Polylactide fibers
View Patent ↗Polylactide fibers are made from a blend of polylactides. One of the polylactides has a ratio of R-lactic and S-lactic units from 8:92 to 92:8. The second polylactide has a ratio of the R-lactic and S-lactic units of ≥97:3 or ≤3:97. The ratio of the R-lactic units to S-lactic units in the blend is from 7:93 to 25:75 or from 75:25 to 93:7. The polylactide fiber contains at least 5 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
1. A polylactide fiber that contains at least 75% by weight polylactide resin, wherein
(a) the polylactide resin is a blend formed by melt blending, solution blending or both melt blending and solution blending (1) 20 to 90% by weight of a first polylactide in which the ratio of the R-lactic and S-lactic units is from 50:50 to 10:90 and (2) from 80 to 10% by weight of a second polylactide in which the ratio of the R-lactic and S-lactic units is ≤3:97, and wherein the R-lactic units and S-lactic units combined constitute at least 90% of the weight of the second polylactide
(b) the ratio of the R-lactic units to S-lactic units in the blend is from 8:92 to 20:80; and
(c) the polylactide fiber contains at least 5 up to 30 Joules of polylactide crystallites having a melting temperature of 140° C. to 190° C. per gram of polylactide resin in the fiber and no more than 5 J/g of other crystallites that melt in the temperature range of 20° C. to 250° C.
2. The fiber of claim 1 , wherein the blend of polylactide resins contains about 15 to 50 milliequivalents of carboxyl end groups per kilogram of polylactide resins.
3. The fiber of claim 2 , wherein the first polylactide resin has a weight average molecular weight from 40,000 to 125,000.
4. The fiber of claim 3 , which contains at least 10 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
5. The fiber of claim 4 , which contains 12 to 22 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
6. The fiber of claim 1 , which loses 7 to 20% of its mass upon immersing 0.48 g of the fiber in 100 mL of a 0.1 M phosphate buffer solution for 6 days at 65° C.
7. The fiber of claim 6 , which exhibits 5 to 25% shrinkage when heated in air at 80° C. for 10 minutes.
8. The fiber of claim 1 , which contains an agent that increases the hydrophilicity of the polylactide resin, or a catalyst for the hydrolysis of the polylactide resin, or both.
9. A plant covering comprising the fiber of claim 1 .
10. A blend of polylactide resins formed by melt blending, solution blending or both melt blending and solution blending (1) 20 to 90% by weight of a first polylactide in which the ratio of the R-lactic and S-lactic units is from 50:50 to 10:90 and (2) from 80 to 10% by weight of a second polylactide in which the ratio of the R-lactic and S-lactic units is ≤3:97, and wherein the R-lactic units and S-lactic units combined constitute at least 90% of the weight of the second polylactide, wherein the ratio of the R-lactic units to S-lactic units in the blend is from 8:92 to 20:80.