IP Library Granted Patent US 9,911,873
Granted Patent B2
US 9,911,873 · App. 15/234,586 · Granted Mar 6, 2018

Hydrogenation of passivated contacts

Inventors: William Nemeth (Wheat Ridge, CO); Hao-Chih Yuan (Vancouver, WA); Vincenzo LaSalvia (Golden, CO); Pauls Stradins (Golden, CO); Matthew R. Page (Littleton, CO)
Assignee: Alliance for Sustainable Energy, LLC
H01L31/022425H01L31/02167H01L31/068H01L31/1872Y02E10/547Y02P70/521
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Quick Facts
Patent No.
US 9,911,873
App. No.
15/234,586
Granted
Mar 6, 2018
Kind
B2
Abstract

Methods of hydrogenation of passivated contacts using materials having hydrogen impurities are provided. An example method includes applying, to a passivated contact, a layer of a material, the material containing hydrogen impurities. The method further includes subsequently annealing the material and subsequently removing the material from the passivated contact.

Claims (20)

1. A method comprising:

applying, to a passivated contact, a layer of a material, the material containing hydrogen impurities;

subsequently annealing the layer of the material; and

subsequently removing the layer of the material from the passivated contact.

2. The method of claim 1 , wherein the layer of the material comprises alumina (Al2O3).

3. The method of claim 1 , wherein the layer of the material is applied using Plasma-Enhanced Chemical Vapor Deposition (PECVD).

4. The method of claim 1 , wherein the layer of the material is applied using Atomic Layer Deposition (ALD).

5. The method of claim 1 , wherein the passivated contact comprises a layer of polycrystalline silicon (pcSi) on silicon oxide (SiOx).

6. The method of claim 1 , further comprising growing the passivated contact on a silicon wafer, wherein growing the passivated contact comprises growing a layer of silicon oxide (SiOx) on the silicon wafer.

7. The method of claim 6 , wherein the layer of silicon oxide has a thickness of 10 nm or less.

8. The method of claim 7 , wherein the layer of silicon oxide has a thickness of 2 nm or less.

9. The method of claim 6 , wherein the layer of silicon oxide is thermally grown on the silicon wafer.

10. The method of claim 6 , wherein the layer of silicon oxide is chemically grown on the silicon wafer.

11. The method of claim 6 , wherein growing the passivated contact further comprises growing amorphous silicon on the layer of silicon oxide.

12. The method of claim 11 , wherein growing the passivated contact further comprises thermally crystalizing the amorphous silicon to form a layer of polycrystalline silicon (pcSi).

13. The method of claim 11 , wherein the amorphous silicon is applied using Plasma-Enhanced Chemical Vapor Deposition (PECVD).

14. The method of claim 1 , wherein removing the layer of the material comprises applying at least one of an acid or a base to the layer of the material.

15. The method of claim 1 , further comprising applying a doped amorphous silicon cap on the passivated contact after removing the layer of the material.

16. The method of claim 15 , wherein the doped amorphous silicon cap has a thickness between about 3 nm and about 7 nm.

17. The method of claim 1 , wherein the passivated contact is incorporated within a solar cell.

Assignments (3)
CHANGE OF NAME Recorded Dec 16, 2025
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: ALLIANCE FOR ENERGY INNOVATION, LLC
Reel/Frame 073993/0276 →
CONFIRMATORY LICENSE Recorded Nov 18, 2016
From: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 040703/0249 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2016
From: NEMETH, WILLIAM; YUAN, HAO-CHIH; LASALVIA, VINCENZO; STRADINS, PAULS; PAGE, MATTHEW R.
To: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
Reel/Frame 039670/0469 →
Continuity (2)
Provisional Application 62203799 · Aug 11, 2015
Related Publication 20170047458A1 · Feb 16, 2017