Carbonyl functional inversion agents for water-in-oil latices and methods of use
View Patent ↗Water-in-oil latices of water soluble or dispersible polymers and methods of using the same are presented. The latices include carbonyl functional inversion agents that provide rapid and complete inversion of the latices under conditions wherein the water source used to invert the latex is provided at high temperature, or includes a high level of total dissolved solids, or is both high temperature and high total dissolved solids.
1. A water-in-oil latex comprising
about 15 wt % to 70 wt % of a water soluble or dispersible polymer comprising 1 mol % to about 100 mol % acrylamide monomers;
about 0.1 wt % to 20.0 wt % of an inversion surfactant characterized as having a hydrophilic/lipophilic balance of 10 or greater; and
about 0.1 wt % to 20.0 wt % of an inversion agent that is a carbonyl functional inversion agent, wherein the inversion agent is not a surfactant.
2. The latex of claim 1 comprising about 1.0 wt % to 20.0 wt % of the inversion agent and inversion surfactant combined.
3. The latex of claim 1 , wherein the inversion agent is selected from hydroxycarboxylic acids or salts thereof, hydroxyamides, hydroxamates, and amino acids.
4. The latex of claim 3 , wherein the hydroxycarboxylic acid or salt thereof is a carboxymethyl polyol ether.
5. The latex of claim 4 , wherein the carboxymethyl polyol ether is a carboxymethyl-1,2-diol, carboxymethyl erythritol, carboxymethyl sorbitol, carboxymethyl polyglycerol, or carboxymethyl glycerol.
6. The latex of claim 3 , wherein the hydroxycarboxylic acid is an α-hydroxyacid or a β-hydroxyacid.
7. The latex of claim 6 , wherein the α-hydroxyacid is glycolic acid, lactic acid, tartaric acid, or malic acid and the β-hydroxyacid is hydroxypropionic acid, carnitine, or salicylic acid.
8. The latex of claim 1 comprising about 0.1 wt % to 5.0 wt % of the inversion agent.
9. The latex of claim 1 comprising
about 3 wt % to 50 wt % water;
about 10 wt % to 40 wt % of a compound or blend thereof that is less than 0.1 wt % soluble in water at 25° C. and is substantially a liquid over the range of 20° C. to 90° C. and comprising linear, branched, or cyclic hydrocarbon moieties;
about 20 wt % or less of a latex surfactant characterized as having a hydrophilic/lipophilic balance of between 2 and 10; and
about 0.1 wt % to 5.0 wt % of the inversion agent.
10. The latex of claim 1 , wherein the inversion agent is a hydrotrope.
11. The latex of claim 1 , wherein the inversion agent is characterized as having a hydrophilic/lipophilic balance of greater than about 19.
12. The latex of claim 1 , wherein the latex is shelf stable.
13. The latex of claim 1 , wherein the latex has a bulk viscosity at least 15% lower than the same latex excluding the inversion agent.
14. A method of forming an invertible latex, the method comprising
(a) forming a water-in-oil latex comprising
about 15 wt % to 70 wt % of a water soluble or dispersible polymer;
about 3 wt % to 50 wt % water;
about 10 wt % to 40 wt % of a compound or blend thereof that is less than 0.1 wt % soluble in water at 25° C. and is substantially a liquid over the range of 20° C. to 90° C. and comprising linear, branched, or cyclic hydrocarbon moieties; and
about 20 wt % or less of a latex surfactant characterized as having a hydrophilic/lipophilic balance of between 2 and 10; and
(b) adding to the latex
about 0.1 wt % to 20.0 wt % of an inversion surfactant characterized as having a hydrophilic/lipophilic balance of 10 or greater; and
about 0.1 wt % to 5.0 wt % of a carbonyl functional inversion agent to form an invertible latex, wherein the inversion agent is not a surfactant.
15. The method of claim 14 , wherein the invertible latex is shelf stable.
16. The method of claim 14 , wherein the inversion agent is selected from hydroxycarboxylic acids or salts thereof, hydroxyamides, hydroxamates, and amino acids.
17. The method of claim 16 , wherein the hydroxycarboxylic acid or salt thereof is a carboxymethyl polyol ether selected from carboxymethyl-1,2-diol, carboxymethyl erythritol, carboxymethyl sorbitol, carboxymethyl polyglycerol or carboxymethyl glycerol.
18. The method of claim 16 , wherein the hydroxycarboxylic acid is an α-hydroxyacid selected from glycolic acid, lactic acid, tartaric acid, and malic acid, or a β-hydroxyacid selected from hydroxypropionic acid, carnitine, and salicylic acid.
19. A method of recovering hydrocarbon compounds from a subterranean reservoir, the method comprising
(a) forming an invertible latex according to the method of claim 14 ,
(b) adding a water source to the invertible latex in a single addition to form a polymer flooding solution comprising about 100 ppm to 10,000 ppm of the water soluble or dispersible polymer,
(c) injecting the polymer flooding solution into the subterranean reservoir, and
(d) recovering the hydrocarbon compounds.
20. The method of claim 19 , wherein the water source is about 30° C. to 100° C.
21. The method of claim 19 , wherein the water source includes about 0.1 to 30 wt % total dissolved solids.
22. The method of claim 19 , wherein the water source is about 30° C. to 100° C. and includes about 0.1 to 30 wt % total dissolved solids.