Lactamic polymer containing an acetoacetate moiety
The invention provides lactamic polymers comprising an acetoacetate moiety. The lactamic polymers may be readily functionalized and the functionalized lactamic polymers may be further derivatized to provide a wide variety of useful polymers having desirable chemical and physical properties. The lactamic polymers of the invention may be employed in a wide variety of compositions. (A); (B) wherein R 1 -R 6 , w, x, y, z, and n are described herein.
1. A lactamic polymer having the following structure:
wherein each R 1 is independently selected from the group consisting of hydrogen and C 1 -C 30 functionalized and unfunctionalized alkyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each R 3 is independently selected from the group consisting of C 1 -C 6 functionalized and unfunctionalized alkyl, amide, carbonyl, and carboxyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each R 5 is independently selected from the group consisting of C 1 -C 12 functionalized and unfunctionalized alkyl and alkenyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof;
wherein w, a maleic anhydride derived monomer, may be partially or fully ring-opened; w, x, and y are mole percent, the sum of which =100%; and each n is an integer independently ranging from 1-4.
2. The polymer according to claim 1 , wherein each R 1 is independently hydrogen or methyl.
3. The polymer according to claim 1 , wherein each R 3 is —C(O)OCH 2 CH 2 —.
4. The polymer according to claim 1 , wherein each R 5 is independently selected from the group consisting of C 1 -C 8 functionalized and unfunctionalized alkyl and alkenyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof.
5. The polymer according to claim 1 , wherein w ranges from 1-97%, x ranges from 1-97%, and y ranges from 1-97%.
6. The polymer according to claim 1 , wherein each n is an integer independently ranging from 1-3.
7. The polymer according to claim 1 , wherein the polymer has a structure selected from the group consisting of:
8. A composition comprising a lactamic polymer having the following structure:
wherein each R 1 is independently selected from the group consisting of hydrogen and C 1 -C 30 functionalized and unfunctionalized alkyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each R 3 is independently selected from the group consisting of C 1 -C 6 functionalized and unfunctionalized alkyl, amide, carbonyl, and carboxyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof; each R 5 is independently selected from the group consisting of C 1 -C 12 functionalized and unfunctionalized alkyl and alkenyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof;
wherein w, a maleic anhydride derived monomer, may be partially or fully ring-opened; w, x, and y are mole percent, the sum of which =100%; and each n is an integer independently ranging from 1-4.
9. The composition according to claim 8 , wherein each R1 is independently hydrogen or methyl.
10. The composition according to claim 8 , wherein each R 3 is —C(O)OCH 2 CH 2 —.
11. The composition according to claim 8 , wherein each R 5 is independently selected from the group consisting of C 1 -C 8 functionalized and unfunctionalized alkyl and alkenyl groups, wherein any of the before mentioned groups may be with or without heteroatoms, and mixtures thereof.
12. The composition according to claim 8 , wherein w ranges from 1-97%, x ranges from 1-97%, and y ranges from 1-97%.
13. The composition according to claim 8 , wherein each n is an integer independently ranging from 1-3.
14. The composition according to claim 8 , wherein the polymer has a structure selected from the group consisting of:
15. The composition according to claim 8 , wherein the composition comprises adhesives, aerosols, agricultural compositions, anti-soil redeposition agents, batteries, beverages, biocides, block copolymers, branch/comb copolymers, cementing compositions, cleaning compositions, coating compositions, conductive materials, cosmetic compositions, cross-linkers, dental compositions, polymeric dyes, decorated pigments, detergents, dispersants, drugs, electronics, encapsulations, foods, hair sprays, household-industrial-institutional, inks and coatings, interlaminate adhesives, lithographic solutions, membrane additive compositions, metal working fluids, oilfield compositions, paints, paper, personal care compositions, pharmaceuticals, pigment additives, plasters, plastics, printing, reactive biocides, refractive index modifiers, sequestrants, soil release compositions, static control agents, and wood-care compositions.
16. The composition according to claim 8 , the composition further comprising an inert solvent.
17. The composition according to claim 8 , the composition further comprising a reactive solvent.
18. The polymer composition according to claim 8 , the composition further comprising a cross-linker.