Rubber composition for use in tire treads
View Patent ↗A rubber composition comprises: per 100 parts by weight of a diene-based rubber, from 70 to 95 parts by weight of an inorganic filler containing two types of silicas, a silica X and a silica Y, and a carbon black. A compounded amount of the silica X is x parts by weight and a compounded amount of the silica Y is y parts by weight. A total amount of the silica X and the silica Y (x+y) is 85% by weight or greater of the inorganic filler, and a weight ratio of the silica X to the silica Y (x/y) is from 1/3 to 2/1. A nitrogen adsorption specific surface area of the silica X is 160 m 2 /g±10%, and a nitrogen adsorption specific surface area of the silica Y is 200 m 2 /g±10%.
1. A rubber composition for use in tire treads, the rubber composition comprising:
per 100 parts by weight of a diene-based rubber containing 80 to 90% by weight of a terminal-modified solution-polymerized styrene-butadiene rubber and from 10 to 20% by weight of a natural rubber, from 75 to 95 parts by weight of an inorganic filler containing two types of silicas, a silica X and a silica Y, and a carbon black;
where a compounded amount of the silica X is taken to be x parts by weight and a compounded amount of the silica Y is taken to be y parts by weight,
a total amount of the silica X and the silica Y (x+y) being 85% by weight or greater of the inorganic filler, and the total amount of the silica X and the silica Y (x+y) being 70 to 90.25 parts by weight per 100 parts by weight of the diene-based rubber, and a weight ratio of the silica X to the silica Y (x/y) being from 1/2 to 2/1;
a nitrogen adsorption specific surface area of the silica X being in a range of 150 to 170 m 2 /g, and a nitrogen adsorption specific surface area of the silica Y being in a range of 200 to 215 m 2 /g; and
the terminal-modified solution-polymerized styrene-butadiene rubber having a functional group selected from the group consisting of: a hydroxyl group-containing polyorganosiloxane structure and a hydroxyl group.
2. The rubber composition for use in tire treads according to claim 1 , wherein a styrene unit content of the terminal-modified solution-polymerized styrene-butadiene rubber is 35% by weight or greater.
3. The rubber composition for use in tire treads according to claim 1 , wherein a glass transition temperature of the terminal-modified solution-polymerized styrene-butadiene rubber is −35° C. or higher.
4. The rubber composition for use in tire treads according to claim 3 , wherein a styrene unit content of the terminal-modified solution-polymerized styrene-butadiene rubber is 35% by weight or greater.
5. The rubber composition for use in tire treads according to claim 1 , further comprising an alkyltriethoxysilane having an alkyl group having from 7 to 20 carbons in an amount of 0.1 to 20% by weight of the total amount of the silicas (x+y).
6. The rubber composition for use in tire treads according to claim 5 , wherein a glass transition temperature of the terminal-modified solution-polymerized styrene-butadiene rubber is −35° C. or higher.
7. The rubber composition for use in tire treads according to claim 6 , wherein a styrene unit content of the terminal-modified solution-polymerized styrene-butadiene rubber is 35% by weight or greater.
8. The rubber composition for use in tire treads according to claim 1 , wherein the nitrogen adsorption specific surface area of the silica X is in a range of 165 to 170 m 2 /g.
9. A pneumatic tire comprising the rubber composition for use in tire treads described in claim 1 .
10. A rubber composition for use in tire treads, the rubber composition comprising:
per 100 parts by weight of a diene-based rubber containing 55 to 90% by weight of a terminal-modified solution-polymerized styrene-butadiene rubber and from 10 to 20% by weight of a natural rubber, from 70 to 95 parts by weight of an inorganic filler containing two types of silicas, a silica X and a silica Y, and a carbon black;
where a compounded amount of the silica X is taken to be x parts by weight and a compounded amount of the silica Y is taken to be y parts by weight,
a total amount of the silica X and the silica Y (x+y) being 85% by weight or greater of the inorganic filler, and a weight ratio of the silica X to the silica Y (x/y) being from 1/2 to 2/1;
a nitrogen adsorption specific surface area of the silica X being in a range of 150 to 175 m 2 /g, and a nitrogen adsorption specific surface area of the silica Y being in a range of 185 to 215 m 2 /g;
the rubber composition further comprising an alkyltriethoxysilane having an alkyl group having from 7 to 20 carbons in an amount of 0.1 to 20% by weight of the total amount of the silicas (x+y); and
the terminal-modified solution-polymerized styrene-butadiene rubber having a functional group selected from the group consisting of: a hydroxyl group-containing polyorganosiloxane structure and a hydroxyl group.
11. A rubber composition for use in tire treads, the rubber composition comprising:
per 100 parts by weight of a diene-based rubber containing 55 to 90% by weight of a terminal-modified solution-polymerized styrene-butadiene rubber and from 10 to 20% by weight of a natural rubber, from 70 to 95 parts by weight of an inorganic filler containing two types of silicas, a silica X and a silica Y, and a carbon black;
where a compounded amount of the silica X is taken to be x parts by weight and a compounded amount of the silica Y is taken to be y parts by weight,
a total amount of the silica X and the silica Y (x+y) being 85% by weight or greater of the inorganic filler, and a weight ratio of the silica X to the silica Y (x/y) being from 1/2 to 2/1; and
a nitrogen adsorption specific surface area of the silica X being in a range of 165 to 175 m 2 /g, and a nitrogen adsorption specific surface area of the silica Y being in a range of 185 to 194 m 2 /g; and
the terminal-modified solution-polymerized styrene-butadiene rubber having a functional group selected from the group consisting of: a hydroxyl group-containing polyorganosiloxane structure and a hydroxyl group.