IP Library Granted Patent US 9,790,373
Granted Patent B2
US 9,790,373 · App. 15/215,369 · Granted Oct 17, 2017

Indirect printing apparatus employing sacrificial coating on intermediate transfer member

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Quick Facts
Patent No.
US 9,790,373
App. No.
15/215,369
Granted
Oct 17, 2017
Kind
B2
Abstract

A sacrificial coating composition for an image transfer member in an aqueous ink imaging system. The sacrificial coating composition includes a latex having polymer particles dispersed in a continuous liquid phase; at least one hygroscopic material; at least one surfactant; and water.

Claims (32)

1. A sacrificial coating composition for an image transfer member in an aqueous ink imaging system, comprising:

a latex comprising polymer particles dispersed in a continuous liquid phase, the latex comprising a styrene/n-butyl acrylate/methacrylic acid terpolymer;

at least one hygroscopic material;

at least one surfactant; and

water.

2. A sacrificial coating composition for an image transfer member in an aqueous ink imaging system, comprising:

a latex comprising polymer particles dispersed in a continuous liquid phase, the polymers in the latex having a glass transition temperature ranging from about −45° C. to about 100° C., a weight average molecular weight ranging from about 3000 to about 300,000, and a particle size ranging from 50 nm to 300 nm;

at least one hygroscopic material;

at least one surfactant; and

water.

3. The sacrificial coating composition of claim 2 , wherein the polymer particles comprise one or more repeating polymeric units selected from the group consisting of acrylic acid units, acrylate units, methacrylic acid units, methacrylate units, diene units, aliphatic nitrile units, vinyl ether units, vinyl ester units, vinyl ketone units, vinylidene halide units, vinyl substituted heterocyclic amine units, acrylamide units, methacrylamide units, vinyl substituted aromatic hydrocarbon units, vinyl halide units and alkene units.

4. The sacrificial coating composition of claim 2 , wherein the latex comprises one or more acrylic resins made from at least one monomer selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, methacrylic acid and acrylic acid.

5. The sacrificial coating composition of claim 2 , wherein the polymer particles comprise polyvinyl acetate copolymer.

6. The sacrificial coating composition of claim 2 , wherein the hygroscopic material is a polyol.

7. The sacrificial coating composition of claim 2 , wherein the at least one hygroscopic material is selected from the group consisting of glycerol, sorbitol, vinyl alcohol, xylitol, maltito, polymeric polyols, glyceryl triacetate, urea and alpha-hydroxy acids (AHA's) or mixtures thereof.

8. The sacrificial coating composition of claim 2 , wherein the at least one surfactant is selected from the groups consisting of anionic surfactants, nonionic surfactants, siloxane surfactants and fluorosurfactants.

9. The sacrificial coating composition of claim 2 , wherein the at least one surfactant is non-ionic surfactant having an HLB value ranging from about 4 to about 14.

10. The sacrificial coating composition of claim 2 , wherein latex comprises a styrene/n-butyl acrylate/methacrylic acid terpolymer.

11. A sacrificial coating composition for an image transfer member in an aqueous ink imaging system, comprising:

a latex comprising polymer particles dispersed in a continuous liquid phase, the latex having a viscosity of about 3 cps to about 800 cps at 25° C., a pH ranging from about 3 to about 10, and a solid content ranging from 5% to about 70%;

at least one hygroscopic material;

at least one surfactant; and

water.

12. The sacrificial coating composition of claim 11 , wherein latex comprises a styrene/n-butyl acrylate/methacrylic acid terpolymer.

13. The sacrificial coating composition of claim 11 , wherein the polymer particles comprise one or more repeating polymeric units selected from the group consisting of acrylic acid units, acrylate units, methacrylic acid units, methacrylate units, diene units, aliphatic nitrile units, vinyl ether units, vinyl ester units, vinyl ketone units, vinylidene halide units, vinyl substituted heterocyclic amine units, acrylamide units, methacrylamide units, vinyl substituted aromatic hydrocarbon units, vinyl halide units and alkene units.

14. The sacrificial coating composition of claim 11 , wherein the latex comprises one or more acrylic resins made from at least one monomer selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, methacrylic acid and acrylic acid.

15. The sacrificial coating composition of claim 11 , wherein the polymers in the latex have a glass transition temperature of ranging from about −45° C. to about 100° C., a weight average molecular weight ranging from about 3000 to about 300,000, and a particle size ranging from 50 nm to 300 nm.

16. The sacrificial coating composition of claim 11 , wherein the polymer particles comprise polyvinyl acetate copolymer.

17. The sacrificial coating composition of claim 11 , wherein the hygroscopic material is a polyol.

18. The sacrificial coating composition of claim 11 , wherein the at least one hygroscopic material is selected from the group consisting of glycerol, sorbitol, vinyl alcohol, xylitol, maltito, polymeric polyols, glyceryl triacetate, urea and alpha-hydroxy acids (AHA's) or mixtures thereof.

19. The sacrificial coating composition of claim 11 , wherein the at least one surfactant is selected from the groups consisting of anionic surfactants, nonionic surfactants, siloxane surfactants and fluorosurfactants.

20. The sacrificial coating composition of claim 11 , wherein the at least one surfactant is non-ionic surfactant having an HLB value ranging from about 4 to about 14.

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
RELEASE OF SECURITY INTEREST IN PATENTS AT R/F 062740/0214 Recorded May 18, 2023
From: CITIBANK, N.A., AS AGENT
To: XEROX CORPORATION
Reel/Frame 063694/0122 →
SECURITY INTEREST Recorded Nov 10, 2022
From: XEROX CORPORATION
To: CITIBANK, N.A., AS AGENT
Reel/Frame 062740/0214 →