Nonwovens having aligned segmented fibers
Nonwoven fabrics suitable for a wide variety of applications (e.g., healthcare, filtration, industrial, packaging, etc.) are provided. In one aspect, the nonwoven fabric includes a plurality of segmented fibers. Each of the plurality of segmented fibers may comprise a fiber axis and a plurality of alternating larger diameter and smaller diameter segments along the fiber axis. The plurality of segmented fibers may be substantially aligned in a first direction.
1. A nonwoven fabric, comprising:
a plurality of incrementally-stretched meltspun segmented fibers,
wherein each of the plurality of incrementally-stretched meltspun segmented fibers comprises a fiber axis and a plurality of alternating larger diameter segments and smaller diameter segments along the fiber axis, each of the plurality of incrementally-stretched meltspun fibers having from 5 to 50 discrete larger diameter segments separated by the plurality of smaller diameter segments per linear meter, and
wherein the plurality of incrementally-stretched meltspun fibers include a first meltspun fiber having a first larger diameter segment and smaller diameter segment along a first fiber axis of the first meltspun fiber; wherein the plurality of incrementally-stretched meltspun segmented fibers are incrementally-stretched at least three times in a first direction and substantially aligned in the first direction, and wherein the first larger diameter segment has a first linear length and the first smaller diameter segments has a second linear length, and wherein the second linear length is greater than the first linear length; and wherein the first direction comprises a cross direction, and wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a machine direction elongation and a cross direction elongation, the machine direction elongation being greater than the cross direction elongation.
2. The nonwoven fabric according to claim 1 , wherein the machine direction elongation at break is at least 3 times longer than the cross direction elongation at break.
3. The nonwoven fabric according to claim 1 , wherein the first direction comprises a cross direction, and wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a cross direction tensile strength and a machine direction tensile strength, the cross direction tensile strength being at least 2 times stronger than the machine direction tensile strength.
4. The nonwoven fabric according to claim 1 , wherein at least one of the larger diameter segments has a diameter from 1 μm to 100 μm, and at least one of the smaller diameter segments has a diameter from 0.5 μm to 25 μm.
5. The nonwoven fabric according to claim 1 , wherein the plurality of alternating larger diameter segments and smaller diameter segments have a fiber diameter change Δd f between a first larger diameter segment and a first smaller diameter segment, and the fiber diameter change Δd f comprises from 5% to 60%.
6. The nonwoven fabric according to claim 1 , wherein at least one of the larger diameter segments has a diameter that is at least 6% larger than at least one of the smaller diameter segments.
7. The nonwoven fabric according to claim 1 , wherein each of the plurality of incrementally-stretched meltspun segmented fibers comprises a transition region between a respective first larger diameter segment and a respective first smaller diameter segment.
8. The nonwoven fabric according to claim 7 , wherein the transition region comprises a shoulder-like structure.
9. The nonwoven fabric according to claim 1 , wherein the plurality of incrementally-stretched meltspun segmented fibers comprise extensible non-elastic filaments.
10. The nonwoven fabric according to claim 1 , wherein the plurality of incrementally-stretched meltspun segmented fibers comprise at least one of a polypropylene, a polyethylene, a propylene-ethylene random copolymer, a propylene-ethylene block copolymer, a polyethylene terephthalate, a polybutylene terephthalate, a polytrimethylene terephthalate, a polylactic acid, a polyamide, or any combination thereof.
11. The nonwoven fabric according to claim 10 , wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a polypropylene comprising a melt flow rate from 10 g/10 min to 2000 g/10 min tested at 230° C. according to ASTM 1238.
12. A multi-layer composite, comprising:
at least two layers, the at least two layers including at least one layer comprising a nonwoven fabric;
wherein the nonwoven fabric comprises a plurality of incrementally-stretched meltspun segmented fibers, wherein each of the plurality of incrementally-stretched meltspun segmented fibers comprises a fiber axis and a plurality of alternating larger diameter segments and smaller diameter segments along the fiber axis, each of the plurality of incrementally-stretched meltspun fibers having from 5 to 50 discrete larger diameter segments separated by the plurality of smaller diameter segments per linear meter, and
wherein the plurality of incrementally-stretched meltspun fibers include a first meltspun fiber having a first larger diameter segment and smaller diameter segment along a first fiber axis of the first meltspun fiber; wherein the plurality of incrementally-stretched meltspun segmented fibers are incrementally-stretched at least three times in a first direction and substantially aligned in the first direction, and wherein the first larger diameter segments has a first linear length and the first smaller diameter segments has a second linear length, and wherein the second linear length is greater than the first linear length; and wherein the first direction comprises a cross direction, and wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a machine direction elongation and a cross direction elongation, the machine direction elongation being greater than the cross direction elongation.
