IP Library Granted Patent US 10,559,642
Granted Patent B2
US 10,559,642 · App. 15/300,481 · Granted Feb 11, 2020

Organic light-emitting device having a fluoride and metal based intermediate layer and production method

Inventors: Hiroaki Yamane (Osaka, JP); Masaki Nishimura (Tokyo, JP); Jun Hashimoto (Tokyo, JP); Noriyuki Matsusue (Tokyo, JP); Kazuhiro Yoneda (Tokyo, JP); Minh Hiep Hoang (Kanagawa, JP)
Assignee: JOLED INC.
H01L27/3276H01L51/5072H01L51/5076H01L51/5092H01L51/5206H01L51/5228H01L51/5234H01L51/56H01L27/3244H01L51/50H01L51/5218H01L2251/5315
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Quick Facts
Patent No.
US 10,559,642
App. No.
15/300,481
Granted
Feb 11, 2020
Kind
B2
Abstract

An organic light-emitting device including: a substrate; an anode above the substrate; wiring above the substrate, spaced away from the anode in a direction parallel to a main surface of the substrate; a light-emitting layer above the anode, containing an organic light-emitting material; an intermediate layer on the light-emitting layer and the wiring, continuous over the light-emitting layer and the wiring and containing a fluoride of a first metal which is an alkali metal or an alkaline earth metal; an organic functional layer on the intermediate layer, continuous over the light-emitting layer and the wiring and made of an organic material having an electron transporting property or an electron injection property and doped with a second metal having a property of cleaving a bond between the first metal and fluorine in the fluoride; and a cathode on the organic functional layer, continuous over the light-emitting layer and the wiring.

Claims (36)

1. An organic light-emitting device, comprising:

a substrate;

an anode disposed above the substrate;

a wiring disposed above the substrate, the wiring being spaced away from the anode in a direction parallel to a main surface of the substrate;

a light-emitting layer disposed above the anode and containing an organic light-emitting material;

an intermediate layer disposed on the light-emitting layer and above the wiring, the intermediate layer being continuous over the light-emitting layer and the wiring and containing a fluoride of a first metal, the first metal being an alkali metal or an alkaline earth metal;

an organic functional layer disposed on the intermediate layer, the organic functional layer being continuous over the light-emitting layer and the wiring and made of an organic material doped with a second metal, the organic material having at least one of an electron transporting property and an electron injection property, the second metal having a property of cleaving a bond between the first metal and fluorine in the fluoride of the first metal; and

a cathode disposed on the organic functional layer, the cathode being continuous over the light-emitting layer and the wiring, wherein

0.1≤x≤4, 3≤y≤50, and y≥20x, where

x denotes a film thickness [nm] of the intermediate layer and y denotes a dope concentration [wt %] of the second metal in the organic functional layer.

2. An organic light-emitting device, comprising:

a substrate;

an anode disposed above the substrate;

a wiring disposed above the substrate, the wiring being spaced away from the anode in a direction parallel to a main surface of the substrate;

a light-emitting layer disposed above the anode and containing an organic light-emitting material;

an intermediate layer disposed on the light-emitting layer and above the wiring, the intermediate layer being continuous over the light-emitting layer and the wiring and containing a fluoride of a first metal, the first metal being an alkali metal or an alkaline earth metal;

an organic functional layer disposed on the intermediate layer, the organic functional layer being continuous over the light-emitting layer and the wiring and made of an organic material doped with a second metal, the organic material having at least one of an electron transporting property and an electron injection property, the second metal having a property of cleaving a bond between the first metal and fluorine in the fluoride of the first metal; and

a cathode disposed on the organic functional layer, the cathode being continuous over the light-emitting layer and the wiring, wherein

1≤x≤2, 20≤y≤40, and y≥20x, where

x denotes a film thickness [nm] of the intermediate layer and y denotes a dope concentration [wt %] of the second metal in the organic functional layer.

3. A production method of an organic light-emitting device, comprising:

forming an anode and a wiring above a substrate, the wiring being spaced away from the anode in a direction parallel to a main surface of the substrate;

forming a light-emitting layer containing an organic light-emitting material above the anode;

forming an intermediate layer on the light-emitting layer and above the wiring, the intermediate layer being continuous over the light-emitting layer and the wiring and containing a fluoride of a first metal, the first metal being an alkali metal or an alkaline earth metal;

forming an organic functional layer on the intermediate layer, the organic functional layer being continuous over the light-emitting layer and the wiring and made of an organic material doped with a second metal, the organic material having at least one of an electron transporting property and an electron injection property, the second metal having a property of cleaving a bond between the first metal and fluorine in the fluoride of the first metal; and

forming a cathode on the organic functional layer, the cathode being continuous over the light-emitting layer and the wiring, wherein

0.1≤x≤4, 3≤y≤50, and y≥20x, where

x denotes a film thickness [nm] of the intermediate layer and y denotes a dope concentration [wt %] of the second metal in the organic functional layer.

4. A production method of an organic light-emitting device, comprising:

forming an anode and a wiring above a substrate, the wiring being spaced away from the anode in a direction parallel to a main surface of the substrate;

forming a light-emitting layer containing an organic light-emitting material above the anode;

forming an intermediate layer on the light-emitting layer and above the wiring, the intermediate layer being continuous over the light-emitting layer and the wiring and containing a fluoride of a first metal, the first metal being an alkali metal or an alkaline earth metal;

forming an organic functional layer on the intermediate layer, the organic functional layer being continuous over the light-emitting layer and the wiring and made of an organic material doped with a second metal, the organic material having at least one of an electron transporting property and an electron injection property, the second metal having a property of cleaving a bond between the first metal and fluorine in the fluoride of the first metal; and

forming a cathode on the organic functional layer, the cathode being continuous over the light-emitting layer and the wiring, wherein

1≤x≤2, 20≤y≤40, and y≥20x, where

x denotes a film thickness [nm] of the intermediate layer and y denotes a dope concentration [wt %] of the second metal in the organic functional layer.

Assignments (7)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2025
From: JDI DESIGN AND DEVELOPMENT G.K.
To: MAGNOLIA BLUE CORPORATION
Reel/Frame 072039/0656 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 31, 2024
From: JOLED, INC.
To: JDI DESIGN AND DEVELOPMENT G.K.
Reel/Frame 066382/0619 →
CORRECTION BY AFFIDAVIT FILED AGAINST REEL/FRAME 063396/0671 Recorded Jun 12, 2023
From: JOLED, INC.
To: JOLED, INC.
Reel/Frame 064067/0723 →
SECURITY INTEREST Recorded Apr 20, 2023
From: JOLED, INC.
To: INCJ, LTD.
Reel/Frame 063396/0671 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2016
From: HOANG, MINH HIEP
To: PANASONIC CORPORATION
Reel/Frame 040787/0456 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2016
From: YAMANE, HIROAKI; NISHIMURA, MASAKI; HASHIMOTO, JUN; MATSUSUE, NORIYUKI; YONEDA, KAZUHIRO
To: JOLED INC.
Reel/Frame 040787/0508 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2016
From: PANASONIC CORPORATION
To: JOLED INC.
Reel/Frame 040787/0479 →