Process for fabricating polymeric articles
A process for the production of a polymeric article directed to (a) forming a ply having successive layers, namely, (i) a first layer made up of strands of an oriented polymer material; (ii) a second layer of a polymeric material; (iii) a third layer made up of strands of an oriented polymeric material, wherein the second layer has a lower peak melting temperature that of the first and third layers; (b) subjecting the ply to conditions of time, temperature, and pressure sufficient to melt a proportion of the firsts layer to melt the second layer entirely, and to melt a proportion of the third layer, and to compact the ply; and (c) cooling the compacted ply. The resultant articles have good mechanical properties yet may be made at a lower compaction temperature than articles not employing the second layer, leading to a more controllable manufacturing process.
1. A non-planar polymeric article comprising a ply of at least three layers wherein a portion of first and third layers and substantially all of second layer has been melted and wherein the first and third layers of the ply comprise the same type of polymer and the second layer comprises a polymer with the same chemical composition and grade of polymers as the first and third layers with a lower degree of molecular orientation and a lower melting temperature than that of the first and third layers, wherein the first and third layers comprise a thickness of greater than 5 μm but not exceeding 1 mm, and wherein the second layer comprises a thickness of at least 5 μm but not exceeding 100 μm.
2. The polymeric article of claim 1 wherein the first and third layers comprise polyethylene, polypropylene, polyoxymethylene, polyester, blends thereof, or mixtures thereof.
3. The polymeric article of claim 1 wherein the second layer has a melting temperature of at least 5° C. lower than a melting temperature of the first or third layers.
4. A composition comprising at least three distinct, successive layers of unmelted polymeric material wherein first and third layers comprise the same type of polymer and second layer comprises a polymer with the same chemical composition and grade of polymers as the first and third layers with a lower degree of molecular orientation and a lower melting temperature than that of the first and third layers, wherein the first and third layers comprise a thickness of greater than 5 μm but not exceeding 1 mm, and wherein the second layer comprises a thickness of at least 5 μm but not exceeding 100 μm.
5. The composition of claim 4 wherein a layer of unmelted polymeric material comprises a polymer selected from the group consisting of polyethylene, polypropylene, polyoxymethylene, polyester, blends thereof, and mixtures thereof.
6. The composition of claim 4 wherein the thickness of the second layer is less than that of either the first layer or the third layer.