Retardation film, circularly-polarizing plate, and image-displaying device
An object of the present invention is to provide a retardation film excellent in various properties such as optical properties, heat resistance, mechanical properties, and reliability. The present invention relates to a retardation film containing a thermoplastic resin and composed of a single layer, in which the retardation film has a value of wavelength dispersion that is a ratio of retardations at a wavelength of 450 nm and at a wavelength of 550 nm being 0.75 or more and 0.92 or less; a birefringence at a wavelength of 550 nm and the wavelength dispersion satisfy a relationship of Δn≥0.0140×(R450/R550)−0.0082; and a photoelastic coefficient is 25×10 −12 Pa −1 or less.
1. A circularly polarizing plate comprising a retardation film and a polarizer stacked on the retardation film,
the retardation film comprising a thermoplastic resin and composed of a single layer,
wherein the retardation film has:
a value of wavelength dispersion (R450/R550) as a ratio of an in-plane retardation (R450) at a wavelength of 450 nm and an in-plane retardation (R550) at a wavelength of 550 inn being 0.75 or more and 0.92 or less;
a birefringence (Δn) at a wavelength of 550 nm satisfying a relationship of the following mathematical formula (I) with the wavelength dispersion (R450/R550); and
a photoelastic coefficient of 25×10 −12 Pa −1 or less:
birefringence= R 550[nm]/(film thickness[mm]×10 6 ),
Δ n≥ 0.0140×( R 450 /R 550)−0.0082 (I),
wherein the thermoplastic resin comprises at least one bonding group of a carbonate bond and an ester bond and one or more structural units selected from the group consisting of a structural unit represented by the following general formula (1) and a structural unit represented by the following general formula (2),
wherein in the thermoplastic resin, a content of an aromatic group-containing structural unit other than the structural unit represented by the general formula (1) and the structural unit represented by the general formula (2) is 5% by mass or less:
wherein in the general formula (1) and the general formula (2), each of R 1 to R 3 is independently a direct bond or an alkylene group having a carbon number of from 1 to 4, which may have a substituent, and each of R 4 to R 9 is independently hydrogen atom, an alkyl group having a carbon number of from 1 to 10, which may have a substituent, an aryl group having a carbon number of from 4 to 10, which may have a substituent, an acyl group having a carbon number of from 1 to 10, which may have a substituent, an alkoxy group having a carbon number of from 1 to 10, which may have a substituent, an aryloxy group having a carbon number of from 1 to 10, which may have a substituent, an acyloxy group having a carbon number of from 1 to 10, which may have a substituent, an amino group which may have a substituent, a vinyl group having a carbon number of from 1 to 10, which may have a substituent, an ethynyl group having a carbon number of from 1 to 10, which may have a substituent, a sulfur atom having a substituent, a silicon atom having a substituent, a halogen atom, a nitro group, or a cyano group, provided that at least two adjacent groups out of R 4 to R 9 may be linked to each other to form a ring.
2. The circularly polarizing plate according to claim 1 , wherein the thermoplastic resin has a refractive index at a sodium d line (589 mm) of from 1.49 to 1.56.
3. The circularly polarizing plate according to claim 1 , wherein the thermoplastic resin has a glass transition temperature of 120° C. to 160° C.
4. The circularly polarizing plate according to claim 1 , wherein the thermoplastic resin has an elastic modulus of 1 GPa to 2.5 GPa.
5. The circularly polarizing plate according to claim 1 , wherein the thermoplastic resin comprises the structural unit represented by the general formula (1) or the general formula (2) in an amount of 1% to 40% by mass in total.
6. The circularly polarizing plate according to claim 1 , wherein the thermoplastic resin comprises a structural unit represented by the following general formula (3)
7. An image display device comprising the circularly polarizing plate according to claim 1 .
8. An organic EL panel comprising the circularly polarizing plate according to claim 1 .