Use of PEBA having long blocks for the manufacture of all or part of a catheter
A copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: number-average molecular mass of the PE blocks greater than 500 g/mol, and number-average molecular mass of the PA blocks greater than 10 000 g/mol.
1. A process for manufacturing a burst-proof catheter balloon, said process comprising:
a) a step of providing a copolymer containing polyether blocks and polyamide blocks in which said copolymer has the following characteristics:
1) number-average molecular mass of the polyether blocks greater than 500 g/mol,
2) number-average molecular mass of the polyamide blocks greater than 13,000 g/mol, and
3) the copolymer comprises polyether blocks composed of a majority of PTMG monomer units,
4) a Shore hardness of greater than 72;
b) an optional step of mixing said copolymer with at least one other polymer and/or at least one additive, so as to manufacture a composition comprising:
1) from 30% to 100% by weight of a said copolymer containing polyether blocks and polyamide blocks
2) from 0 to 70% by weight of at least one other polymer chosen from polyamides, TPU, COPE, PVC, ABS, PS, PET, PETE, PVDF, ETFE, Polyimide, PEEK, PEKK, and silicone,
3) from 0 to 40% of at least one additive, relative to the total weight of the composition;
c) a step of processing said copolymer or said composition at a temperature within the range from 200 to 300° C.;
d) a step of forming the balloon at a temperature below the Tm (melting point) of the copolymer;
e) a step of recovering the balloon.
2. The process as claimed in claim 1 , comprising wherein said processing step c) comprises at least one of the following steps: dry blending, extrusion, coextrusion, tube extrusion, overmolding, blow-molding, and combinations thereof.
3. A method comprising manufacturing an inflatable catheter balloon with improved bursting strength with a powder or granule composition, wherein said powder or granule composition comprises:
1) from 30% to 100% by weight of a copolymer containing polyether blocks and polyamide blocks in which said copolymer has the following characteristics:
a) number-average molecular mass of the polyether blocks greater than 500 g/mol,
b) number-average molecular mass of the polyamide blocks greater than 13,000 g/mol, and
c) the copolymer comprises polyether blocks composed of a majority of PTMG monomer units,
d) a Shore hardness of greater than 72;
2) from 0 to 70% by weight of at least one other polymer chosen from polyamides, TPU, COPE, PVC, ABS, PS, PET, PETE, PVDF, ETFE, Polyimide, PEEK, PEKK, and silicone,
3) from 0 to 40% of at least one additive,
relative to the total weight of the composition.