Phenanthroline-based compound for organic electroluminescence device
The present invention discloses a phenanthroline-based compound and an organic EL device employing the compound as phosphorescent light emitting host material of a light emitting layer and/or electron transporting layer material and/or hole blocking layer material and/or a thermally activated delayed fluorescence (TADF) material of a light emitting layer which can display good performance.
1. A phenanthroline-based compound is represented by the following formula (1):
wherein A is selected from the group consisting of formula (2) to formula (8):
L represents a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heterarylene group having 3 to 30 ring carbon atoms, m represent an integer of 0 to 4, n represents an integer of 0 to 6, p represents an integer of 0 to 7, q represents an integer of 0 to 8, r represents an integer of 0 to 10, M represents a metal atom or a non-metal atom or group; X is a divalent bridge comprising atoms or groups selected from the group consisting of O, S, C(R 13 )(R 14 ), NR 15 and Si(R 16 )(R 17 ), Ar is selected from the group consisting of a substituted or unsubstituted aryl group having 6 to 30 carbon atoms and a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, R 1 to R 17 are independently selected from the group consisting of a hydrogen atom, a halide, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms and a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms.
2. The phenanthroline-based compound according to claim 1 , wherein L is represented by the following formula (9):
wherein X 5 to X 9 independently represents a nitrogen atom or C(R s ), and each R s represents a hydrogen, a halide, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.
3. The phenanthroline-based compound according to claim 1 , wherein M represents a metal atom selected from the group consisting of Li, Na, K and Yb.
4. The phenanthroline-based compound according to claim 1 , wherein M represents a non-metal atom or group bonded with oxygen, and the non-metal atom or group is selected from the group consisting of hydrogen and an alkyl group having 1 to 30 carbon atoms.
5. The phenanthroline-based compound according to claim 1 , wherein the compound is represented by one of the following formulas:
6. An organic electroluminescence device comprising a pair of electrodes consisting of a cathode and an anode, and between the pairs of electrodes comprising at least a light emitting layer, one or more layers of organic thin film layers, wherein at least one of the at least a light emitting layer and the one or more organic thin film layers comprises the phenanthroline-based compound with a general formula (1) according to claim 1 .
7. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer comprises the phenanthroline-based compound with a general formula (1) used as a phosphorescent host material.
8. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer comprises the phenanthroline-based compound with a general formula (1) used as a thermally activated delayed fluorescence host material.
9. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer comprises the phenanthroline-based compound with a general formula (1) used as a thermally activated delayed fluorescence dopant material.
10. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer comprises a phosphorescent dopant material.
11. The organic electroluminescent device according to claim 10 , wherein the phosphorescent dopant material is an iridium complex.
12. The organic electroluminescence device according to claim 6 , wherein the one or more organic thin film layers comprises the phenanthroline-based compound with a general formula (1) used as an electron transporting material.
13. The organic electroluminescence device according to claim 6 , wherein the one or more organic thin film layers comprises the phenanthroline-based compound with a general formula (1) used as a hole blocking material.
14. The organic electroluminescent device according to claim 6 , wherein the at least a light emitting layer comprises one of the compounds as the following formulas:
15. The organic electroluminescent device according to claim 6 , wherein the one or more organic thin film layers are one or more electron transporting layers or one or more hole blocking layers, and at least one of the one or more electron transporting layers and the one or more hole blocking layers comprises one of the compounds as the following formulas:
16. The organic electroluminescence device according to claim 15 , wherein the one or more electron transporting layer comprises lithium or 8-hydroxy-quinolinolato-lithium.
17. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer emits phosphorescent light selected from the group consisting of red, blue, green and yellow lights.
18. The organic electroluminescence device according to claim 6 , wherein the at least a light emitting layer emits thermally activated delayed fluorescent light selected from the group consisting of red, blue, green and yellow lights.
19. The organic electroluminescence device according to claim 6 , wherein the device is an organic light emitting device.
20. The organic electroluminescent device according to claim 6 , wherein the device is a lighting panel.
21. The organic electroluminescent device according to claim 6 , wherein the device is a backlight panel.