IP Library Granted Patent US 9,889,634
Granted Patent B2
US 9,889,634 · App. 15/227,495 · Granted Feb 13, 2018

Formable light weight composites

Inventor: Shimon Mizrahi (Haifa, IL)
Assignee: PRODUCTIVE RESEARCH LLC
B32B15/085B23K11/11B29C70/025B29C70/028B29C70/088B32B7/12B32B15/043B32B15/08B32B15/18B32B15/20B32B27/281B32B27/30B32B27/32B32B27/34B32B27/36B32B27/365B32B27/38B32B27/40B23K2203/16B23K2203/172B29K2305/00B29K2705/02B29K2705/12B32B2250/40B32B2262/103B32B2264/105B32B2264/108B32B2270/00B32B2307/306B32B2307/54B32B2419/00B32B2605/00B32B2607/00Y10T156/1041Y10T428/12389Y10T428/12444Y10T428/12486Y10T428/12569Y10T428/2495Y10T428/24967Y10T428/24994Y10T428/31678
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Quick Facts
Patent No.
US 9,889,634
App. No.
15/227,495
Granted
Feb 13, 2018
Kind
B2
Abstract

The present invention relates to light weight composite materials which comprise a metallic layer and a polymeric layer, the polymeric layer containing a filled thermoplastic polymer which includes a thermoplastic polymer and a metallic fiber. The composite materials of the present invention may be formed using conventional stamping equipment at ambient temperatures. Composite materials of the present invention may also be capable of being welded to other metal materials using a resistance welding process such as resistance spot welding.

Claims (32)

1. An article comprising:

a light weight composite having

(i) a first metal foil;

(ii) a second metal foil; and

(iii) an extruded polymeric core layer interposed between the first and second metal foils; wherein the polymeric core layer includes:

a synthetic elastomer having either or both of a tensile modulus at 100% elongation of less than about 3 MPa, a tensile elongation at break greater than about 110%, both measured according to ASTM D638-08 at a nominal strain rate of about 0.1; and from about 3 volume percent to less than about 30 volume percent metal fibers based on the total volume of the polymeric core layer;

wherein

the polymeric core layer has an apparent modulus of rigidity according to ASTM D1043-02 of at least about 200 MPa over a temperature range of about −40° C. to about 50° C.; the metal fibers have a weight average length from about 5 μm to about 25 mm;

and the composite material is stamped and welded to a metal material.

2. The article of claim 1 , wherein the polymeric core layer comprises a thermoplastic polymer including a polyethylene copolymer of one or more α-olefins and optionally one or more additives wherein the polyethylene copolymer includes at least about 80 weight % ethylene polymer and has a peak melting temperature as measured according to ASTM D3418-08 or a glass transition temperature as measured according to ASTM D3418-08 above about 80° C. and below about 250° C.

3. The article of claim 1 , wherein the concentration of pores and voids in the polymeric core layer is from 0 to about 10 volume %, based on the total volume of the polymeric core layer.

4. The article of claim 2 , wherein the thermoplastic polymer has a number average molecular weight greater than about 20,000;

the concentration of any grafted polymer in the polymeric core layer is up to about 10 wt. %, based on the total weight of the polymeric core layer;

the first metal foil includes steel, the part is welded to a steel part and the metal fibers include plain carbon steel fibers; and

the thermoplastic polymer has a crystallinity of about 10% or more.

5. The article of claim 4 , wherein the metal fibers are chopped fibers and have a weight average length of about 5 μm to 8 mm.

6. The article of claim 5 , wherein metal fibers are present in an amount from about 5 volume percent to 20 volume percent, based on the total volume of the polymeric core layer;

and the thickness of one or both of the first and second metal foils is 0.15 mm or more.

7. The article of claim 1 , wherein the first metal foil and the second metal foil each have a first surface facing the polymeric core layer, wherein the polymeric core layer contacts at least 70% of the first surfaces of the first and second metal foils.

8. The article of claim 1 , wherein the composite material includes an edge region sealed by crimping and/or bending the composite material.

9. The article of claim 1 , wherein the composite material includes an edge region sealed by an attached cover.

10. The article of claim 1 , wherein the composite material includes an edge region sealed by welding, soldering or brazing.

11. The article of claim 1 , wherein the composite material includes a spacer entirely interposed between the first and second metal foils.

12. The article of claim 1 , wherein the composite material includes a spacer partially interposed between the first and second metal foils.

13. The article of claim 12 , wherein the spacer includes a first region having a first thickness and interposed between the first and second metal foils and a second region having a second thickness greater than the first thickness, wherein the second regions is located away from the first and second metal foils.

14. The article of claim 8 , wherein the article includes a laser weld joint joining the composite material and the metal material.

15. The article of claim 9 , wherein the article includes a laser weld joint joining the composite material and the metal material.

16. The article of claim 10 , wherein the article includes a laser weld joint joining the composite material and the metal material.

17. The article of claim 11 , wherein the article includes a laser weld joint joining the composite material and the metal material.

18. The article of claim 12 , wherein the article includes a laser weld joint joining the composite material and the metal material.

19. The article of claim 1 , wherein the composite material has a cover over one or more edges.

20. The article of claim 1 , wherein the cover is a coating or a lamination over the one or more edges.

Assignments (2)
SECURITY INTEREST Recorded Mar 14, 2025
From: MATERIAL SCIENCES CORPORATION; MATERIAL SCIENCES CORPORATION, ENGINEERED MATERIALS AND SOLUTIONS GROUP, INC.; CONTINUOUS COLOUR COAT LIMITED
To: TCW ASSET MANAGEMENT COMPANY LLC, AS AGENT
Reel/Frame 070520/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 4, 2018
From: MIZRAHI, SHIMON
To: PRODUCTIVE RESEARCH LLC
Reel/Frame 045004/0808 →
Continuity (6)
Continuation 13939666 · Jul 11, 2013
Continuation 13052292 · Mar 21, 2011
Continuation 12540771 · Aug 13, 2009
Provisional Application 61181511 · May 27, 2009
Provisional Application 61089704 · Aug 18, 2008
Related Publication 20160339675A1 · Nov 24, 2016