Phosphorus functional inversion agents for water-in-oil latices and methods of use
View Patent ↗Water-in-oil lattices of water soluble or dispersible polymers and methods of using the same are presented. The lattices include phosphorus functional inversion agents that provide rapid and complete inversion of the lattices under conditions wherein the water source used to invert the latex is provided at high temperature, or includes a high level of total dissolved solids, or is both high temperature and high total dissolved solids.
1. A water-in-oil latex comprising
about 15 wt % to 70 wt % of a water soluble or dispersible polymer comprising 1 mol % to about 100 mol % acrylamide monomers;
about 0.1 wt % to 20.0 wt % of an inversion surfactant characterized as having a hydrophilic/lipophilic balance of 10 or greater; and
about 0.1 wt % to 20.0 wt % of a phosphorus functional inversion agent that is a hydrotrope.
2. The latex of claim 1 comprising about 1.0 wt % to 20.0 wt % of the inversion agent and inversion surfactant combined.
3. The latex of claim 1 , wherein the phosphorus functional inversion agent comprises a phosphorus functional compound characterized as a water-soluble compound having at least one phosphono moiety or at least one phosphino moiety.
4. The latex of claim 3 , wherein the phosphorus functional compound has 1 to 5 phosphono moieties.
5. The latex of claim 1 , wherein the phosphorus functional inversion agent is characterized as having a hydrophilic/lipophilic balance of greater than about 45.
6. The latex of claim 1 comprising about 0.1 wt % to 5.0 wt % of the phosphorus functional inversion agent.
7. The latex of claim 1 comprising
about 3 wt % to 50 wt % water;
about 10 wt % to 40 wt % of a compound or blend thereof that is less than 0.1 wt % soluble in water at 25° C. and is substantially a liquid over the range of 20° C. to 90° C. and comprising linear hydrocarbon moieties;
about 20 wt % or less of a latex surfactant characterized as having a hydrophilic/lipophilic balance of between 2 and 10; and
about 0.1 wt % to 5.0 wt % of the inversion agent.
8. The latex of claim 1 , wherein the latex is shelf stable.
9. A method of forming an invertible latex, the method comprising
(a) forming a water-in-oil latex comprising
about 15 wt % to 70 wt % of a water soluble or dispersible polymer;
about 3 wt % to 50 wt % water;
about 10 wt % to 40 wt % of a compound or blend thereof that is less than 0.1 wt % soluble in water at 25° C. and is substantially a liquid over the range of 20° C. to 90° C. and comprising linear, branched, or cyclic hydrocarbon moieties; and
about 20 wt % or less of a latex surfactant characterized as having a hydrophilic/lipophilic balance of between 2 and 10; and
(b) adding to the latex about 0.1 wt % to 20.0 wt % of an inversion surfactant characterized as having a hydrophilic/lipophilic balance of 10 or greater and about 0.1 wt % to 5.0 wt % of a phosphorus functional inversion agent to form an invertible latex, wherein the phosphorus functional inversion agent is a hydrotrope.
10. The method of claim 9 , wherein the invertible latex is shelf stable.
11. The method of claim 9 , wherein the phosphorus functional inversion agent comprises a phosphorus functional compound characterized as a water-soluble compound having at least one phosphono moiety or at least one phosphino moiety.
12. The method of claim 9 , wherein the phosphorus functional inversion agent is characterized as having a hydrophilic/lipophilic balance of greater than about 45.
13. A method of recovering hydrocarbon compounds from a subterranean reservoir, the method comprising
(a) forming a water-in-oil latex comprising:
about 15 wt % to 70 wt % of a water soluble or dispersible polymer;
about 3 wt % to 50 wt % water;
about 10 wt % to 40 wt % of a compound or blend thereof that is less than 0.1 wt % soluble in water at 25° C. and is substantially a liquid over the range of 20° C. to 90° C. and comprising linear, branched, or cyclic hydrocarbon moieties; and
about 20 wt % or less of a latex surfactant characterized as having a hydrophilic/lipophilic balance of between 2 and 10;
(b) adding to the latex about 0.1 wt % to 20.0 wt % of an inversion surfactant characterized as having a hydrophilic/lipophilic balance of 10 or greater and about 0.1 wt % to 5.0 wt % of a phosphorus functional inversion agent to form an invertible latex, wherein the phosphorus functional inversion agent is a hydrotrope;
(c) adding a water source to the invertible latex in a single addition to form a polymer flooding solution comprising about 100 ppm to 10,000 ppm of the water soluble or dispersible polymer,
(d) injecting the polymer flooding solution into the subterranean reservoir, and
(e) recovering the hydrocarbon compounds.
14. The method of claim 13 , wherein the water source comprises a temperature of about 30° C. to 100° C.
15. The method of claim 13 , wherein the water source includes about 0.1 to 30 wt % total dissolved solids.
16. The method of claim 13 , wherein the water source comprises a temperature of about 30° C. to 100° C. and includes about 0.1 to 30 wt % total dissolved solids.