Low temperature milling of inks for improved properties
This disclosure is directed to formulations for inks and methods for achieving those formulations for use in an emerging class of variable data digital lithographic image forming devices. Specific sub-system requirements that are unique to the emerging architecture caused an exploration of formula boundaries that, through experimentation, were determined to substantially reduce particle sizes for the color pigments enabling a higher latitude for ink image thickness. Experimentally-derived behavior in reducing particle size and adjusting rheological properties results when a inks are processed using a 3-roll mill with cooling employed. Inks demonstrated a preferably reduced preferred particle size distribution enabling a higher latitude for ink image thickness down to about 0.5 microns. Improved rheological profiles allow the inks to have higher zero-shear or static viscosity to be less runny and to allow more consistent flow into and through ink loaders and Anilox systems to a reimageable surface of an imaging member.
1. An ink composition useful for variable data digital lithographic printing, comprising:
an acrylate ink base formulation;
a pigment component; and
a clay component,
a slurry material comprising the acrylate ink base formulation, the pigment component, and the clay component;
wherein the acrylate ink base formulation, the pigment component, and the clay component are pulverized in a roll mill while at least one roll in the roll mill is actively cooled when processing the slurry material;
wherein the pulverizing renders an ink composition comprising ink particles with diameters in a range of 300 nm or less.
2. The ink composition of claim 1 , the acrylate ink base formulation comprising:
at least one of an acrylate monomer, oligomer or polymer, or a mixture thereof.
3. The ink composition of claim 2 , the acrylate ink base formulation further comprising:
a rheology modifying agent; and
a stabilizing agent.
4. The ink composition of claim 3 , further comprising at least one photoinitiator component.
5. The ink composition of claim 1 , the diameters of the ink particles being in a range of 100 nm to 300 nm.
6. The ink composition of claim 1 , the roll mill being a 3-roll mill comprising a feed roller at an input side, an apron roller at an output side and a center roller sandwiched between the feed roller and the apron roller,
each of the feed roller and the apron roller achieving a respective standard operating temperature in a pulverizing processing of a slurry material,
each of the feed roller and the apron roller being separately actively cooled to reduce a temperature of the respective each of the feed roller and the apron roller during the pulverizing.
7. The ink composition of claim 6 , the temperature of the feed roller being reduced by more than 6 degrees C. under the respective standard operating temperature for the feed roller.
8. The ink composition of claim 6 , the temperature of the feed roller being reduced by more than 12 degrees C. under the respective standard operating temperature for the feed roller.
9. The ink composition of claim 6 , the temperature of the apron roller being reduced by 10 degrees C. or more under the respective standard operating temperature for the apron roller.
10. The ink composition of claim 6 , the temperature of the apron roller being reduced by 15 degrees C. or more under the respective standard operating temperature for the apron roller.
11. A method for preparing an ink composition for use in digital printing, comprising:
preparing an acrylate ink base formulation;
dispersing at least a pigment component and a clay component in the acrylate ink base formulation to produce pigmented ink slurry;
pulverizing the slurry in a roll mill while at least one roll in the roll mill is actively cooled to reduce a temperature of the at least one roll during the pulverizing rendering ink particles with diameters in a range of 300 nm or less.
12. The method of claim 11 , the acrylate ink base formulation comprising:
at least one of an acrylate monomer, oligomer or polymer, or a mixture thereof.
13. The method of claim 12 , the acrylate ink base formulation further comprising:
a rheology modifying agent; and
a stabilizing agent.
14. The method of claim 13 , the slurry further comprising at least one photoinitiator component.
15. The method of claim 11 , the diameters of the ink particles being in a range of 100 nm to 300 nm.
16. The method of claim 11 , the roll mill being a 3-roll mill comprising a feed roller at an input side, an apron roller at an output side and a center roller sandwiched between the feed roller and the apron roller,
each of the feed roller and the apron roller achieving a respective standard operating temperature in a pulverizing processing of a slurry material,
the method further comprising actively cooling each of the feed roller and the apron roller separately to reduce a temperature of the respective each of the feed roller and the apron roller during the pulverizing.
17. The method of claim 16 , further comprising reducing the temperature of the feed roller by more than 6 degrees C. under the respective standard operating temperature for the feed roller.
18. The method of claim 16 , further comprising reducing the temperature of the feed roller y more than 12 degrees C. under the respective standard operating temperature for the feed roller.
19. The method of claim 16 , further comprising reducing the temperature of the apron roller by 10 degrees C. or more under the respective standard operating temperature for the apron roller.
20. The method of claim 16 , further comprising reducing the temperature of the apron roller by 15 degrees C. or more under the respective standard operating temperature for the apron roller.