanna (Charlotte, NC); Gina Parise Sloan (Statesville, NC); Brian Patrick Aylward (Concord, NC); Karen Terry Welch (Kannapolis, NC); Dennis Earl Shireman (Marion, AR); Kevin Andrew Kavchok (Charlotte, NC); Charles L. Hawes (Cordova, TN)
Assignees: Microban Products Company; W.M. Barr & Company, Inc.
A01N25/10A01N31/02A01N33/12A01N59/00A01N59/02
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Quick Facts
Patent No.
US 10,842,147
App. No.
15/162,094
Granted
Nov 24, 2020
Kind
B2
Abstract

A biofilm sealant is provided imparting a residual biocidal property. The biofilm sealant is used to treat a surface to impart a film having a capacity to quickly kill bacteria and other germs for at least 24 hours after deposit of the film on a treated surface. The disinfectant formulation biofilm sealant comprises a polymer binder, wherein the polymer binder is an oxazoline homopolymer or an extended or a modified polymer based on an oxazoline homopolymer, and a biocidal compound.

Claims (34)

1. A biocidal composition comprising:

a polyoxazoline present in a range of 0.2% to 4% based on the weight of the disinfectant formulation, the polyoxazoline having a structure of

wherein: R 1 is methyl; R 2 is hydroxyl; R 3 is ethyl; and n=10 to 1,000,000, and

a quaternary ammonium compound or a mixture of quaternary ammonium compounds present in a range of 0.3% to 4% based on the weight of the disinfectant formulation,

the quaternary ammonium compound (QAC) having the molecular structure of:

wherein

R 1 is methyl;

R 2 is alkyl C8-10; methyl-benzyl; or ethyl-benzyl;

R 3 is methyl;

R 4 is alkyl C8-18; and

X − is chloride, or carbonate/bicarbonate;

wherein the biocidal composition is a biofilm sealant.

2. The biocidal composition according to claim 1 , wherein the polyoxazoline is prepared with a monomer of ethyloxazoline.

3. The biocidal composition according to claim 2 , wherein ethyloxazoline is copolymerized with a heterocyclic monomer.

4. The biocidal composition according to claim 1 , wherein the disinfectant formulation is in a form of a liquid.

5. The biocidal composition according to claim 1 , wherein the quaternary ammonium compound is present in a composition comprising: N-alkyl dimethyl benzyl ammonium chloride, N-octyl decyl dimethyl ammonium chloride, di-n-decyl dimethyl ammonium chloride, and di-n-octyl dimethyl ammonium chloride.

6. A biocidal composition comprising:

a polyoxazoline present in a range of 0.2% to 4% based on the weight of the disinfectant formulation, the polyoxazoline having a structure of

wherein: R 1 is methyl; R 2 is hydroxyl; R 3 is ethyl; and n=10 to 1,000,000,

a quaternary ammonium compound or a mixture of quaternary ammonium compounds present in a range of 0.3% to 4% based on the weight of the disinfectant formulation, and

wherein the composition is a biofilm sealant having a residual biocidal property and

the quaternary ammonium compound (QAC) has a molecular structure of:

wherein

R 1 is methyl;

R 2 is alkyl C8-10; methyl-benzyl; or ethyl-benzyl;

R 3 is methyl;

R 4 is alkyl C8-18; and

X − is chloride, or carbonate/bicarbonate.

7. The biocidal composition according to claim 5 , wherein the biocidal composition comprises: 40 weight % of N-alkyl dimethyl benzyl ammonium chloride, 30 weight % of N-octyl decyl dimethyl ammonium chloride, 15 weight % of di-n-decyl dimethyl ammonium chloride, and 15 weight % of di-n-octyl dimethyl ammonium chloride, wherein the percentage is a weight percentage of individual quaternary ammonium compounds based on the total weight of the quaternary ammonium compounds within the composition.

8. The biocidal composition according to claim 1 , further comprising a carrier comprised of a solvent or a mixture of solvents.

9. The biocidal composition according to claim 8 , wherein the solvent or mixture of solvents comprise water, a low molecular weight alcohol, alkylene glycol ether, a terpene or terpene derivative, and a combination thereof.

10. The biocidal composition according to claim 9 , wherein the alcohol is present in an amount of at least 10%.

11. The biocidal composition according to claim 1 , further comprising a surfactant or a wetting agent.

12. The biocidal composition according to claim 11 , wherein the surfactant is present in a range of 0.01% to 2%.

Assignments (5)
SECURITY INTEREST Recorded Dec 10, 2025
From: MICROBAN PRODUCTS COMPANY
To: FIFTH THIRD BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 073176/0547 →
NUNC PRO TUNC ASSIGNMENT Recorded Jan 26, 2023
From: W.M. BARR & COMPANY
To: MICROBAN PRODUCTS COMPANY
Reel/Frame 062498/0718 →
PATENT COLLATERAL AGREEMENT Recorded Jul 12, 2018
From: W.M. BARR & COMPANY, INC.
To: FIFTH THIRD BANK, AS AGENT
Reel/Frame 046567/0311 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 25, 2016
From: LAN, TIAN; AYLWARD, BRIAN PATRICK; HANNA, SAMUEL JAMES; SLOAN, GINA PARISE; WELCH, KAREN TERRY
To: MICROBAN PRODUCTS COMPANY
Reel/Frame 038714/0337 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 25, 2016
From: SHIREMAN, DENNIS EARL; KAVCHOK, KEVIN ANDREW; HAWES, CHARLES L.
To: W. M. BARR & COMPANY, INC.
Reel/Frame 038714/0396 →
Continuity (5)
Continuation In Part 14949046 · Nov 23, 2015
Provisional Application 62084917 · Nov 26, 2014
Provisional Application 62127075 · Mar 2, 2015
Provisional Application 62166403 · May 26, 2015
Related Publication 20160262383A1 · Sep 15, 2016