Systems and methods for regeneration of aqueous alkaline solution
This invention is directed to regeneration of solutions comprising metal ions, and production of valuable hydroxide compounds. Specifically, the invention is related to regeneration of spent electrolyte solutions comprising metal ions (e.g. Al ions), such as electrolyte solutions used in metal/air batteries. The invention is further related to production of layered double hydroxides, and, optionally aluminum tri-hydroxide from aluminate.
1. A method for the treatment of aqueous alkaline waste solution comprising dissolved hydroxide ions of metal A, said method comprising:
providing a system comprising:
at least one reservoir;
solid-liquid separation means;
concentration means;
agitation means;
inlet for solid and liquid reagent addition;
introducing, aqueous alkaline waste solution comprising dissolved hydroxide ions of metal A into said system;
producing and separating layered double hydroxide (LDH), solid metal A hydroxides or a combination thereof from said waste solution and reducing the amount of dissolved hydroxide ions of metal A in said waste solution, thus producing a regenerated aqueous alkaline solution, comprising reduced amount of dissolved hydroxide ions of metal A,
wherein said producing and separating LDH from said waste solution comprises:
adding metal B ions to said waste solution to induce precipitation of LDH;
separating said LDH from said waste solution; and
optionally drying said LDH; and
wherein the aqueous alkaline waste solution is a spent electrolyte that has been removed from a metal-air battery and the regenerated aqueous alkaline solution is then reused in the metal air battery or another metal air battery.
2. The method of claim 1 , wherein said metal A is aluminum and said hydroxide ions of metal A is aluminate as Al(OH 4 ) − and said solid metal A hydroxides is Al(OH) 3 .
3. The method of claim 1 , wherein said aqueous alkaline waste solution is a waste solution from a chemical process comprising oxidation of metal A or a spent electrolyte from a process comprising electrochemical oxidation of metal A.
4. The method of claim 3 , wherein during said chemical or electrochemical process, metal A is dissolved in an alkaline solution such that said metal A forms dissolved metal A ions in said alkaline solution.
5. The method of claim 1 , wherein said producing solid metal A hydroxides from said waste solution comprises separating, or precipitating and separating, said solid metal A hydroxides from said solution.
6. The method of claim 5 , wherein said solid metal A hydroxides are precipitated by an electrolysis process, a dialysis process, a hydrolysis process, osmosis, phoresis or a combination thereof.
7. The method of claim 6 , wherein said hydrolysis process comprises adding water to said waste solution, thus causing precipitation of solid metal A hydroxides.
8. The method of claim 1 , wherein said producing solid metal A hydroxides comprises the removal of dissolved hydroxide ions of metal A from said solution by decomposition of said dissolved hydroxide ions of metal A to solid metal A hydroxides and to free alkali hydroxides.
9. The method of claim 1 , wherein, prior to said addition of metal B ions said waste solution undergoes re-digestion, wherein said re-digestion comprises heating and agitating said waste solution to re-dissolve metal A solid hydroxide precipitate.
10. The method of claim 1 , wherein said metal B ion is selected from the group consisting of Ca ++ , Mg ++ , Ba ++ and Sr ++ .
11. The method of claim 1 , wherein said waste solution comprises NaOH, KOH, NH 4 OH, LiOH or organic base hydroxides.
12. The method of claim 11 , wherein the concentration of said KOH or NaOH solution varies between 20 and 45 wt %.
13. The method of claim 1 , wherein said method further comprises filtration, centrifugation, solids cake compression, washing, decanting, dewatering, drying, solvent evaporation, or a combination thereof.
14. The method of claim 1 , wherein said LDH comprises Al.
15. The method of claim 1 , wherein said LDH comprises meixnerite, hydrotalcite (HTC), or a combination thereof.