Cables made of phase change material
Disclosed is a cable comprising a core and a PCM layer surrounding the core wherein the PCM layer consists of a PCM composition wherein the PCM composition comprises a PCM and an ethylene copolymer; and the core consists of a yarn, strand, or wire each made of a natural or synthetic polymeric material or a metal. The invention is useful for thermal management in a variety of applications in such as, for example, automotive, building, packaging, garments, and footwear.
1. A cable comprising a core and a phase change material (PCM) layer surrounding the core, wherein the PCM layer consists of a PCM composition; the PCM composition comprises a PCM and an ethylene copolymer; and the core consists of a yarn, strand, or wire; each of said yarn, strand and wire being made of a natural or synthetic polymeric material or a metal;
wherein the cable comprises two additional layers, wherein the first additional layer is made of a blend of ionomer and polyamide and the second additional layer is made of a polymer selected from the group consisting of grafted or non-grafted polypropylene homopolymer, grafted or non-grafted polypropylene copolymer, perfluoro ethylene-propylene copolymer, perfluoroalkoxy alkane copolymer, ethylene tetrafluoroethylene copolymer, ethylene acrylate rubber and combinations of two or more thereof.
2. The cable of claim 1 , wherein the amount of ethylene copolymer in the PCM composition is less than or equal to 30 weight percent, based on the total weight of the PCM composition.
3. The cable of claim 1 , wherein the ethylene copolymer is ethylene vinyl acetate.
4. The cable of claim 1 , wherein the yarn, strand or wire is made of polyparaphenylene terephtalamide.
5. The cable of claim 1 , wherein the two additional layer(s) have a thickness of between 50 and 600 μm.
6. The cable of claim 1 , wherein the amount of PCM is at least 70 weight percent, based on the total weight of the cable.
7. The cable of claim 1 , wherein the cable has a diameter of 3 to 6 mm.
8. A process for making the cable of claim 1 , said process comprising the steps of:
providing the core;
extruding the PCM composition onto the core to form the cable; and
extruding two layers of a protective polymer onto the PCM composition and the core, wherein the first layer is made of a blend of ionomer and polyamide and the second layer is made of a polymer selected from the group consisting of grafted or non-grafted polypropylene homopolymer, grafted or non-grafted polypropylene copolymer, perfluoro ethylene-propylene copolymer, perfluoroalkoxy alkane copolymer, ethylene tetrafluoroethylene copolymer, ethylene acrylate rubber, and combinations of two or more thereof.
9. The use of the cable of claim 1 in thermal management.
10. The use of the cable of claim 1 in the automotive industry.
11. The use of the cable of claim 1 in electrical and heat batteries.