Rubber composition for tire rim cushion or rubber finishing, and pneumatic tire
View Patent ↗A rubber composition for a tire rim cushion or rubber finishing contains a diene rubber and a filler containing a carbon black. The diene rubber contains a natural rubber and/or an isoprene rubber, and a modified polymer that is obtained by reacting a nitrone compound with a double bond of a conjugated diene polymer. The content of the natural rubber and/or the isoprene rubber in the diene rubber is from 30 to 60 mass %, the content of the modified polymer in the diene rubber is from 8 to 70 mass %, the content of the filler is from 60 to 90 parts by mass per 100 parts by mass of the diene rubber, and the nitrogen adsorption specific surface area of the carbon black is from 60 to 150 m 2 /g. Such rubber composition has excellent low heat build-up and ozone resistance when formed into a tire.
1. A rubber composition for a tire rim cushion or rubber finishing, the rubber composition comprising: a diene rubber and a filler containing a carbon black;
the diene rubber containing a natural rubber and/or an isoprene rubber, and a modified polymer that is obtained by reacting a nitrone compound having a carboxy group with a double bond of a conjugated diene polymer;
a content of the natural rubber and/or the isoprene rubber in the diene rubber being from 30 to 60 mass %;
a content of the modified polymer in the diene rubber being from 8 to 70 mass %;
a content of the filler being from 60 to 90 parts by mass per 100 parts by mass of the diene rubber; and
a nitrogen adsorption specific surface area of the carbon black being from 60 to 150 m 2 /g.
2. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein the diene rubber contains the natural rubber,
a content of the natural rubber in the diene rubber is from 30 to 60 mass %, and
a content of the carbon black is from 67 to 90 parts by mass per 100 parts by mass of the diene rubber.
3. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein the filler further contains silica,
a content of the carbon black is from 5 to 85 parts by mass per 100 parts by mass of the diene rubber,
a content of the silica is from 5 to 85 parts by mass per 100 parts by mass of the diene rubber, and
a total content of the carbon black and the silica is from 60 to 90 parts by mass per 100 parts by mass of the diene rubber.
4. The rubber composition for a tire rim cushion or rubber finishing according to claim 3 , wherein a CTAB adsorption specific surface area of the silica is from 50 to 230 m 2 /g.
5. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein the nitrone compound is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
6. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
7. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein an amount of the nitrone compound that is reacted with the double bond of the conjugated diene polymer is from 0.1 to 10 parts by mass per 100 parts by mass of the diene rubber.
8. The rubber composition for a tire rim cushion or rubber finishing according to claim 1 , wherein the modified polymer is a modified polymer obtained by reacting a nitrone compound with a double bond of a butadiene rubber.
9. A pneumatic tire comprising the rubber composition described in claim 1 in a tire rim cushion or rubber finishing.
10. The rubber composition for a tire rim cushion or rubber finishing according to claim 2 , wherein the nitrone compound is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
11. The rubber composition for a tire rim cushion or rubber finishing according to claim 3 , wherein the nitrone compound is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
12. The rubber composition for a tire rim cushion or rubber finishing according to claim 4 , wherein the nitrone compound is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
13. The rubber composition for a tire rim cushion or rubber finishing according to claim 2 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
14. The rubber composition for a tire rim cushion or rubber finishing according to claim 3 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
15. The rubber composition for a tire rim cushion or rubber finishing according to claim 4 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
16. The rubber composition for a tire rim cushion or rubber finishing according to claim 5 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
17. The rubber composition for a tire rim cushion or rubber finishing according to claim 10 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
18. The rubber composition for a tire rim cushion or rubber finishing according to claim 11 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.
19. The rubber composition for a tire rim cushion or rubber finishing according to claim 12 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %,
where “degree of modification” refers to a proportion (mol %) of double bonds modified with the nitrone compound relative to all the double bonds of conjugated diene contained in the conjugated diene polymer.