Low-B bare earth magnet
The present invention discloses a low-B rare earth magnet. The rare earth magnet contains a main phase of R 2 T 14 B and comprises the following raw material components: 13.5 at %˜4.5 at % of R, 5.2 at %˜5.8 at % of B, 0.3 at %˜0.8 at % of Cu, 0.3 at %˜3 at % of Co, and the balance being T and inevitable impurities, the R being at least one rare earth element comprising Nd, and the T being an element mainly comprising Fe. 0.3˜0.8 at % of Cu and an appropriate amount of Co are co-added into the rare earth magnet, so that three Cu-rich phases formed in the grain boundary, and the magnetic effect of the three Cu-rich phases existing in the grain boundary and the solution of the problem of insufficient B in the grain boundary can obviously improve the squareness and heat-resistance of the magnet.
1. A low-B rare earth magnet containing a main phase of R 2 T 14 B and comprising the following raw material components:
13.5 at %˜14.5 at % of R,
5.2 at %˜5.8 at % of B,
0.3 at %˜0.8 at % of Cu,
0.3 at %˜3 at % of Co, and
a balance being T and inevitable impurities, wherein:
the R is at least one rare earth element comprising Nd, and
the T is an element mainly comprising Fe the T further comprises X,
the X is at least three elements selected from Al, Si, Ga, Sn, Ge, Ag, Au, Bi, Mn, Cr, P or S, and
a total composition of the X is 0 at %-1.0 at %.
2. The low-B rare earth magnet according to claim 1 , wherein:
and
in the inevitable impurities, an amount of O is below 1 at %, an amount of C is below 1 at % and an amount of N is below 0.5 at %.
3. The low-B rare earth magnet according to claim 1 , wherein the low-B rare earth magnet is manufactured by the following processes:
a process of preparing an alloy for rare earth magnet with molten rare earth magnet components;
processes of producing a fine powder by coarsely crushing and finely crushing the alloy for rare earth magnet; and
processes of obtaining a compact by a magnetic field compacting method, sintering the compact in a vacuum or inert gas at a temperature of 900° C.˜1100° C., and forming a first Cu crystal phase, a second Cu crystal phase and a third Cu crystal phase in a grain boundary of the low-B rare earth magnet, wherein:
a molecular composition of the first Cu crystal phase is a phase of RT 2 series,
a molecular composition of the second Cu crystal phase is a phase of R 6 T 13 X series,
a molecular composition of the third Cu crystal phase is a phase of RT 5 series, and
a total content of the first Cu crystal phase and the second Cu crystal phase is over 65 volume % of the grain boundary.
4. The low-B rare earth magnet according to claim 3 , wherein the low-B rare earth magnet is a magnet of Nd—Fe—B series with a maximum magnetic energy product over 43 MGOe.
5. The low-B rare earth magnet according to claim 1 , wherein:
the total composition of the X is 0.3 at %˜1.0 at %.
6. The low-B rare earth magnet according to claim 5 , wherein an amount of Dy, Ho, Gd or Tb is below 1 at % of the R.
7. The low-B rare earth magnet according to claim 5 , wherein:
the X comprises Ga, and
an amount of Ga is 0.1 at %˜0.2 at %.
8. The low-B rare earth magnet according to claim 5 , wherein oxygen content of the low-B rare earth magnet is below 0.6 at %.
9. A low-B rare earth magnet containing a main phase of R 2 T 14 B and comprising the following raw material components:
13.5 at %˜14.5 at % of R,
5.2 at %˜5.8 at % of B,
0.3 at %˜0.8 at % of Cu,
0.3 at %˜3 at % of Co, and
a balance being T and inevitable impurities, wherein:
the R is at least one rare earth element comprising Nd,
the T is an element mainly comprising Fe the T further comprises X,
the X is at least three elements selected from Al, Si, Ga, Sn, Ge, Ag, Au, Bi, Mn, Cr, P or S, and
a total composition of the X is 0 at %-1.0 at %, and
the low-B rare earth magnet is manufactured by the following processes:
a process of preparing an alloy for rare earth magnet with molten rare earth magnet components;
processes of producing a fine powder by coarsely crushing and finely crushing the alloy for rare earth magnet; and
processes of obtaining a compact by a magnetic field compacting method, sintering the compact in a vacuum or inert gas at a temperature of 900° C.˜1100° C., forming a first Cu crystal phase, a second Cu crystal phase and a third Cu crystal phase in a grain boundary of the low-B rare earth magnet, and performing RH grain boundary diffusion at a temperature of 700° C.˜1050° C., wherein:
a molecular composition of the first Cu crystal phase is a phase of RT 2 series,
a molecular composition of the second Cu crystal phase is a phase of R 6 T 13 X series,
a molecular composition of the third Cu crystal phase is a phase of RT 5 series, and
a total content of the first Cu crystal phase and the second Cu crystal phase is over 65 volume % of the grain boundary.
10. The low-B rare earth magnet according to claim 9 , wherein:
the RH is selected from Dy, Ho or Tb,
and
in the inevitable impurities, an amount of O is controlled below 1 at %, an amount of C is controlled below 1 at % and an amount of N is controlled below 0.5 at %.
11. The low-B rare earth magnet according to claim 9 , wherein the low-B rare earth magnet is further manufactured using an aging treatment comprising treating the magnet after the RH grain boundary diffusion at a temperature of 400° C.˜650° C.
12. The low-B rare earth magnet according to claim 10 , wherein the low-B rare earth magnet is further manufactured using an aging treatment comprising treating the magnet after the RH grain boundary diffusion at a temperature of 400° C.˜650° C.