Retardation film, circularly-polarizing plate, and image-displaying device
The retardation film of the present invention contains a thermoplastic resin and is constituted of a single layer. A value of wavelength dispersion (R450/R550) that is a ratio of a retardation R450 at a wavelength of 450 nm and a retardation R550 at a wavelength of 550 nm is 0.70 or more and 0.85 or less; and a photoelastic coefficient is 14×10 −12 Pa −1 or less.
1. A retardation film comprising a thermoplastic resin and composed of a single layer,
wherein the retardation film has:
a value of wavelength dispersion (R450/R550) as a ratio of an in-plane retardation R450 at a wavelength of 450 nm and an in-plane retardation R550 at a wavelength of 550 nm being 0.70 to 0.85; and
a photoelastic coefficient of 14×10 −12 Pa −1 or less,
wherein the thermoplastic resin comprises at least one bonding group of a carbonate bond and an ester bond and one or more structural units selected from the group consisting of a structural unit represented by the following general formula (1) and a structural unit represented by the following general formula (2),
wherein in the thermoplastic resin, a content of an aromatic group-containing structural unit other than the structural unit represented by the general formula (1) and the structural unit represented by the general formula (2) is 5% by mass or less:
wherein in the general formula (1) and the general formula (2), each of R 1 to R 3 is independently a direct bond or an alkylene group having a carbon number of from 1 to 4, which may have a substituent, and each of R 4 to R 9 is independently hydrogen atom, an alkyl group having a carbon number of from 1 to 10, which may have a substituent, an aryl group having a carbon number of from 4 to 10, which may have a substituent, an acyl group having a carbon number of from 1 to 10, which may have a substituent, an alkoxy group having a carbon number of from 1 to 10, which may have a substituent, an aryloxy group having a carbon number of from 1 to 10, which may have a substituent, an acyloxy group having a carbon number of from 1 to 10, which may have a substituent, an amino group which may have a substituent, a vinyl group having a carbon number of from 1 to 10, which may have a substituent, an ethynyl group having a carbon number of from 1 to 10, which may have a substituent, a sulfur atom having a substituent, a silicon atom having a substituent, a halogen atom, a nitro group, or a cyano group, provided that at least two adjacent groups out of R 4 to R 9 may be linked to each other to form a ring and two substituents R 4 's, R 5 's, R 6 's, R 7 's, R 8 's, and R 9 's may be the same with or different from each other,
wherein the thermoplastic resin further comprises a structural unit represented by the following general formula (3):
and
wherein the retardation film has a film thickness of 10 μm to 60 μm.
2. A retardation film comprising a thermoplastic resin and composed of a single layer, wherein the retardation film has:
a value of wavelength dispersion (R450/R550) as a ratio of an in-plane retardation R450 at a wavelength of 450 nm and an in-plane retardation R550 at a wavelength of 550 nm being 0.70 to 0.92; and
a product of a photoelastic coefficient and an elastic modulus satisfying the following formula (I):
(Photoelastic coefficient [Pa −1 ]×10 12 )×(Elastic modulus [Pa]×10 −9 )≤35 (I),
wherein the thermoplastic resin comprises at least one bonding group of a carbonate bond and an ester bond and one or more structural units selected from the group consisting of a structural unit represented by the following general formula (1) and a structural unit represented by the following general formula (2),
wherein in the thermoplastic resin, a content of an aromatic group-containing structural unit other than the structural unit represented by the general formula (1) and the structural unit represented by the general formula (2) is 5% by mass or less:
wherein in the general formula (1) and the general formula (2), each of R 1 to R 3 is independently a direct bond or an alkylene group having a carbon number of from 1 to 4, which may have a substituent, and each of R 4 to R 9 is independently hydrogen atom, an alkyl group having a carbon number of from 1 to 10, which may have a substituent, an aryl group having a carbon number of from 4 to 10, which may have a substituent, an acyl group having a carbon number of from 1 to 10, which may have a substituent, an alkoxy group having a carbon number of from 1 to 10, which may have a substituent, an aryloxy group having a carbon number of from 1 to 10, which may have a substituent, an acyloxy group having a carbon number of from 1 to 10, which may have a substituent, an amino group which may have a substituent, a vinyl group having a carbon number of from 1 to 10, which may have a substituent, an ethynyl group having a carbon number of from 1 to 10, which may have a substituent, a sulfur atom having a substituent, a silicon atom having a substituent, a halogen atom, a nitro group, or a cyano group, provided that at least two adjacent groups out of R 4 to R 9 may be linked to each other to form a ring and two substituents R 4 's, R 5 's, R 6 's, R 7 's, R 8 's, and R 9 's may be the same with or different from each other,
wherein the thermoplastic resin further contains a structural unit represented by the following general formula (3):
and
wherein the retardation film has a film thickness of 10 μm to 60 μm.
3. The retardation film according to claim 1 , wherein the thermoplastic resin has a refractive index at a sodium d line (wavelength: 589 nm) of from 1.49 to 1.56.
4. The retardation film according to claim 1 , wherein the thermoplastic resin has a glass transition temperature of 120° C. to 160° C.
5. The retardation film according to claim 1 , wherein the thermoplastic resin has a saturated water absorption of 1.0% to 3.0%.
6. The retardation film according to claim 1 , wherein the thermoplastic resin comprises 1% to 40% by mass of one or more structural units selected from the group consisting of the structural units represented by the general formula (1) and the general formula (2).
7. A circularly polarizing plate comprising the retardation film according to claim 1 and a polarizer stacked on the retardation film.
8. An image display device comprising the circularly polarizing plate according to claim 7 .
9. An organic EL panel comprising the circularly polarizing plate according to claim 7 .
10. The retardation film according to claim 2 , wherein the thermoplastic resin has a refractive index at a sodium d line (wavelength: 589 nm) of from 1.49 to 1.56.
11. The retardation film according to claim 2 , wherein the thermoplastic resin has a glass transition temperature of 120° C. to 160° C.
12. The retardation film according to claim 2 , wherein the thermoplastic resin has a saturated water absorption of 1.0% to 3.0%.
13. The retardation film according to claim 2 , wherein the thermoplastic resin comprises 1% to 40% by mass of one or more structural units selected from the group consisting of the structural units represented by the general formula (1) and the general formula (2).
14. A circularly polarizing plate comprising the retardation film according to claim 2 and a polarizer stacked on the retardation film.
15. An image display device comprising the circularly polarizing plate according to claim 14 .
16. An organic EL panel comprising the circularly polarizing plate according to claim 14 .