Dirt pick-up resistant composition
View Patent ↗Water-based compositions that are resistant to dirt pickup are described. The water-based composition includes a latex or water-dispersible polymer and a non-VOC UV-VIS (preferably, ultraviolet) absorber as a dirt pickup resistance additive. Methods of making water-based compositions including a non-VOC UV-VIS absorber as a dirt pickup resistance additive are also described.
1. A method of making a dirt pick-up resistant coating composition, the method comprising:
providing a water-dispersible polymer by emulsion polymerization of one or more ethylenically unsaturated monomers in an aqueous solvent, wherein the one or more ethylenically unsaturated monomers comprise 2-ethyl hexyl acrylate, acetoacetoxy ethyl methacrylate, or a combination thereof; and
providing methyl-o-benzoyl benzoate; and
mixing the water-dispersible polymer with the methyl-o-benzoyl benzoate in an amount sufficient to produce a water-based coating composition with improved dirt pick-up resistance relative to a conventional coating composition, based on ΔE values.
2. A method of making a dirt pick-up resistant composition, the method comprising:
providing one or more ethylenically unsaturated monomers in an emulsion, wherein the one or more ethylenically unsaturated monomers comprise 2-ethyl hexyl acrylate, acetoacetoxy ethyl methacrylate, or a combination thereof;
polymerizing the emulsion; and
adding methyl-o-benzoyl benzoate
in an amount sufficient to produce a coating composition with improved dirt pick-up resistance relative to a conventional coating composition, based on ΔE values;
wherein the adding step occurs without the presence of a low VOC coalescent.
3. The method of claim 1 , wherein the coating composition compromises an amount of one or more low VOC coalescents effective to facilitate coalescence of the coating composition.
4. The method of claim 1 , wherein the coating composition shows at least 10% improvement in dirt pick-up resistance relative to a conventional coating composition based on ΔE values.
5. The method of claim 1 , wherein the amount of methyl-o-benzoyl benzoate is 0.1 wt-% to 5.0 wt-%, based on the weight of polymer solids.
6. The method of claim 1 , wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.
7. The method of claim 1 , wherein the composition includes methyl-o-benzoyl benzoate as the only UV absorber.
8. The method of claim 1 , wherein the water-dispersible polymer has at least one Tg within a range of −10° C. to 40° C.
9. The method of claim 1 , wherein the water-based composition is a paint, a sealer, a caulk, or a sealant.
10. The method of claim 2 , wherein the polymerization of the emulsion of one or more ethylenically unsaturated monomers is a single stage process.
11. The method of claim 2 , wherein the polymerization of the emulsion of one or more ethylenically unsaturated monomers is a two-stage process.
12. The method of claim 2 , wherein the water-dispersible polymer has at least one Tg within a range of −10° C. to 40° C.
13. The method of claim 2 , wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.
14. The method of claim 1 , wherein the water-dispersible polymer comprises a surfactant and polymer particles comprising a homopolymer or copolymer including 2-ethyl hexyl acrylate, acetoacetoxy ethyl methacrylate, or a combination thereof.
15. The method of claim 1 , wherein the water-dispersible polymer is derived by polymerization of an emulsion in a single stage process, the emulsion comprising:
about 30 to 45 percent by weight of methyl methacrylate;
about 5 to 20 percent by weight of 2-ethyl hexyl acrylate;
about 30 to 50 percent by weight of butyl acrylate;
about 1 to 5 percent by weight of acetoacetoxy ethyl methacrylate.
16. The method of claim 1 , wherein the water-dispersible polymer is derived by polymerization of an emulsion in two-stage process, the emulsion comprising:
a first monomer composition including
10 to 30 percent by weight of butyl acrylate;
1 to 4 percent by weight acetoacetoxy ethyl methacrylate;
50 to 90 percent by weight of methyl methacrylate; and
1 to 5 percent by weight of (meth)acrylic acid; and
a second monomer composition including
40 to 60 percent by weight of butyl acrylate;
1 to 4 percent by weight of acetoacetoxy ethyl methacrylate;
20 to 50 percent by weight of methyl methacrylate; and
1 to 5 percent by weight of (meth)acrylic acid.
17. A method of making a dirt pick-up resistant coating composition, the method comprising:
providing a water-dispersible polymer having at least one Tg within a range of −10° C. to 40° C., wherein the water-dispersible polymer is an emulsion polymer derived from monomers comprising 2-ethyl hexyl acrylate, acetoacetoxy ethyl methacrylate, or a combination thereof; and
providing methyl-o-benzoyl benzoate; and
mixing the water-dispersible polymer with the methyl-o-benzoyl benzoate in an amount sufficient to produce a water-based coating composition that shows at least 10% improvement in dirt pick-up resistance relative to a conventional coating composition based on ΔE values.
18. The method of claim 17 , wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.