IP Library Granted Patent US 10,851,330
Granted Patent B2
US 10,851,330 · App. 15/220,931 · Granted Dec 1, 2020

Method of improving paper machine fabric performance

Inventors: Harold Laser (Hamilton, CA); Brandon E. Mahler (Cincinnati, OH)
Assignee: DuBois Chemicals, Inc.
C11D11/0017B08B3/022B08B3/026C11D3/044C11D3/2086C11D3/37C11D3/3757D06B5/08D21F1/32D21F7/08D21F7/12D06B2700/14
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Quick Facts
Patent No.
US 10,851,330
App. No.
15/220,931
Granted
Dec 1, 2020
Kind
B2
Abstract

Methods are provided for improving the papermaking process. In various embodiments, the methods include the application of alkali material in combination with an anionic polymeric dispersant and/or a hydroxyfunctional carboxylic acid to papermaking fabrics such that the application thereof removes contaminants from the papermaking fabrics and improves the drainage of said papermaking fabrics. Such alkali material in combination with an anionic polymeric dispersant and/or a hydroxyfunctional carboxylic acid can be applied as a single aqueous solution, and may further comprise a surfactant.

Claims (27)

1. A method of treating and cleaning papermaking fabrics including one or more papermaking felts to increase a drainage rate, the method comprising:

applying an alkali material in combination with an anionic polymeric dispersant and a hydroxyfunctional carboxylic acid to the one or more papermaking felts of the papermaking fabrics as a single aqueous solution to increase a drainage rate through the papermaking fabrics, wherein the papermaking fabrics are contaminated with contaminants comprising wet soils that are hydrophilic and include papermaking fines, and wherein the single aqueous solution comprises a pH from about 9.5 to about 13.5 and a dynamic surface tension of about 25 mN/m to about 40 mN/m; and

based on the application of the single aqueous solution of the alkali material in combination with the anionic polymeric dispersant and the hydroxyfunctional carboxylic acid, removing the contaminants from the papermaking fabrics and improving the drainage of the one or more papermaking felts of the papermaking fabrics such that a resulting drainage rate from the single aqueous solution is higher than the drainage rate through application of the alkali material alone to the one or more papermaking felts of the papermaking fabrics.

2. The method of claim 1 , wherein the papermaking fabrics are contaminated with wet soils in an amount from about 0.1 to about 100% by weight.

3. The method of claim 1 , wherein the alkali material is selected from the group consisting of sodium hydroxide, potassium hydroxide, magnesium hydroxide, ammonia, sodium carbonate, sodium silicate, sodium phosphates, potassium phosphates, alcohol amines, and combinations thereof.

4. The method of claim 1 , wherein the anionic polymeric dispersant is selected from the group consisting of polyacrylic acid and sulfonated analogs and salts thereof, polymaleic acid and sulfonated analogs and salts thereof, poly(maleic anhydride) and sulfonated analogs and salts thereof, polyphosphinocarboxylic acid and sulfonated analogs and salts thereof, polyglutamic acid and sulfonated analogs and salts thereof, polyfumaric acid and sulfonated analogs and salts thereof, polylactic acid and sulfonated analogs and salts thereof, carboxylated vinyl polymers and sulfonated analogs and salts thereof, copolymers of acrylic acid and maleic acid and sulfonated analogs and salts thereof, and combinations thereof.

5. Method of claim 1 , wherein the aqueous solution comprises from about 1% to about 20% by weight anionic polymeric dispersant.

6. The method of claim 1 , wherein the hydroxyfunctional carboxylic acid is an alpha hydroxyl acid.

7. The method of claim 5 , wherein the alpha hydroxyl acid is selected from the group consisting of lactic acid, gluconic acid, glycolic acid, citric acid, mandelic acid, and potassium or sodium salts thereof.

8. The method of claim 1 , wherein the aqueous solution comprises from about 1% to about 20% by weight hydroxyfunctional carboxylic acid.

9. The method of claim 1 , further comprising applying a surfactant.

10. The method of claim 9 , wherein the surfactant is selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants, zwitterionic surfactants, and combinations thereof.

