IP Library Granted Patent US 9,919,925
Granted Patent B2
US 9,919,925 · App. 15/215,993 · Granted Mar 20, 2018

Catalyst or production of multi-walled carbon nanotubes and method of producing multi-walled carbon nanotubes using the same

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Quick Facts
Patent No.
US 9,919,925
App. No.
15/215,993
Granted
Mar 20, 2018
Kind
B2
Abstract

Disclosed is a catalyst for production of multi-walled carbon nanotubes, in which the catalyst includes a transition metal catalyst supported on a support mixture including MgO, and thus can increase the production of multi-walled carbon nanotubes and, at the same time, reduce the number of walls of the multi-walled carbon nanotubes to thereby reduce the surface resistance of the multi-walled carbon nanotubes. Also disclosed is a method of producing multi-walled carbon nanotubes using the catalyst. The catalyst for production of multi-walled carbon nanotubes includes: a support mixture of a first support and a second support mixed with the first support; and a transition metal catalyst supported on the support mixture.

Claims (9)

1. A method for producing multi-walled carbon nanotubes, comprising:

(a) preparing a catalyst for production of multi-walled carbon nanotubes comprising a support mixture of a first support and a second support mixed with the first support and a transition metal catalyst supported on the support mixture, wherein the second support is magnesium oxide (MgO) and the second support is added in an amount of 5-50 wt % based on 100 wt % of the catalyst for production of multi-walled carbon nanotubes; and

(b) reacting the catalyst for production of multi-walled carbon nanotubes with hydrocarbon gas and hydrogen gas at a temperature of 600 to 900° C. to form multi-walled carbon nanotubes,

wherein step (a) comprises:

preparing a mixture by dissolving a Mg precursor in a solvent, adding a boehmite to the solvent containing the dissolved Mg precursor, and mixing the boehmite with the solvent for 10-30 minutes;

preparing a support mixture by drying the prepared mixture at a temperature of 100 to 150° C. for 1-3 hours, and then heat-treating at a temperature of 450 to 550° C. for 1-5 hours;

dissolving a transition metal catalyst precursor in a solvent; and

mixing the solvent containing the dissolved transition metal catalyst precursor with the support mixture for 10-30 minutes.

2. The method of claim 1 , wherein the hydrocarbon gas and the hydrogen gas are supplied at a flow rate of 50-500 sccm for 5-60 minutes.

Assignments (3)
CHANGE OF NAME Recorded Sep 2, 2022
From: SK GLOBAL CHEMICAL CO., LTD
To: SK GEO CENTRIC CO., LTD.
Reel/Frame 061371/0332 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 24, 2018
From: CHOI, HYUN-CHUL
To: SK INNOVATION CO., LTD.; SK GLOBAL CHEMICAL CO., LTD.
Reel/Frame 044714/0686 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 21, 2016
From: KIM, OK-YOUN; KWON, YONG-TAK
To: SK INNOVATION CO., LTD.; SK GLOBAL CHEMICAL CO., LTD.
Reel/Frame 039212/0548 →