Formable light weight composite material systems and methods
View Patent ↗The present invention relates to filled polymeric materials including a polymer and a mass of metallic fibers distributed within the polymer, and to light weight composites which comprise at least a pair of metallic layers and a polymeric layer interposed between the pair of metallic layers, the polymeric layer containing the filled polymeric material. The composite materials of the present invention may be formed using conventional stamping equipment at ambient temperatures. Composite materials of the present invention may also be capable of being welded to other metal materials using a resistance welding process such as resistance spot welding. Preferred composite materials include one or any combination of the following features: metallic fibers that are ribbon fibers; a polymer selected from a polyolefin, a polyamide, or a combination thereof; or a metallic layer (e.g., one or both of the pair of metallic layers) having a surface facing the filled polymeric material that is untreated.
1. A light weight composite comprising:
a first metallic layer;
a second metallic layer; and
an extruded sheet of a filled polymeric material having a thickness interposed between the first metallic layer and the second metallic layer, wherein the filled polymeric materials comprises:
i. one or more polymers including a polyolefin polymer having a crystallinity of about 10 wt. % to about 80 wt. % as measured using differential scanning calorimetry and a melting point greater than about 80° C., as measured according to ASTM D3418-08; and
ii. greater than 5 volume percent and less than 25 volume percent based on the total volume of the filled polymeric material of a mass of metallic fibers distributed within the one or more polymers the mass spanning the thickness of the sheet and including fibers having a generally rectangular cross-section in a direction perpendicular to a length of the fiber, a weight average length greater than about 200 μm and less than about 25 mm,
wherein the weight ratio of the one or more polymers to the metallic fibers is greater than about 2.2:1;
the light weight composite has a weld current range of about 1.5 kA or more; and
the light weight composite is capable of being stamped to a draw ratio greater than 1.5.
2. The light weight composite of claim 1 , wherein the polyolefin polymer includes more than one α-olefins.
3. The light weight composite of claim 1 , wherein the fraction by number of the metallic fibers spanning the thickness of the extruded sheet is about 0.10 or less.
4. The light weight composite of claim 1 , wherein an edge of the light weight composite is sealed.
5. The light weight composite of claim 4 , wherein the sealed edge includes a weld joining the first and second metal layers.
6. An article including the light weight composite of claim 4 ; a metal component; and a weld joint connecting the light weight composite to the metal component.
7. The article of claim 6 , wherein the weld joint is formed by laser welding.
8. A process of forming the article of claim 6 comprising the steps of:
stamping the light weight composite including drawing at least one portion of the light weight composite by a draw ratio greater than 1.5; and
welding the light weight composite to the metal component, wherein the welding step includes laser welding.
9. The light weight composite of claim 1 , wherein the extruded sheet of the filled polymeric material has edges and the light weight composite includes a coating or protective layer over one or more of the edges.
10. The light weight composite of claim 9 , wherein the coating or protective layer substantially protects the edge from contact with a liquid or gas.
11. The light weight composite of claim 9 , wherein the coating or protective layer has a lower permeability to moisture relative to the filled polymeric material.
12. The light weight composite of claim 1 , wherein the one or more polymers has a melt index sufficiently high so that the polymer can be processed using extrusion equipment; and the concentration of pores and voids in the filled polymeric material is from 0 to about 5 volume %, based on the total volume of the filled polymeric material.
13. The light weight composite of claim 12 , wherein
the volume of the filled polymeric material is 30 volume % to 92% of the total volume of the light weight composite,
the total thickness of the first and second metallic layers is from 5% to 70% of the total thickness of the light weight composite; and
the polyolefin polymer includes a polyethylene copolymer having at least 60% ethylene, a number average molecular weight greater than 20,000 and consists entirely of one or more α-olefins.
14. The light weight composite of claim 13 , wherein
the light composite has a thickness of 0.3 mm or more and the filled polymeric material has a generally uniform thickness that is 40% or more of the total thickness of the composite material.
15. A stamped and welded article including the light weight composite of claim 1 welded to a sheet of steel, and including at least one weld nugget joining the sheet of steel and the light weight composite; and
wherein the light weight composite is stamped to a draw ratio greater than 1.5.
16. The article of claim 15 , wherein
the first metallic layer has a thickness from about 0.10 mm to about 1.5 mm;
the second metallic layer has a thickness from about 0.10 mm to about 1.5 mm;
the volume of the filled polymeric material is 30 volume % to 92% of the total volume of the light weight composite;
the total thickness of the first and second metallic sheets is from 5% to 70% of the total thickness of the light weight composite;
the one or more polymers is present at a concentration of about 75 volume percent or more, based on the total volume of the filled polymeric material, and
the first and second metallic layers are formed of steel sheets and the metallic fibers includes steel fibers.
17. The article of claim 16 , wherein the light weight composite includes area contact between a steel fiber and a steel layer, area contact between two steel fibers, or both.
18. The article of claim 15 , wherein
the polyolefin polymer includes more than one α-olefins monomers;
the one or more polymers has a melt index sufficiently high so that the polymer can be processed using extrusion equipment; and
the concentration of pores and voids in the filled polymeric material is from 0 to about 5 volume %, based on the total volume of the filled polymeric material;
the volume of the filled polymeric material is 30 volume % to 92% of the total volume of the light weight composite,
the total thickness of the first and second metallic layers is from 5% to 70% of the total thickness of the light weight composite; and
the light composite has a thickness of 0.3 mm or more and the filled polymeric material has a generally uniform thickness that is 40% or more of the total thickness of the composite material.
19. The article of claim 15 , wherein
the polyolefin is a copolymer including at least 60 wt. % of an α-olefin and at least one additional monomer and the polyolefin is a low density polyethylene, a linear low density polyethylene, a very low density polyethylene, a polyethylene plastomer, or any combination thereof.
20. A process of forming a composite part comprising a step of stamping the light weight composite of claim 1 , includes a step of drawing at least one portion of the light weight composite by a draw ratio greater than 1.5.
21. The process of claim 20 , wherein the process includes a step of welding the light weight composite to at least one additional metal containing material, wherein the welding step includes laser welding.