Cover glass for light emitting diode package, sealed structure, and light emitting device
To provide a cover glass for light emitting diode package, which is capable of preventing deterioration in transmittance characteristics during use for a long period of time, and a light emitting device. The cover glass for light emitting diode package has a basic composition comprising, by mass % as calculated as oxides, from 55 to 80% of SiO 2 , from 0.5 to 15% of Al 2 O 3 , from 5 to 25% of B 2 O 3 , from 0 to 7% of Li 2 O, from 0 to 15% of Na 2 O, from 0 to 10% of K 2 O (provided Li 2 O+Na 2 O+K 2 O=from 2 to 20%), from 0 to 0.1% of SnO 2 and from 0.001 to 0.1% of Fe 2 O 3 , it does not substantially contain As 2 O 3 , Sb 2 O 3 and PbO, and it has an average thermal expansion coefficient of from 45 to 70×10 −7 /° C. in a temperature range of from 0 to 300° C.
1. A cover glass, consisting essentially of, by mass % as calculated as oxides:
from 55 to 80% of SiO 2 ;
from 0.5 to 15% of Al 2 O 3 ;
from 5 to 25% of B 2 O 3 ;
from 0 to 7% of Li 2 O;
from 0 to 15% of Na 2 O;
from 0 to 10% of K 2 O, with the proviso that Li 2 O+Na 2 O+K 2 O=from 2 to 20%;
from 0 to 2% TiO 2 ;
from 0 to 0.1% of SnO 2 ; and
from 0.001 to 0.1% of Fe 2 O 3 ,
wherein the cover glass has an average thermal expansion coefficient of from 45 to 70><10 −7 /° C. in a temperature range of from 0 to 300° C.
2. The cover glass according to claim 1 , consisting essentially of, by mass % as calculated as oxides:
from 55 to 80% of SiO 2 ,
from 0.5 to 15% of Al 2 O 3 ,
from 5 to 25% of B 2 O 3 ,
from 0 to 7% of Li 2 O,
from 0 to 15% of Na 2 O,
from 0 to 10% of K 2 O, with the proviso that Li 2 O+Na 2 O+K 2 O=from 2 to 20%;
from 0 to 2% TiO 2 ;
from 0 to 0.1% of SnO 2 ; and
from 0.003 to 0.1% of Fe 2 O 3 ,
wherein the cover glass has an average thermal expansion coefficient of from 45 to 70×10 −7 /° C. in a temperature range of from 0 to 300° C.
3. The cover glass according to claim 1 , wherein the transmittance at a wavelength of 365 nm in a thickness of 1 mm is at least 85%.
4. The cover glass according to claim 1 , wherein the average transmittance at a wavelength of from 808 to 1,064 nm in a thickness of 1 mm is at least 85%.
5. The cover glass according to claim 1 , wherein the refractive index (nd) is at most 1.52.
6. A sealed structure having a cover glass and a light emitting diode package bonded to each other, wherein a light emitting diode package and the cover glass according to claim 1 are bonded.
7. A sealed structure having a cover glass and a light emitting diode package bonded to each other, wherein the light emitting diode package comprises a glass ceramic substrate obtained by firing a glass ceramic composition comprising a glass powder and a ceramic filler, and the glass ceramic substrate and the cover glass according to claim 1 are bonded.
8. The sealed structure according to claim 6 , wherein the cover glass is bonded to the light emitting diode package via a low melting point glass which is melted by laser irradiation.
9. A light emitting device, comprising a cover glass according to claim 1 , a light emitting diode package having a light emitting diode mounted thereon, and a sealing material comprising a low melting point glass which is melted by laser irradiation to bond the cover glass and the light emitting diode package.
10. The light emitting device according to claim 9 , wherein the sealing material comprises the low melting point glass and an inorganic filler.
11. The light emitting device according to claim 10 , wherein the inorganic filler is at least one member selected from the group consisting of a low-expansion filler and an electromagnetic wave absorbing material.
12. The light emitting device according to claim 9 , wherein the difference in average thermal expansion coefficient in a temperature range of from 25 to 300° C. between the light emitting diode package and the cover glass is at most 20×10 −7 /° C.
13. The light emitting device according to claim 9 , wherein the light emitting diode package comprises a glass ceramic substrate obtained by firing a glass ceramic composition comprising a glass powder and a ceramic filler, and between the average thermal expansion coefficient in a temperature range of from 25 to 300° C. of the glass ceramic substrate and the average thermal expansion coefficient in a temperature range of from 25 to 300° C. of the cover glass, there is a relation of “the average thermal expansion coefficient of the glass ceramic substrate”≧“the average thermal expansion coefficient of the cover glass”.
14. The cover glass according to claim 1 , wherein the amount of SnO 2 is from 0 to 0.002%.