IP Library Granted Patent US 10,081,850
Granted Patent B2
US 10,081,850 · App. 15/177,455 · Granted Sep 25, 2018

Treatment method for solution containing metal ions using cation adsorbent

Inventors: Akira Sato (Yokohama, JP); Daisuke Fukushi (Yokohama, JP); Takao Kusaka (Yokohama, JP); Kayo Nakano (Yokohama, JP); Yukiko Inui (Yokohama, JP); Akito Sasaki (Yokohama, JP)
Assignees: Kabushiki Kaisha Toshiba; Toshiba Materials Co., Ltd.
C22B26/10B01D15/36B01D21/01B01J20/06B01J20/28004B01J20/28016B01J20/28057B01J20/28059B01J20/28061B01J20/28064B82Y30/00C01G41/02C02F1/281C02F1/5272G21F9/12G21F9/125C01P2004/64C01P2006/12C02F2101/006C02F2101/10C02F2101/20C02F2103/08
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Quick Facts
Patent No.
US 10,081,850
App. No.
15/177,455
Granted
Sep 25, 2018
Kind
B2
Abstract

A cation adsorbent of an embodiment includes tungsten oxide particles having a BET specific surface area in a range of 0.82 m 2 /g or more and 820 m 2 /g or less. The cation adsorbent is added to a solution to be treated containing cations being recovery objects, and the cation adsorbent adsorbing the cations is precipitated. The generated precipitate is separated from the solution to recover the cations.

Claims (16)

1. A treatment method of a solution, comprising:

adding a cation adsorbent comprising tungsten oxide particles having a BET specific surface area in a range of 0.82 m 2 /g or more and 820 m 2 /g or less to a solution to be treated containing cations being recovery objects to let the cation adsorbent adsorb the cations;

precipitating the cation adsorbent adsorbing the cations to obtain precipitate; and

separating the precipitate from the solution to recover the cations,

wherein the cation is at least one ion selected from the group consisting of a cesium (Cs) ion, a strontium (Sr) ion, an iodine (I) ion, and a lithium (Li) ion.

2. The treatment method of the solution according to claim 1 , further comprising:

preparing a dispersion liquid by dispersing the cation adsorbent in an aqueous dispersion medium,

wherein the dispersion liquid containing the cation adsorbent is added to the solution.

3. The treatment method of the solution according to claim 1 ,

wherein the solution in which the cation adsorbent is added or the precipitate is treated by using an organic coagulant.

4. The treatment method of the solution according to claim 1 ,

wherein the solution contains a sodium (Na) ion together with the cation.

5. The treatment method of the solution according to claim 1 ,

wherein the solution contains at least one ion selected from the group consisting of a magnesium (Mg) ion, a calcium (Ca) ion, and a potassium (K) ion together with the cation.

6. The treatment method of the solution according to claim 1 ,

wherein the solution is seawater containing the cesium (Cs) ion, and an adsorption ration of the cesium (Cs) ion by the cation adsorbent is 90% or more.

Assignments (3)
NUNC PRO TUNC ASSIGNMENT Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MATERIALS CO. LTD.
Reel/Frame 074940/0511 →
CHANGE OF NAME Recorded Feb 19, 2026
From: TOSHIBA MATERIALS CO. LTD.
To: NITERRA MATERIALS CO., LTD.
Reel/Frame 074941/0803 →
CHANGE OF ADDRESS Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: KABUSHIKI KAISHA TOSHIBA
Reel/Frame 074941/0846 →
Priority Claims (1)
JP 2011-182032 · Aug 23, 2011 · national
Continuity (3)
Division 14182806 · Feb 18, 2014
Continuation PCTJP2012005275 · Aug 23, 2012
Related Publication 20160289794A1 · Oct 6, 2016