Immersible gaseous oxidant cathode for electrochemical cell system
An electrochemical cell system is configured to utilize an oxidant reduction electrode module containing an oxidant reduction electrode mounted to a housing to form a gaseous oxidant space therein that is immersed into the ionically conductive medium. A fuel electrode is spaced from the oxidant reduction electrode, such that the ionically conductive medium may conduct ions between the fuel and oxidant reduction electrodes to support electrochemical reactions at the fuel and oxidant reduction electrodes. A gaseous oxidant channel extending through the gaseous oxidant space provides a supply of oxidant to the oxidant reduction electrode, such that the fuel electrode and the oxidant reduction electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce the oxidant at the oxidant reduction electrode, to generate a discharge potential difference therebetween for application to a load.
1. An oxidant reduction electrode module for connection to a cell cover and immersion into an ionically conductive medium of an electrochemical cell having a chamber with an upwardly facing opening for insertion of the module and closing by the cell cover, the oxidant reduction electrode module comprising:
a housing defining a gaseous oxidant receiving space therein and configured for insertion through the upwardly facing opening of the chamber and immersion into the ionically conductive medium;
an oxidant reduction electrode having an oxidant facing side and an ionically conductive medium facing side, the oxidant reduction electrode mounted to said housing such that the oxidant reduction electrode defines a boundary wall for the gaseous oxidant receiving space, with the oxidant facing side facing inwardly to the gaseous oxidant receiving space and the ionically conductive medium facing side facing outwardly for exposure to the ionically conductive medium;
a gaseous oxidant inlet and a gaseous oxidant outlet coupled by a gaseous oxidant channel extending through the gaseous oxidant receiving space;
one or more support members positioned within the gaseous oxidant receiving space defining the gaseous oxidant channel between the gaseous oxidant inlet and the gaseous oxidant outlet and through the gaseous oxidant receiving space, the one or more support members configured to prevent deformation of the oxidant reduction electrode into the gaseous oxidant receiving space when the oxidant reduction electrode is immersed into the ionically conductive medium, and direct a flow of gaseous oxidant within the gaseous oxidant channel from the gaseous oxidant inlet to the gaseous oxidant outlet; and
a conductor channel comprising an electrical conductor electrically connected to the oxidant reduction electrode;
each of the conductor channel, the gaseous oxidant inlet, and the gaseous oxidant outlet extending upwardly from a top of the housing and each being connectable to a respective connector provided on the cell cover for establishing inlet and outlet of the gaseous oxidant and an electrical connection of the oxidant reduction electrode, and
wherein an oxidant is allowed into the gaseous oxidant receiving space via the gaseous oxidant inlet, the oxidant reduction electrode being configured to absorb the gaseous oxidant via the oxidant facing side and reduce the gaseous oxidant during discharge of the electrochemical cell.
2. The oxidant reduction electrode module of claim 1 , wherein the conductor channel is sealed by a sealant that is impermeable to the ionically conductive medium.
3. The oxidant reduction electrode module of claim 1 , wherein the oxidant reduction electrode is configured to be sealed to the housing by a sealant that is impermeable to the ionically conductive medium.
4. The oxidant reduction electrode module of claim 1 , wherein the oxidant reduction electrode comprises polytetrafluoroethylene.
5. The oxidant reduction electrode module of claim 1 , wherein the one or more support members are formed integral to the housing.
6. The oxidant reduction electrode module of claim 1 , wherein the one or more support members comprise baffles for the gaseous oxidant.
7. The oxidant reduction electrode module of claim 1 , wherein portions of the one or more support members spaced adjacent to one another, separated by a spacing defining a portion of the gaseous oxidant channel.
8. The oxidant reduction electrode module of claim 7 , wherein the spacing is approximately between 1-50 mm.
9. The oxidant reduction electrode module of claim 8 , wherein the spacing is approximately 20 mm.
10. The oxidant reduction electrode module of claim 8 , wherein the spacing is approximately 10 mm.
11. The oxidant reduction electrode module of claim 1 , wherein the gaseous oxidant allowed into the gaseous oxidant receiving space via the gaseous oxidant inlet is pressurized to maintain a positive pressure in the gaseous oxidant receiving space.
12. The oxidant reduction electrode module of claim 1 , wherein the gaseous oxidant inlet and the gaseous oxidant outlet are each provided on the same side of the housing.
13. The oxidant reduction electrode module of claim 1 , wherein the connectors are receptacles.
14. An assembly comprising a cell cover and the oxidant reduction electrode module of claim 1 connected thereto, the cell cover comprising a cell cover oxidant channel formed therein for receipt of gaseous oxidant from the gaseous oxidant outlet of the oxidant reduction electrode module.