PURIFICATION OF BRINE SOLUTION
Systems and methods for treatment of an effluent stream are disclosed. In an aspect, a system can comprise an input configured to receive a brine solution, a purification component in communication with the input and configured to receive the brine solution therefrom, the purification component comprising activated carbon, wherein the brine solution is caused to pass through the activated carbon to produce a purified solution, and an output in communication with the purification component to receive the purified solution therefrom.
1 . A system comprising:
an input configured to receive a brine solution;
a purification component in communication with the input and configured to receive the brine solution therefrom, the purification component comprising activated carbon, wherein the brine solution is caused to pass through the activated carbon to produce a purified solution; and
an output in communication with the purification component to receive the purified solution therefrom.
2 . The system of claim 1 , wherein the brine solution has about 15% by weight to about 30% by weight sodium chloride, or about 18% by weight to about 25% by weight sodium chloride.
3 . The system of claim 1 , wherein the brine solution is a byproduct of one or more of a polymerization reaction.
4 . The system of claim 1 , wherein the brine solution comprises organic impurities.
5 . The system of claim 1 , wherein the brine solution comprises one or more of sodium gluconate, bisphenol A, triethyl amine, sebacic acid, methylene chloride, resorcinol, acetone, Q-salt, n-phenyl phenolphthalein, phenol, cresols, xylenol, and tetrahydroxypropyl ethylenediamine.
6 . The system of claim 1 , wherein the purified solution has less total organic carbon than the brine solution received by the input.
7 . The system of claim 1 , wherein the purified solution has less than about 1 ppm of one or more of bisphenol A, triethyl amine, sebacic acid, methylene chloride, resorcinol, acetone, Q-Salt, n-phenyl phenolphthalein, phenol, cresols, xylenol, and tetrahydroxypropyl ethylenediamine.
8 . The system of claim 1 , wherein the temperature in the purification component is between ambient and about 40° C.
9 . The system of claim 1 , wherein the brine solution has a pH between about 3 and about 10.
10 . The system of claim 1 , further comprising an electrolysis stage configured to receive the purified solution and to output sodium hydroxide solution.
11 . The system of claim 10 , wherein the output sodium hydroxide solution comprises sodium chlorate, sodium carbonate, sodium chloride, or iron, or a combination thereof.
12 . The system of claim 10 , wherein the output sodium hydroxide solution comprises from about 27 to about 35 wt % sodium hydroxide, sodium chlorates below 80 ppm, and iron below 2 ppm.
13 . The system of claim 10 , wherein the output sodium hydroxide solution comprises sodium chlorates below about 20 ppm.
14 . The system of claim 10 , wherein the output sodium hydroxide solution comprises sodium chlorates below about 10 ppm.
15 . The system of claim 10 , wherein the electrolysis stage comprises one or more of a mercury-based component, diaphragm component, membrane component, and oxygen depolarizing cathodes component.
16 . The system of claim 10 , further comprising an interfacial process stage configured to receive the output sodium hydroxide solution and to output polycarbonate.
17 . A method comprising:
receiving a brine solution, wherein the brine solution comprises organic impurities; and
causing the brine solution to pass through a portion of activated carbon, wherein the activated carbon operates to remove at least a portion of one or more of the organic impurities from the brine solution resulting in a purified solution, and wherein the purified solution has less than about 1 ppm of one or more of bisphenol A, triethyl amine, sebacic acid, methylene chloride, resorcinol, acetone, Q-Salt, n-phenyl phenolphthalein, phenol, cresols, xylenol, and tetrahydroxypropyl ethylenediamine.
18 . The method of claim 17 , further comprising performing electrolysis on the purified solution to generate sodium hydroxide.
19 . The method of claim 17 , further comprising performing an interfacial process using the sodium hydroxide to produce polycarbonate.
20 . A method comprising:
reacting bisphenol A and sodium hydroxide in an interfacial polymerization process to produce polycarbonate and a resultant brine solution, wherein the brine solution comprises one or more organic impurities;
causing the brine solution to pass through a volume of activated carbon, wherein the activated carbon operates to remove at least a portion of the one or more organic impurities from the brine solution resulting in a purified solution;
performing electrolysis on the purified solution to generate sodium hydroxide solution comprising from about 27 to about 35 wt % sodium hydroxide, sodium chlorates below 80 ppm, and iron below 2 ppm; and
using the sodium hydroxide solution to make polycarbonate by an interfacial process.