IP Library Granted Patent US 10,450,451
Granted Patent B2
US 10,450,451 · App. 15/310,283 · Granted Oct 22, 2019

Polypropylene composition for automotive interior applications

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,450,451
App. No.
15/310,283
Granted
Oct 22, 2019
Kind
B2
Abstract

Polypropylene composition comprising a heterophasic propylene copolymer and a mineral filler, wherein said heterophasic propylene copolymer has a melting temperature in the range of 140 to 155° C., a xylene cold soluble content in the range of 20 to 35 wt.-% and a comonomer content of the xylene cold soluble fraction in the range of 18 to 95 wt.-%, wherein further the weight ratio between heterophasic propylene copolymer and the mineral filler is in the range of 2/1 to 4/1.

Claims (56)

1. A polypropylene composition comprising

(a) a heterophasic propylene copolymer (HECO) comprising

(a1) a matrix (M) being a propylene homopolymer (H-PP) or propylene copolymer (R-PP) and

(a2) an elastomeric propylene copolymer (EC) dispersed in said matrix (M),

(b) a mineral filler (F),

(c) a high density polyethylene (HDPE), having

(c1) a density of at least 940 kg/m 3 and

(c2) a melt flow rate MFR 2 (190° C.) of 0.2 to 10 g/10 min, and

(d) a plastomer (P) being chemically different to the elastomeric propylene copolymer (EC) of the heterophasic propylene copolymer (HECO), wherein the plastomer (P):

(d1) is a polyethylene,

(d2) has a density in the range 820 to 880 kg/m 3 , and

(d3) has a melt flow rate MFR 2 (190° C.) measured according to ISO 1133 in the range of 0.5 to 30.0 g/10 min,

wherein said heterophasic propylene copolymer (HECO) has

(i) a melting temperature determined by differential scanning calorimetry (DSC) in the range of 140 to 155° C.,

(ii) an ethylene content in the range of 22.0 to 35.0 wt %, based on the total weight of the heterophasic propylene copolymer (HECO),

(iii) a xylene cold soluble (XCS) content in the range of 20 to 35 wt.-%, and

(iv) a comonomer content of the xylene cold soluble (XCS) fraction in the range of 60 to 95 wt.-%,

wherein further the weight ratio between the heterophasic propylene copolymer (HECO) and the mineral filler (F) [(HECO)/(F)] is in the range of 2/1 to below 4/1 and

the melt flow rate MFR 2 (230° C.) measured according to ISO1133 of the polypropylene composition is in the range of 1.0 to 11.0 g/10min.

2. The polypropylene composition according to claim 1 , wherein

(a) the matrix (M) has melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 20 to 80 g/10 min, and/or

(b) the heterophasic propylene copolymer (HECO) has 2,1 regio-defects of at least 0.2 mol % determined by 13 C-NMR spectroscopy.

3. A polypropylene composition comprising

(a) a heterophasic propylene copolymer (HECO) comprising

(a1) a matrix (M) being a propylene homopolymer (H-PP) or propylene copolymer (R-PP) and

(a2) an elastomeric propylene copolymer (EC) dispersed in said matrix (M),

and

(b) a mineral filler (F),

(c) a high density polyethylene (HDPE), having

(c1) a density of at least 940 kg/m 3 and

(c2) a melt flow rate MFR 2 (190° C.) of 0.2 to 10 g/10 min, and

(d) a plastomer (P) being chemically different to the elastomeric propylene copolymer (EC) of the heterophasic propylene copolymer (HECO), wherein the plastomer (P):

(d1) is a polyethylene,

(d2) has a density in the range 820 to 880 kg/m 3 , and

(d3) has a melt flow rate MFR 2 (190° C.) measured according to ISO 1133 in the range of 0.5 to 30.0 g/10 min,

wherein said heterophasic propylene copolymer (HECO) has

(i) 2,1 regio-defects of at least 0.2 mol % determined by 13 C-NMR spectroscopy,

(ii) an ethylene content in the range of 22.0 to 35.0 wt %, based on the total weight of the heterophasic propylene copolymer (HECO),

(iii) a xylene cold soluble (XCS) content in the range of 20 to 35 wt.-%, and

(iv) a comonomer content of the xylene cold soluble (XCS) fraction in the range of 60 to 95 wt.-%,

wherein further the weight ratio between the heterophasic propylene copolymer (HECO) and the mineral filler (F) [(HECO)/(F)] is in the range of 2/1 to below 4/1, and the melt flow rate MFR 2 (230° C.) measured according to ISO1133 of the polypropylene composition is in the range of 1.0 to 11.0 g/10 min.

4. The polypropylene composition according to claim 3 , wherein the matrix (M) has melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 20 to 80 g/10 min.

5. The polypropylene composition according to claim 1 , wherein

(a) the matrix (M) is a propylene homopolymer (H-PP), and/or

(b) the intrinsic viscosity of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) is at least 1.0.

6. The polypropylene composition according to claim 1 , wherein the melt flow rate MFR 2 (230° C.) measured according to ISO 1133

of the heterophasic propylene copolymer (HECO) is in the range of 1.0 to 30 g/10 min.

7. The polypropylene composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has a first glass transition temperature Tg(1) and a second glass transition temperature Tg(2), wherein said first glass transition temperature Tg(1) is above the second glass transition temperature Tg(2).

8. An article comprising a composition according to claim 1 .

9. The article according to claim 8 , wherein the article is an automotive interior article.

10. The polypropylene composition according to claim 3 , wherein

(a) the matrix (M) is a propylene homopolymer (H-PP), and/or

(b) the intrinsic viscosity of the xylene cold soluble fraction (XCS) of the heterophasic propylene copolymer (HECO) is at least 1.0.

11. The polypropylene composition according to claim 3 , wherein the melt flow rate MFR 2 (230° C.) measured according to ISO 1133

of the heterophasic propylene copolymer (HECO) is in the range of 1.0 to 30 g/10 min.

12. The polypropylene composition according to claim 3 , wherein the heterophasic propylene copolymer (HECO) has a first glass transition temperature Tg(1) and a second glass transition temperature Tg(2), wherein said first glass transition temperature Tg(1) is above the second glass transition temperature Tg(2).

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 10, 2016
From: WANG, JINGBO; RESCONI, LUIGI; DOSHEV, PETAR; GAHLEITNER, MARKUS
To: BOREALIS AG
Reel/Frame 040279/0146 →