Toner formulation and method of preparing the same
A chemically prepared toner composition made up of a toner particle with a core having a first polymer binder, a monomer free radical polymerization formed core shell styrene acrylic latex having a liquid gel core, a pigment, a wax, and a shell formed around the core including a second polymer binder and method to make the same is disclosed. An optional borax coupling agent can be placed between the outer surface of the core and the shell to assist in the binding of the polymer found in the shell onto the surface of the toner core containing the first polymer.
1. A chemically prepared toner composition, comprising:
a core including a first polymer binder, a core shell latex having a liquid gel core including a monomer, a cross linking agent, a chain transfer agent and a plasticizing oil, a pigment, and a wax; and
a shell formed around the core including a second polymer binder.
2. The chemically prepared toner of claim 1 , wherein the monomer in the core shell latex includes a hydrophilic monomer having carboxyl (—COOH) and hydroxy (—OH) functional groups and a hydrophobic monomer having styrene and acrylate functionality.
3. The chemically prepared toner of claim 2 , wherein the hydrophobic monomer having acrylate functionality is an alkyl acrylate.
4. The chemically prepared toner of claim 3 , wherein the alkyl acrylate monomer is lauryl acrylate.
5. The chemically prepared toner of claim 2 , wherein the hydrophilic monomers having carboxyl (—COOH) and hydroxy (—OH) functional groups are hydroxyethyl methacrylate and beta-carboxyethyl acrylate.
6. The chemically prepared toner of claim 1 , wherein the plasticizing oil is a hydrocarbon oil having 10 or more carbons.
7. The chemically prepared toner of claim 1 , wherein the glass transition temperature (Tg) of the core shell latex is between 20° C. and 60° C.
8. The chemically prepared toner of claim 1 , wherein the first polymer binder and the second polymer binder each include a polyester resin.
9. The chemically prepared toner composition of claim 8 , wherein the first polymer binder includes a first polyester resin or mixture and the second polymer binder includes a second polyester resin or mixture different from the first polyester resin or mixture.
10. The chemically prepared toner of claim 1 , further comprising a borax coupling agent between the outer surface of the core and the shell.