TWO-LAYER COATINGS ON METAL SUBSTRATES AND DENSE ELECTROLYTE FOR HIGH SPECIFIC POWER METAL-SUPPORTED SOFC
A fuel cell includes a chromium-containing metal support, a ceramic electrode layer on the metal support and an electroconductive ceramic layer between the chromium-containing metal support and the ceramic electrode layer. The electroconductive ceramic layer includes a ceramic material selected from lanthanum-doped strontium titanate and perovskite oxides.
1 . A method comprising:
forming an electroconductive ceramic layer on a porous metal support;
forming a ceramic anode layer on the electroconductive ceramic layer;
forming a ceramic electrolyte layer on the ceramic anode layer; and
forming a ceramic cathode layer on the ceramic electrolyte layer.
2 . The method as recited in claim 1 , wherein:
forming the electroconductive ceramic layer comprises sintering the electroconductive ceramic layer;
forming the ceramic anode layer comprises sintering the ceramic anode layer; and
forming the ceramic electrolyte layer comprises using ion-assisted electron beam physical vapor deposition to deposit the ceramic electrolyte layer on the ceramic anode layer.
3 . A method of limiting oxidation of a chromium-containing metal support in a fuel cell, the method comprising:
using an electroconductive ceramic barrier layer between a chromium-containing metal support and a ceramic electrode layer disposed on the chromium-containing metal support, the electroconductive ceramic barrier layer including a ceramic material selected from a group consisting of lanthanum-doped strontium titanate and perovskite oxides.
4 . A method of processing a fuel cell, the method comprising:
providing a substrate that includes:
a chromium-containing metal support;
a ceramic electrode layer on the metal support; and
an electroconductive ceramic layer between the chromium-containing metal support and the ceramic electrode layer, the electroconductive ceramic layer includes a ceramic material selected from a group consisting of lanthanum-doped strontium titanate and perovskite oxides; and
depositing a dense ceramic electrolyte layer on the ceramic electrode layer.