Composite color particles
The present invention is directed to a display fluid comprising charged composite color particles dispersed in a solvent. The composite color particle comprises core particles which are at least one color core particle and at least one core particle having a high refractive index, a shell in which the color core particles and the high refractive index core particles are completely or partially embedded, and steric stabilizer molecules on the surface of the composite color particle. A display fluid comprising the composite color particles of the present invention provides improved optical performance.
1. A composite color particle comprising:
a) at least one color core particle which is non-white and non-black;
b) at least one white core particle comprising TiO 2 ;
c) a shell in which the color core particle and the white core particle are completely or partially embedded, wherein the weight ratio of the color core particles to the white core particles is about 1:2 to 5:1; and
d) steric stabilizers on the surface of the composite color particle.
2. The composite color particle of claim 1 , wherein the refractive index of the color core particle is lower than that of the white core particle.
3. The composite color particle of claim 1 , wherein the color core particle is red, green, blue, yellow, magenta or cyan.
4. The composite color particle of claim 1 , wherein the color core particle comprises an organic pigment.
5. The composite color particle of claim 1 , wherein the color core particle comprises an inorganic pigment.
6. The composite color particle of claim 1 , wherein the white core particle has a size in the range of 10 nm to 500 nm.
7. The composite color particle of claim 1 , wherein there is more than one type of color core particle and the different types of color core particles are of different colors.
8. The composite color particle of claim 1 , wherein the weight ratio of the color core particles to the white core particles is about 1:1 to 3:1.
9. The composite color particle of claim 1 , wherein the shell is formed of polyacrylate, polyurethane, polyurea, polyethylene, polyester or polysiloxane.
10. The composite color particle of claim 1 , wherein the shell is formed from styrene, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, vinyl pyridine, n-vinyl pyrrolidone, 2-hydoxyethyl acrylate, 2-hydroxyethyl methacrylate or dimethylaminoethyl methacrylate.
11. The composite color particle of claim 1 , wherein the steric stabilizer is formed of high molecular weight polymers.
12. The composite color particle of claim 1 , wherein the steric stabilizer is formed of polyethylene, polypropylene, polyester, polysiloxane or a mixture thereof.
13. The composite color particle of claim 1 , wherein the refractive index of the composite color particle is between 1.5 and 2.5 at 589 nm.
14. An electrophoretic fluid comprising the composite color particles of claim 1 dispersed in a solvent or solvent mixture.
15. An electrophoretic display device comprising an electrophoretic fluid of claim 14 sandwiched between two electrode layers.