Curable polymeric materials and their use for fabricating electronic devices
Disclosed are curable linear polymers that can be used as active and/or passive organic materials in various electronic, optical, and optoelectronic devices. In some embodiments, the device can include an organic semiconductor layer and a dielectric layer prepared from such curable linear polymers. In some embodiments, the device can include a passivation layer prepared from the linear polymers described herein. The present linear polymers can be solution-processed, then cured thermally (particularly, at relatively low temperatures) and/or photochemically into various thin film materials with desirable properties.
1. An electronic device comprising a field-effect transistor having a semiconductor layer comprising a semiconducting electronic material, a dielectric layer comprising an insulating electronic material, and source, drain, and gate electrodes each comprising a conducting electronic material, wherein the field-effect transistor comprises an organic material comprising a ring-opening metathesis polymerization (ROMP) polymer; wherein:
the ROMP polymer is a linear polymer characterized by unsaturated bonds in the backbone and is obtained via ring-opening metathesis polymerization from an optionally substituted norbornene monomer, an optionally substituted dicyclopentadiene monomer, or a heteroatom derivative thereof; and wherein at least some of the unsaturated bonds in the backbone of the linear polymer are either hydrogenated, oxidized or epoxidized; and
either the dielectric layer comprises the organic material as the insulating electronic material, or the organic material is in contact with at least one of the semiconducting electronic material, the insulating electronic material, and the conducting electronic material.
2. The electronic device of claim 1 , wherein the ROMP polymer is a linear polymer characterized by unsaturated bonds in the backbone and is obtained via ring-opening metathesis polymerization from an optionally substituted norbornene monomer.
3. The electronic device of claim 1 , wherein the ROMP polymer is a linear polymer characterized by unsaturated bonds in the backbone and is obtained via ring-opening metathesis polymerization from a heteroatom derivative of an optionally substituted norbornene monomer.
4. The electronic device of claim 1 , wherein the ROMP polymer is a linear polymer characterized by unsaturated bonds in the backbone and is obtained via ring-opening metathesis polymerization from an optionally substituted dicyclopentadiene monomer.
5. The electronic device of claim 1 , wherein the ROMP polymer is a linear polymer characterized by unsaturated bonds in the backbone and is obtained via ring-opening metathesis polymerization from a heteroatom derivative of an optionally substituted dicyclopentadiene monomer.
6. The electronic device of claim 1 , wherein no more than 50% of the unsaturated bonds in the backbone of the linear polymer are hydrogenated.
7. The electronic device of claim 1 , wherein some of the unsaturated bonds in the backbone of the linear polymer are oxidized.
8. The electronic device of claim 1 , wherein some of the unsaturated bonds in the backbone of the linear polymer are epoxidized.
9. The electronic device of claim 1 , wherein the dielectric layer comprises the organic material as the insulating electronic material.
10. The electronic device of claim 1 , wherein the organic material is in contact with the semiconducting electronic material.
11. The electronic device of claim 1 , wherein the organic material is in contact with the insulating electronic material.
12. The electronic device of claim 1 , wherein the organic material is in contact with the conducting electronic material.