Liquid crystal composition and liquid crystal display device
To show a liquid crystal composition having at least one or a suitable balance regarding at least two of characteristics such as a short response time, a large voltage holding ratio, a low threshold voltage, a large contrast ratio, a long service life and a small flicker rate; and an AM device having characteristics such as a short response time, a large voltage holding ratio, a low threshold voltage, a large contrast ratio and a long service life. The liquid crystal composition has a negative dielectric anisotropy and contains a specific compound having a large negative dielectric anisotropy as a first component, and the composition may contain a specific compound having a high maximum temperature or a small viscosity as a second component, a specific compound having a large negative dielectric anisotropy as a third component, and a specific compound having a polymerizable group as an additive component.
1. A liquid crystal composition that has a negative dielectric anisotropy, and consists essentially of at least one compound selected from the group of compounds represented by formula (1) as a first component, at least one compound selected from the group of compounds represented by formula (2) as a second component, and at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein, in formula (1), R 1 is alkyl having 1 to 12 carbons, or alkyl having 1 to 12 carbons in which at least one piece of hydrogen is replaced by halogen; and R 2 is alkyl having 1 to 12 carbons or alkoxy having 1 to 12 carbons;
in formula (2), R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkyl having 1 to 12 carbons in which at least one piece of hydrogen is replaced by halogen, or alkenyl having 2 to 12 carbons in which at least one piece of hydrogen is replaced by halogen; ring A and ring B are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 1 is a single bond, ethylene or carbonyloxy; and a is 1, 2 or 3;
in formula (3), R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkenyloxy having 2 to 12 carbons, or alkyl having 1 to 12 carbons in which at least one piece of hydrogen is replaced by halogen; ring C and ring E are independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, 1,4-phenylene in which at least one piece of hydrogen is replaced by fluorine or chlorine, or tetrahydropyran-2,5-diyl; ring D is 2,3-difluoro-1,4-phenylene, 2-chloro-3-fluoro-1,4-phenylene, 2,3-difluoro-5-methyl-1,4-phenylene, 3,4,5-trifluoronaphthalene-2,6-diyl or 7,8-difluorochroman-2,6-diyl; Z 2 and Z 3 are independently a single bond, ethylene, carbonyloxy or methyleneoxy; and b is 0, 1, 2 or 3, c is 0 or 1, and a sum of b and c is 3 or less, and when b is 2, Z 2 is a single bond, carbonyloxy or methyleneoxy.
2. The liquid crystal composition according to claim 1 , wherein a proportion of the first component is in the range of 3% by weight to 40% by weight based on the weight of the liquid crystal composition.
3. The liquid crystal composition according to claim containing at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-13) as the second component:
wherein, in formula (2-1) to formula (2-13), R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkyl having 1 to 12 carbons in which at least one piece of hydrogen is replaced by halogen, or alkenyl having 2 to 12 carbons in which at least one piece of hydrogen is replaced by halogen.
4. The liquid crystal composition according to claim 1 , wherein a proportion of the second component is in the range of 10% by weight to 90% by weight based on the weight of the liquid crystal composition.
5. The liquid crystal composition according to claim 1 , containing at least one compound selected from the group of compounds represented by formula (3-1) to (3-18) as the third component:
wherein, in formula (3-1) to formula (3-18), R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkenyloxy having 2 to 12 carbons, or alkyl having 1 to 12 carbons in which at least one piece of hydrogen is replaced by halogen.
6. The liquid crystal composition according to claim 1 , wherein a proportion of the third component is in the range of 10% by weight to 80% by weight based on the weight of the liquid crystal composition.
7. A liquid crystal display device, including the liquid crystal composition according to claim 1 .
8. The liquid crystal display device according to claim 7 , wherein an operating mode in the liquid crystal display device includes an IPS mode, a VA mode, an FFS mode or an FPA mode, and a driving mode in the liquid crystal display device includes an active matrix mode.
9. The liquid crystal display device according to claim 7 , wherein a flicker rate is in the range of 0% to 1%.