Binder for lithium cell
It is an object of the present invention to provide an electrode having superior charge-discharge capacity, even in the case of using an active material containing silicon. The present invention relates to “a binder for a lithium cell comprises a polymer having a monomer unit derived from acrylic acid, and 1 to 2 kinds of monomer units derived from the compound shown by the general formula (I), the general formula (II), or the general formula (III), as constituents, and cross-linked by a cross-linking agent selected from the compounds described by the following general formulae [1] to [13], and the polymer described by the following general formula [14]”, “a composition for producing an electrode of a lithium cell comprising 1) an active material containing silicon, 2) a conductive assistant, and 3) the above-described binder for a cell”, and “an electrode for a lithium cell having 1) an active material containing silicon, 2) a conductive assistant, 3) the above-described binder for a cell, and (4) a current collector”.
1. A binder for a lithium cell, comprising a polymer having
(i) an acrylic acid monomer unit, and
(ii) 1 to 2 kinds of monomer units other than acrylic acid derived from a compound represented by the following general formula (I) or general formula (II), as constituents, and
cross-linked by a cross-linking agent which is a compounds represented by the following general formulae [4];
wherein R 1 represents hydrogen atom or a methyl group, and provided that in the case where R 2 is hydrogen atom, R 1 represents a methyl group; R 2 represents hydrogen atom, an alkyl group having 1 to 20 carbon atoms; an alkyl group having 1 to 20 carbon atoms, which is substituted with fluorine atom, a hydroxyl group or a cyano group; an aryl group having 6 to 10 carbon atoms; an arylalkyl group having 7 to 13 carbon atoms; an alkoxyalkyl group having 2 to 9 carbon atoms; an alkoxyalkoxyalkyl group having 3 to 9 carbon atoms; an aryloxyalkyl group having 7 to 13 carbon atoms; a morpholinoalkyl group having 5 to 7 carbon atoms; a trialkylsilyl group having 3 to 9 carbon atoms; an alicyclic hydrocarbon group having 6 to 10 carbon atoms, which has oxygen or does not have oxygen; a dialkylaminoalkyl group having 3 to 9 carbon atoms; a hexahydrophthalimide-N-alkyl group having 9 to 15 carbon atoms; the group shown by the following general formula (IV)
wherein R 3 represents an alkylene group having 1 to 6 carbon atoms, which has a hydroxyl group as a substituent or does not have a substituent; R 4 represents hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a phenyl group; “v” represents an integer of 2 to 20;
or the group shown by the following general formula (V)
wherein R 5 to R 7 each independently represent an alkyl group having 1 to 3 carbon atoms;
R 8 represents an alkylene group having 1 to 3 carbon atoms,
wherein R 11 represents hydrogen atom or a methyl group; R 12 represents hydrogen atom, or alkyl group having 1 to 6 carbon atoms; R 13 represents hydrogen atom, an alkyl group having 1 to 6 carbon atoms; a dialkylaminoalkyl group having 3 to 9 carbon atoms; or a hydroxyalkyl group having 1 to 6 carbon atoms,
wherein R 3 4 to R 3 7 each independently represent an alkylene group having 1 to 6 carbon atoms; 1 represents an integer of 1 to 6; m represents an integer of 0 to 6; v1 and v2 each independently represent an integer of 0 or 1.