13. The multi-layer composite according to claim 12 , further comprising at least one non-segmented layer, at least one film layer, or both.
14. The multi-layer composite according to claim 12 , wherein the at least two layers comprise (i) a first nonwoven fabric defined by the nonwoven fabric comprising a plurality of incrementally-stretched meltspun segmented fibers and (ii) a second nonwoven fabric, the first and second nonwoven fabrics being cross-lapped and bonded together.
15. The nonwoven fabric according to claim 1 , wherein the plurality of incrementally-stretched meltspun segmented fibers consist of (i) at least one polymeric material consisting of a polypropylene, a polyethylene, a propylene-ethylene random copolymer, a propylene-ethylene block copolymer, a polyethylene terephthalate, a polybutylene terephthalate, a polytrimethylene terephthalate, or any combination thereof; and (ii) at least one additive; wherein the at least one additive consists of calcium carbonate, titanium oxide, a barium sulfate, talc, a nanoclay, a colorant, a fluorochemical, an antistatic agent, or any combination thereof.
16. The nonwoven fabric according to claim 15 , wherein the at least one polymeric material is polypropylene, polyethylene, a propylene-ethylene random copolymer, a propylene-ethylene block copolymer, or any combination thereof.
17. The nonwoven fabric according to claim 16 , wherein the at least one polymeric material is polypropylene.
18. The nonwoven fabric according to claim 1 , wherein the plurality of incrementally-stretched meltspun segmented fibers are incrementally-stretched at least four times in a first direction, and each of the plurality of incrementally-stretched meltspun fibers have from 15 to 50 discrete larger diameter segments separated by the plurality of smaller diameter segments per linear meter.
19. The nonwoven fabric according to claim 1 , wherein the nonwoven fabric is provided in a spread-out and flat configuration in a first direction and a second direction that is perpendicular to the first direction.
20. A nonwoven fabric, comprising:
a plurality of incrementally-stretched meltspun segmented fibers, wherein each of the plurality of incrementally-stretched meltspun segmented fibers comprises a fiber axis and a plurality of alternating larger diameter segments and smaller diameter segments along the fiber axis, each of the plurality of incrementally-stretched meltspun fibers having from 5 to 50 discrete larger diameter segments separated by the plurality of smaller diameter segments per linear meter, and
wherein the plurality of incrementally-stretched meltspun fibers include a first meltspun fiber having a first larger diameter segment and smaller diameter segment along a first fiber axis of the first meltspun fiber; wherein the plurality of incrementally-stretched meltspun segmented fibers are incrementally-stretched at least three times in a first direction and substantially aligned in the first direction, and wherein the first larger diameter segment has a first linear length and the first smaller diameter segments has a second linear length, and wherein the second linear length is greater than the first linear length; and
wherein the first direction comprises a cross direction, and wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a cross direction tensile strength and a machine direction tensile strength, the cross direction tensile strength being at least 2 times stronger than the machine direction tensile strength.
21. A multi-layer composite, comprising:
at least two layers, the at least two layers including at least one layer comprising a nonwoven fabric; wherein the nonwoven fabric comprises a plurality of incrementally-stretched meltspun segmented fibers, wherein each of the plurality of incrementally-stretched meltspun segmented fibers comprises a fiber axis and a plurality of alternating larger diameter segments and smaller diameter segments along the fiber axis, each of the plurality of incrementally-stretched meltspun fibers having from 5 to 50 discrete larger diameter segments separated by the plurality of smaller diameter segments per linear meter, and
wherein the plurality of incrementally-stretched meltspun fibers include a first meltspun fiber having a first larger diameter segment and smaller diameter segment along a first fiber axis of the first meltspun fiber; wherein the plurality of incrementally-stretched meltspun segmented fibers are incrementally-stretched at least three times in a first direction and substantially aligned in the first direction, and wherein the first larger diameter segments has a first linear length and the first smaller diameter segments has a second linear length, and wherein the second linear length is greater than the first linear length; and
wherein the first direction comprises a cross direction, and wherein the plurality of incrementally-stretched meltspun segmented fibers comprise a cross direction tensile strength and a machine direction tensile strength, the cross direction tensile strength being at least 2 times stronger than the machine direction tensile strength.