Hot press formed article having excellent delamination resistance and method for manufacturing the same
An HPF molding member having a melted aluminum plating layer formed on the surface of a base steel sheet and excellent delamination resistance. The base steel sheet comprises: 0.18-0.25% by weight of C; 0.1-1.0% by weight of Si; 0.9-1.5% by weight of Mn; 0.03% by weight or less of P; 0.01% by weight or less of S; 0.01-0.05% by weight of Al; 0.05-0.5% by weight of Cr; 0.01-0.05% by weight of Ti; 0.001-0.005% by weight of B; 0.009% by weight or less of N; and the balance Fe and other impurities. The plating layer consists of a soft diffusion layer and a hard alloy layer, the hard alloy layer having a tau layer irregularly and non-continuously dispersed and distributed on the inside thereof at 10% or more of the entire area fraction. The difference in hardness between the alloy layer and the diffusion layer is 400 (Hv) or less.
1. A hot press formed (HPF) article having excellent delamination resistance, a hot dip aluminum plating layer being formed on a surface of a substrate steel sheet, wherein the substrate steel sheet includes, in % by weight, C: 0.18% to 0.25%, Si: 0.1% to 1.0%, Mn: 0.9% to 1.5%, P: 0.03% or less, S: 0.01% or less, Al: 0.01% to 0.05%, Cr: 0.05% to 0.5%, Ti: 0.01% to 0.05%, B: 0.001% to 0.005, N: 0.009% or less, and a remainder of Fe and other impurities;
the plating layer is formed to have a soft diffusion layer and a hard alloy layer;
the alloy layer comprises Fe 2 Al 5 matrix phase and a tau phase comprised of Fe—Al—Si based alloy phase;
the tau phase is irregularly and discontinuously dispersed and distributed inside the alloy layer in an amount of 10% or greater based on the total area fraction so that a difference in hardnesses between the alloy layer and the diffusion layer is 400 (Hv) or less.
2. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the substrate steel sheet is a cold rolled steel sheet or a hot rolled steel sheet.
3. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the tau phase is present in a range of 10% by weight to 20% by weight inside the alloy layer.
4. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the tau phase has an aspect ratio in a range of 1 to 4.
5. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the tau phase having a size of 5 μm or less occupies an area of 50% or greater with respect to the total tau phase fraction.
6. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the substrate steel sheet further includes Mo+W in an amount of 0.001% to 0.5%.
7. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the substrate steel sheet further includes a sum of one or more types of Nb, Zr or V in a range of 0.001% to 0.4%.
8. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the substrate steel sheet further includes Cu+Ni in a range of 0.005% to 2.0%.
9. The hot press formed (HPF) article having excellent delamination resistance of claim 1 , wherein the substrate steel sheet further includes one or more types of Sb, Sn or Bi in an amount of 0.03% or less.
10. A method for manufacturing a hot press formed (HPF) article having excellent delamination resistance, the method comprising:
preparing a steel sheet including, in % by weight, C: 0.18% to 0.25%, Si: 0.1% to 1.0%, Mn: 0.9% to 1.5%, P: 0.03% or less, S: 0.01% or less, Al: 0.01% to 0.05%, Cr: 0.05% to 0.5%, Ti: 0.01% to 0.05%, B: 0.001% to 0.005, N: 0.009% or less, and a remainder of Fe and other impurities;
hot dip aluminum plating the steel sheet by, after heating the steel sheet to a temperature of 550° C. to 850° C., immersing the steel sheet in a hot dip aluminum plating bath maintained at a temperature of 640° C. to 680° C. and composed of, in % by weight, Si: 7% to 13%, Fe: less than 3%, and the remainder of Al and other unavoidable impurities;
skin pass milling (SPM) the hot dip aluminum plating steel sheet with an elongation of 0.5% to 3% after cooling the hot dip galvanized steel sheet;
alloying a hot dip aluminum plating layer on a surface of the hot dip aluminum plated steel sheet by heating the hot dip aluminum plated steel sheet to a temperature of 850° C. to 950° C. and maintaining the temperature for a certain period of time; and
manufacturing a hot press formed (HPF) product by rapidly cooling the alloyed hot dip aluminum plated steel sheet to a temperature of 300° C. or lower while hot press forming the alloyed hot dip aluminum plated steel sheet.
11. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the alloyed hot dip aluminum plating layer is formed to have a soft diffusion layer and a hard alloy layer;
the alloy layer comprises Fe 2 Al 5 matrix phase and a tau phase comprised of Fe—Al—Si based alloy phase;
a tau phases is irregularly and discontinuously dispersed and distributed inside the alloy layer in an amount of 10% or greater based on the total area fraction.
12. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 11 , wherein the tau phase is present in a range of 10% by area to 20% by area inside the alloy layer.
13. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 11 , wherein the tau phase has an aspect ratio in a range of 1 to 4.
14. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 11 , wherein the tau phase having a size of 5 μm or less occupies an area of 50% or greater with respect to the total tau phase fraction.
15. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the steel sheet is a cold rolled steel sheet or a hot rolled steel sheet.
16. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the substrate steel sheet further includes Mo+W in an amount of 0.001% to 0.5%.
17. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the substrate steel sheet further includes a sum of one or more types of Nb, Zr or V in a range of 0.001% to 0.4%.
18. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the substrate steel sheet further includes Cu+Ni in a range of 0.005% to 2.0%.
19. The method for manufacturing a hot press formed (HPF) article having excellent delamination resistance of claim 10 , wherein the substrate steel sheet further includes one or more types of Sb, Sn or Bi in an amount of 0.03% or less.