Ionic liquid filled porous carbon anode active material and method for manufacturing the same
Provided is a method for manufacturing an anode active material particle having good lithium ion conducting property and good formability. The method for manufacturing an anode active material includes a first step of making a carbon particle with pores have contact with an ionic liquid having a lithium ion conducting property, and making the ionic liquid flow into the pores, and a second step of washing the carbon particle after the first step, while leaving the ion liquid inside the pores.
1. A method for manufacturing an anode active material particle comprising:
a first step of contacting a carbon particle having pores with an ionic liquid in which a lithium salt is dissolved, and making the ionic liquid flow into the pores; and
a second step of washing the carbon particle with an organic solvent after the first step, while leaving the ionic liquid inside the pores.
2. The method according to claim 1 , wherein in the first step, a decompression in a system is carried out with the carbon particle immersed in the ionic liquid, for discharging a gas existing inside the pores to the outside of the pores and making the ionic liquid flow into the pores.
3. The method according to claim 1 , wherein the ionic liquid includes a TFSA anion.
4. The method according to claim 1 , wherein the carbon particle is a graphite particle.
5. The method according to claim 4 , wherein the graphite particle is a natural graphite particle.
6. The method according to claim 1 , wherein a particle diameter of the carbon particle is in the range of from 0.1 μm to 50 μm.
7. The method according to claim 6 , wherein a specific surface area of the carbon particle is more than 0.5 m 2 /g to 10 m 2 /g.
8. The method according to claim 7 , wherein a specific surface area of the anode active material particle is in the range of from 0.5 m 2 /g to 2 m 2 /g, and smaller than the specific surface area of the carbon particle.
9. A method for manufacturing an anode comprising a step of carrying out a pressure forming on an anode mixture including the anode active material particle manufactured by the method according to claim 1 .
10. A method for manufacturing a lithium battery, the method comprising:
arranging the anode manufactured by the method according to claim 9 in a manner that the anode has contact with one surface of an inorganic solid electrolyte layer; and
arranging a cathode on the other surface of the inorganic solid electrolyte layer.