11. The method of claim 9 , wherein the surfactant is selected from the group consisting of dodecylbenzene sulfonate, sodium-1-octane sulfonate, sodium caprylyl sulfonate, alcohol ethoxylates, and combinations thereof.

12. The method of claim 1 , the aqueous solution further comprising a surfactant.

13. The method of claim 12 , wherein the aqueous solution comprises from about 1% to about 20% by weight surfactant.

14. The method of claim 12 , wherein the aqueous solution comprises from about 6% to about 18% by weight surfactant.

15. The method of claim 1 , wherein the method further comprises applying one or more compounds selected from the group consisting of sodium hypocholorite, peroxides, triethanolamine, ethylenediaminetetraacetic acid, nitrilotriacetic acid, sodium silicate, tetrasdoium pyrophosphate, sodium tripolyphosphate, 1-(2,5-dimethoxy-4-methylphenyl)propan-2-amine, and combinations thereof.

16. The method of claim 1 , wherein the aqueous solution further comprises one or more compounds selected from the group consisting of sodium hypocholorite, peroxides, triethanolamine, ethylenediaminetetraacetic acid, nitrilotriacetic acid, sodium silicate, tetrasdoium pyrophosphate, sodium tripolyphosphate, 1-(2,5-dimethoxy-4-methylphenyl)propan-2-amine, and combinations thereof.

17. The method of claim 1 , wherein contaminants comprise organic contaminants.

18. The method of claim 1 , wherein the papermaking fabrics comprise forming fabrics, press felt fabrics, and dryer fabrics.

19. The method of claim 1 , wherein the aqueous solution is applied to the papermaking fabrics at a dosage of about 100 ppm to about 50,000 ppm while a papermaking machine is operating.

20. The method of claim 1 , wherein the aqueous solution is applied to the papermaking fabrics at a dosage of about 0.1% to about 100% while a papermaking machine is not operating.

21. The method of claim 1 , wherein the aqueous solution is applied to the papermaking fabrics through high pressure needle showers, fan showers, flooded nip showers, manual foaming equipment, or manual spraying equipment.

22. The method of claim 18 , wherein the aqueous solution is applied to the papermaking fabrics continuously or intermittently.

23. The method of claim 1 , wherein the aqueous solution is applied to the papermaking fabrics at a temperature from about 50° C. to about 60° C.

24. The method of claim 2 , wherein the wet soils comprise of papermaking fibers and fines, hydrosols, hydrogels, or combinations thereof.

25. The method of claim 17 , wherein the organic contaminants comprise of wet soils.

Assignments (12)
PATENT SECURITY AGREEMENT Recorded Jun 18, 2024
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 067774/0852 →
SECURITY INTEREST Recorded Jul 22, 2022
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 060588/0838 →
RELEASE OF SECURITY INTEREST Recorded Apr 4, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: DUBOIS CHEMICALS, INC.
Reel/Frame 055814/0512 →
SECURITY INTEREST Recorded Jun 30, 2020
From: DUBOIS CHEMICALS, INC., AS GRANTOR
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 053085/0382 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TITLE TO READ RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 042038/0101 PREVIOUSLY RECORDED ON REEL 050598 FRAME 0028. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Oct 10, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 052091/0032 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 042038/0153 Recorded Oct 1, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 050597/0851 →
SECURITY INTEREST Recorded Oct 1, 2019
From: DUBOIS CHEMICALS, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 050573/0202 →
SECURITY INTEREST Recorded Oct 1, 2019
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP, AS COLLATERAL AGENT
Reel/Frame 050573/0867 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 04238/0101 Recorded Oct 1, 2019
From: ANTARES CAPITAL LP
To: DUBOIS CHEMICALS, INC.
Reel/Frame 050598/0028 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 17, 2017
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP
Reel/Frame 042038/0101 →
SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 17, 2017
From: DUBOIS CHEMICALS, INC.
To: ANTARES CAPITAL LP
Reel/Frame 042038/0153 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 18, 2016
From: LASER, HAROLD; MAHLER, BRANDON E.
To: DUBOIS CHEMICALS, INC.
Reel/Frame 039475/0500 →
Continuity (2)
Provisional Application 62198517 · Jul 29, 2015
Related Publication 20170029748A1 · Feb 2, 2017