2. The binder according to claim 1 , wherein the polymer has
(i) the acrylic acid monomer unit, and
(ii) 1 to 2 kinds of monomer units other than acrylic acid derived from a compound represented by the following general formula (I-I) or general formula (II-I), as constituents;
wherein R 101 represents hydrogen atom or a methyl group, and provided that when R 201 is hydrogen atom, R 101 represents a methyl group; R 201 represents hydrogen atom, the alkyl group having 1 to 20 carbon atoms, the alkyl group having 1 to 20 carbon atoms, substituted with fluorine atom, a hydroxyl group or a cyano group, the arylalkyl group having 7 to 13 carbon atoms, the aryloxyalkyl group having 7 to 13 carbon atoms, the hexahydrophthalimide-N-alkyl group having 9 to 15 carbon atoms, or the group shown by the following general formula (IV-I)
wherein R 301 represents the alkylene group having 1 to 3 carbon atoms, which has a hydroxyl group as a substituent or does not have a substituent; R 401 represents hydrogen atom, the alkyl group having 1 to 6 carbon atoms, or a phenyl group; and “v” is the same as described above,
wherein R 111 represents hydrogen atom or a methyl group; R 121 represents hydrogen atom, the alkyl group having 1 to 6 carbon atoms; and R 131 represents hydrogen atom, the alkyl group having 1 to 6 carbon atoms, or the hydroxyalkyl having 1 to 6 carbon atoms.
3. The binder according to claim 2 , wherein the polymer has
(i) the acrylic acid monomer unit, and
(ii) 1 to 2 kinds of monomer units other than acrylic acid derived from a compound represented by the following general formula (I-II) or general formula (II-II), as constituents:
wherein R 102 represents hydrogen atom or a methyl group (provided that when R 202 is hydrogen atom, R 102 represents a methyl group); R 202 represents hydrogen atom, the alkyl group having 1 to 20 carbon atoms, the alkyl group having 1 to 20 carbon atoms, substituted with fluorine atom, a hydroxyl group or a cyano group, the aryloxyalkyl group having 7 to 13 carbon atoms, or the group shown by the following general formula (IV-II)
wherein R 302 represents the alkylene group having 1 to 3 carbon atoms; R 402 represents hydrogen atom, or the alkyl group having 1 to 6 carbon atoms; and “v” is the same as described above,
wherein R 112 represents hydrogen atom or a methyl group; R 122 and R 132 each independently represent hydrogen atom, or the alkyl group having 1 to 3 carbon atoms.
4. The binder according to claim 1 , wherein the polymer has
(i) the acrylic acid monomer unit, and
(ii) 1 to 2 kinds of monomer units other than acrylic acid derived from a compound represented by the following general formula (I-II) or general formula (II-II), as constituents:
wherein R 102 represents hydrogen atom or a methyl group (provided that when R 202 is hydrogen atom, R 102 represents a methyl group); R 202 represents hydrogen atom, the alkyl group having 1 to 20 carbon atoms, the alkyl group having 1 to 20 carbon atoms, substituted with fluorine atom, a hydroxyl group or a cyano group, the aryloxyalkyl group having 7 to 13 carbon atoms, or the group shown by the following general formula (IV-II)
wherein R 302 represents the alkylene group having 1 to 3 carbon atoms; R 402 represents hydrogen atom, or the alkyl group having 1 to 6 carbon atoms; and “v” is the same as described above,
wherein R 112 represents hydrogen atom or a methyl group; R 122 and R 132 each independently represent hydrogen atom, or the alkyl group having 1 to 3 carbon atoms.
5. The binder according to claim 1 , wherein the polymer is neutralized.
6. The binder according to claim 1 , wherein the polymer is neutralized with sodium hydroxide.
7. The binder according to claim 1 , wherein the polymer is dissolved or dispersed in water.
8. A composition for preparation of an electrode of a lithium cell, comprising 1) an active material containing silicon, 2) a conductive assistant, and 3) the binder for a cell according to claim 1 .
9. The composition according to claim 8 , wherein the active material containing silicon contains carbon, silicon, a silicon oxide, silicon bonded with a metal, or the mixed one of at least two or more kinds thereof.
10. The composition according to claim 9 , wherein an electrode is a negative electrode.
11. An electrode for a lithium cell, having 1) an active material containing silicon, 2) a conductive assistant, 3) the binder for a cell according to claim 1 , and (4) a current collector.
12. The electrode according to claim 11 , wherein the active material containing silicon contains carbon, silicon, a silicon oxide, silicon bonded with a metal, or the mixed one of at least two or more kinds thereof.
13. The electrode according to claim 12 , wherein the electrode is a negative electrode.