NdFeB system sintered magnet
A NdFeB system sintered magnet produced by the grain boundary diffusion method and has a high coercive force and squareness ratio with only a small decrease in the maximum energy product. A NdFeB system sintered magnet having a base material produced by orienting powder of a NdFeB system alloy and sintering the powder, with Dy and/or Tb (the “Dy and/or Tb” is hereinafter called R H ) attached to and diffused from a surface of the base material through the grain boundary inside the base material by a grain boundary diffusion treatment, wherein the difference C gx −C x between the R H content C gx (wt %) in the grain boundary and the R H content C x (wt %) in main-phase grains which are grains constituting the base material at the same depth within a range from the surface to which R H is attached to a depth of 3 mm is equal to or larger than 3 wt %.
1. A NdFeB system sintered magnet comprising:
main-phase grains; and
a rare-earth rich phase containing Dy and/or Tb at a grain boundary of the main-phase grains, the Dy and/or Tb being referred to as R H ,
wherein a difference C gx −C x between an R H content C gx in the grain boundary and an R H content C x in the main-phase grains at a same depth within a range from a surface to a depth of 3 mm is equal to or larger than 3 wt %,
wherein a thickness of the NdFeB system sintered magnet is from equal to or greater than 6 mm to equal to or smaller than 10 mm, and
wherein a squareness ratio of the NdFeB system sintered magnet is equal to or greater than 95.0% and equal to or smaller than 96.2%.
2. The NdFeB system sintered magnet according to claim 1 ,
wherein a carbon content of the NdFeB system sintered magnet is higher than 0 ppm and equal to or lower than 1000 ppm.
3. The NdFeB system sintered magnet according to claim 1 ,
wherein an average grain size of the main-phase grains is equal to or smaller than 4.5 μm.
4. The NdFeB system sintered magnet according to claim 1 ,
wherein a percentage of a grain-boundary triple point at which the R H content difference between the grain-boundary triple point and a two-grain boundary portion leading to the grain-boundary triple point is equal to or lower than 3% exceeds 60%.
5. A NdFeB system sintered magnet comprising:
main-phase grains; and
a rare-earth rich phase containing Dy and/or Tb at a grain boundary of the main-phase grains, the Dy and/or Tb being referred to as R H ,
wherein a difference C gx −C x between an RH content C gx in the grain boundary and an R H content C x in the main-phase grains at a same depth within a range from a surface to a depth of 3 mm is equal to or larger than 3 wt %,
wherein a thickness of the NdFeB system sintered magnet is from equal to or greater than 6 mm to equal to or smaller than 10 mm, and
wherein a percentage of a grain-boundary triple point at which the R H content difference between the grain-boundary triple point and a two-grain boundary portion leading to the grain-boundary triple point is equal to or lower than 3% exceeds 60%.
6. The NdFeB system sintered magnet according to claim 5 ,
wherein a carbon content of the NdFeB system sintered magnet is higher than 0 ppm and equal to or lower than 1000 ppm.
7. The NdFeB system sintered magnet according to claim 5 ,
wherein an average grain size of the main-phase grains is equal to or smaller than 4.5 μm.